A [CuII24] truncated octahedron and its [CuII8] building block Article Swipe

View

Euan K. Brechin , Lucinda R. B. Wilson , Gary S. Nichol , Scott J. Dalgarno ·

YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.26434/chemrxiv-2025-l2tk4

Reaction of CuCl2·2H2O with p-tert-butylthiacalix[4]arene (H4TC[4]A) affords a [CuII24] cage whose metallic skeleton conforms to a truncated octahedron in which the metal ions are strongly antiferromagnetically coupled. A structurally related [Cu8] cluster can be made using CuBr2 in an otherwise identical reaction.

Related Topics

Concepts

Block (permutation group theory) Octahedron Geology Combinatorics Mathematics Crystallography Chemistry Crystal structure

Metadata

Type: preprint
Language: en
Landing Page: https://doi.org/10.26434/chemrxiv-2025-l2tk4
OA Status: gold
Related Works: 10
OpenAlex ID: https://openalex.org/W4407772014

All OpenAlex metadata

Raw OpenAlex JSON

OpenAlex ID: https://openalex.org/W4407772014

Canonical identifier for this work in OpenAlex
DOI: https://doi.org/10.26434/chemrxiv-2025-l2tk4

Digital Object Identifier
Title: A [CuII24] truncated octahedron and its [CuII8] building block

Work title
Type: preprint

OpenAlex work type
Language: en

Primary language
Publication year: 2025

Year of publication
Publication date: 2025-02-20

Full publication date if available
Authors: Euan K. Brechin, Lucinda R. B. Wilson, Gary S. Nichol, Scott J. Dalgarno

List of authors in order
Landing page: https://doi.org/10.26434/chemrxiv-2025-l2tk4

Publisher landing page
Open access: Yes

Whether a free full text is available
OA status: gold

Open access status per OpenAlex
OA URL: https://doi.org/10.26434/chemrxiv-2025-l2tk4

Direct OA link when available
Concepts: Block (permutation group theory), Octahedron, Geology, Combinatorics, Mathematics, Crystallography, Chemistry, Crystal structure

