1,2,4-Triazole and Its Derivatives as Corrosion Inhibitors for Aluminum Brass (HAl77-2) in 3.5 wt.% NaCl Solution Article Swipe

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YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.5755/j02.ms.38849

In this work, the 1,2,4-triazole and its derivatives were used as target corrosion inhibitors, the corrosion inhibition of 1,2,4-triazole (TAZ), 3-amino-1,2,4-triazole (ATA) and 3,5-diamino-1,2,4-triazole (DAT) in 3.5 wt.% NaCl solutions for aluminum brass (HAl77-2) are reported. The inhibition properties and mechanism were investigated by weight loss tests, electrochemical tests (electrochemical impedance spectroscopy and linear polarization resistance tests), surface characteristic analysis (scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) tests), and quantum chemistry calculations. The results showed that TAZ, ATA, and DAT effectively inhibited the corrosion of HAl77-2. The maximum inhibition efficiencies of the three corrosion inhibitors were 84.4 %, 86.4 %, and 87.1 %, respectively. The adsorption processes followed the Langmuir adsorption isotherm model and were of mixed type, i.e., both physisorption and chemisorption. SEM and EDS tests confirmed the effective adsorption of the TAZ, ATA, and DAT on the HAl77-2 surface. The results of quantum chemistry calculations were consistent with the electrochemical test results.

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Brass Materials science Solid mechanics Structural material Aluminium Corrosion Metallurgy Triazole Nuclear chemistry Combinatorial chemistry Inorganic chemistry Copper Organic chemistry Composite material Chemistry

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Type: article
Language: en
Landing Page: https://doi.org/10.5755/j02.ms.38849
PDF: https://matsc.ktu.lt/index.php/MatSc/article/download/38849/16937
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DOI: https://doi.org/10.5755/j02.ms.38849

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Title: 1,2,4-Triazole and Its Derivatives as Corrosion Inhibitors for Aluminum Brass (HAl77-2) in 3.5 wt.% NaCl Solution

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Language: en

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Publication year: 2025

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Publication date: 2025-05-29

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Authors: Di Zhu, Hong Ju, Hanzhi LI, Xu Jia

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Concepts: Brass, Materials science, Solid mechanics, Structural material, Aluminium, Corrosion, Metallurgy, Triazole, Nuclear chemistry, Combinatorial chemistry, Inorganic chemistry, Copper, Organic chemistry, Composite material, Chemistry

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abstract_inverted_index.characteristic	58
abstract_inverted_index.chemisorption.	124
abstract_inverted_index.electrochemical	47, 153
abstract_inverted_index.(electrochemical	49
abstract_inverted_index.energy-dispersive	65
abstract_inverted_index.3-amino-1,2,4-triazole	20
abstract_inverted_index.3,5-diamino-1,2,4-triazole	23
cited_by_percentile_year
countries_distinct_count	0
institutions_distinct_count	4
citation_normalized_percentile.value	0.18203968
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False