Top concepts (fields/topics) attached by OpenAlex
Cited by: 0

Total citation count in OpenAlex
Related works (count): 10

Other works algorithmically related by OpenAlex

Full payload

id	https://openalex.org/W4407772014
doi	https://doi.org/10.26434/chemrxiv-2025-l2tk4
ids.doi	https://doi.org/10.26434/chemrxiv-2025-l2tk4
ids.openalex	https://openalex.org/W4407772014
fwci	0.0
type	preprint
title	A [CuII24] truncated octahedron and its [CuII8] building block
biblio.issue
biblio.volume
biblio.last_page
biblio.first_page
topics[0].id	https://openalex.org/T10612
topics[0].field.id	https://openalex.org/fields/25
topics[0].field.display_name	Materials Science
topics[0].score	0.9994999766349792
topics[0].domain.id	https://openalex.org/domains/3
topics[0].domain.display_name	Physical Sciences
topics[0].subfield.id	https://openalex.org/subfields/2504
topics[0].subfield.display_name	Electronic, Optical and Magnetic Materials
topics[0].display_name	Magnetism in coordination complexes
topics[1].id	https://openalex.org/T10163
topics[1].field.id	https://openalex.org/fields/27
topics[1].field.display_name	Medicine
topics[1].score	0.9973000288009644
topics[1].domain.id	https://openalex.org/domains/4
topics[1].domain.display_name	Health Sciences
topics[1].subfield.id	https://openalex.org/subfields/2730
topics[1].subfield.display_name	Oncology
topics[1].display_name	Metal complexes synthesis and properties
topics[2].id	https://openalex.org/T10096
topics[2].field.id	https://openalex.org/fields/16
topics[2].field.display_name	Chemistry
topics[2].score	0.9965999722480774
topics[2].domain.id	https://openalex.org/domains/3
topics[2].domain.display_name	Physical Sciences
topics[2].subfield.id	https://openalex.org/subfields/1604
topics[2].subfield.display_name	Inorganic Chemistry
topics[2].display_name	Metal-Organic Frameworks: Synthesis and Applications
is_xpac	False
apc_list
apc_paid
concepts[0].id	https://openalex.org/C2777210771
concepts[0].level	2
concepts[0].score	0.7106618285179138
concepts[0].wikidata	https://www.wikidata.org/wiki/Q4927124
concepts[0].display_name	Block (permutation group theory)
concepts[1].id	https://openalex.org/C198819137
concepts[1].level	3
concepts[1].score	0.6410954594612122
concepts[1].wikidata	https://www.wikidata.org/wiki/Q188884
concepts[1].display_name	Octahedron
concepts[2].id	https://openalex.org/C127313418
concepts[2].level	0
concepts[2].score	0.4732573330402374
concepts[2].wikidata	https://www.wikidata.org/wiki/Q1069
concepts[2].display_name	Geology
concepts[3].id	https://openalex.org/C114614502
concepts[3].level	1
concepts[3].score	0.2666005492210388
concepts[3].wikidata	https://www.wikidata.org/wiki/Q76592
concepts[3].display_name	Combinatorics
concepts[4].id	https://openalex.org/C33923547
concepts[4].level	0
concepts[4].score	0.26432254910469055
concepts[4].wikidata	https://www.wikidata.org/wiki/Q395
concepts[4].display_name	Mathematics
concepts[5].id	https://openalex.org/C8010536
concepts[5].level	1
concepts[5].score	0.1957293152809143
concepts[5].wikidata	https://www.wikidata.org/wiki/Q160398
concepts[5].display_name	Crystallography
concepts[6].id	https://openalex.org/C185592680
concepts[6].level	0
concepts[6].score	0.1218370795249939
concepts[6].wikidata	https://www.wikidata.org/wiki/Q2329
concepts[6].display_name	Chemistry
concepts[7].id	https://openalex.org/C115624301
concepts[7].level	2
concepts[7].score	0.0
concepts[7].wikidata	https://www.wikidata.org/wiki/Q895901
concepts[7].display_name	Crystal structure
keywords[0].id	https://openalex.org/keywords/block
keywords[0].score	0.7106618285179138
keywords[0].display_name	Block (permutation group theory)
keywords[1].id	https://openalex.org/keywords/octahedron
keywords[1].score	0.6410954594612122
keywords[1].display_name	Octahedron
keywords[2].id	https://openalex.org/keywords/geology
keywords[2].score	0.4732573330402374
keywords[2].display_name	Geology
keywords[3].id	https://openalex.org/keywords/combinatorics
keywords[3].score	0.2666005492210388
keywords[3].display_name	Combinatorics
keywords[4].id	https://openalex.org/keywords/mathematics
keywords[4].score	0.26432254910469055
keywords[4].display_name	Mathematics
keywords[5].id	https://openalex.org/keywords/crystallography
keywords[5].score	0.1957293152809143
keywords[5].display_name	Crystallography
keywords[6].id	https://openalex.org/keywords/chemistry
keywords[6].score	0.1218370795249939
keywords[6].display_name	Chemistry
language	en
locations[0].id	doi:10.26434/chemrxiv-2025-l2tk4
locations[0].is_oa	True
locations[0].source
locations[0].license	cc-by
locations[0].pdf_url
locations[0].version	acceptedVersion
locations[0].raw_type	posted-content
locations[0].license_id	https://openalex.org/licenses/cc-by
locations[0].is_accepted	True
locations[0].is_published	False
locations[0].raw_source_name
locations[0].landing_page_url	https://doi.org/10.26434/chemrxiv-2025-l2tk4
indexed_in	crossref
authorships[0].author.id	https://openalex.org/A5090097086
authorships[0].author.orcid	https://orcid.org/0000-0002-9365-370X
authorships[0].author.display_name	Euan K. Brechin
authorships[0].countries	GB
authorships[0].affiliations[0].institution_ids	https://openalex.org/I98677209
authorships[0].affiliations[0].raw_affiliation_string	The University of Edinburgh
authorships[0].institutions[0].id	https://openalex.org/I98677209
authorships[0].institutions[0].ror	https://ror.org/01nrxwf90
authorships[0].institutions[0].type	education
authorships[0].institutions[0].lineage	https://openalex.org/I98677209
authorships[0].institutions[0].country_code	GB
authorships[0].institutions[0].display_name	University of Edinburgh
authorships[0].author_position	first
authorships[0].raw_author_name	Euan Brechin
authorships[0].is_corresponding	False
authorships[0].raw_affiliation_strings	The University of Edinburgh
authorships[1].author.id	https://openalex.org/A5081945466
authorships[1].author.orcid	https://orcid.org/0000-0001-8762-1851
authorships[1].author.display_name	Lucinda R. B. Wilson
authorships[1].countries	GB
authorships[1].affiliations[0].institution_ids	https://openalex.org/I98677209
authorships[1].affiliations[0].raw_affiliation_string	The University of Edinburgh
authorships[1].institutions[0].id	https://openalex.org/I98677209
authorships[1].institutions[0].ror	https://ror.org/01nrxwf90
authorships[1].institutions[0].type	education
authorships[1].institutions[0].lineage	https://openalex.org/I98677209
authorships[1].institutions[0].country_code	GB
authorships[1].institutions[0].display_name	University of Edinburgh
authorships[1].author_position	middle
authorships[1].raw_author_name	Lucinda Wilson
authorships[1].is_corresponding	False
authorships[1].raw_affiliation_strings	The University of Edinburgh
authorships[2].author.id	https://openalex.org/A5054940417
authorships[2].author.orcid	https://orcid.org/0000-0002-1597-3679
authorships[2].author.display_name	Gary S. Nichol
authorships[2].countries	GB
authorships[2].affiliations[0].institution_ids	https://openalex.org/I98677209
authorships[2].affiliations[0].raw_affiliation_string	The University of Edinburgh
authorships[2].institutions[0].id	https://openalex.org/I98677209
authorships[2].institutions[0].ror	https://ror.org/01nrxwf90
authorships[2].institutions[0].type	education
authorships[2].institutions[0].lineage	https://openalex.org/I98677209
authorships[2].institutions[0].country_code	GB
authorships[2].institutions[0].display_name	University of Edinburgh
authorships[2].author_position	middle
authorships[2].raw_author_name	Gary Nichol
authorships[2].is_corresponding	False
authorships[2].raw_affiliation_strings	The University of Edinburgh
authorships[3].author.id	https://openalex.org/A5040141364
authorships[3].author.orcid	https://orcid.org/0000-0001-7831-012X
authorships[3].author.display_name	Scott J. Dalgarno
authorships[3].affiliations[0].raw_affiliation_string	Heriot-Watt University
authorships[3].author_position	last
authorships[3].raw_author_name	Scott Dalgarno
authorships[3].is_corresponding	False
authorships[3].raw_affiliation_strings	Heriot-Watt University
has_content.pdf	False
has_content.grobid_xml	False
is_paratext	False
open_access.is_oa	True
open_access.oa_url	https://doi.org/10.26434/chemrxiv-2025-l2tk4
open_access.oa_status	gold
open_access.any_repository_has_fulltext	False
created_date	2025-10-10T00:00:00
display_name	A [CuII24] truncated octahedron and its [CuII8] building block
has_fulltext	False
is_retracted	False
updated_date	2025-11-06T03:46:38.306776
primary_topic.id	https://openalex.org/T10612
primary_topic.field.id	https://openalex.org/fields/25
primary_topic.field.display_name	Materials Science
primary_topic.score	0.9994999766349792
primary_topic.domain.id	https://openalex.org/domains/3
primary_topic.domain.display_name	Physical Sciences
primary_topic.subfield.id	https://openalex.org/subfields/2504
primary_topic.subfield.display_name	Electronic, Optical and Magnetic Materials
primary_topic.display_name	Magnetism in coordination complexes
related_works	https://openalex.org/W2324615561, https://openalex.org/W2086120259, https://openalex.org/W2245170124, https://openalex.org/W2076393078, https://openalex.org/W1986527768, https://openalex.org/W2132477358, https://openalex.org/W3186982001, https://openalex.org/W1984402782, https://openalex.org/W2137941439, https://openalex.org/W2004200960
cited_by_count	0
locations_count	1
best_oa_location.id	doi:10.26434/chemrxiv-2025-l2tk4
best_oa_location.is_oa	True
best_oa_location.source
best_oa_location.license	cc-by
best_oa_location.pdf_url
best_oa_location.version	acceptedVersion
best_oa_location.raw_type	posted-content
best_oa_location.license_id	https://openalex.org/licenses/cc-by
best_oa_location.is_accepted	True
best_oa_location.is_published	False
best_oa_location.raw_source_name
best_oa_location.landing_page_url	https://doi.org/10.26434/chemrxiv-2025-l2tk4
primary_location.id	doi:10.26434/chemrxiv-2025-l2tk4
primary_location.is_oa	True
primary_location.source
primary_location.license	cc-by
primary_location.pdf_url
primary_location.version	acceptedVersion
primary_location.raw_type	posted-content
primary_location.license_id	https://openalex.org/licenses/cc-by
primary_location.is_accepted	True
primary_location.is_published	False
primary_location.raw_source_name
primary_location.landing_page_url	https://doi.org/10.26434/chemrxiv-2025-l2tk4
publication_date	2025-02-20
publication_year	2025
referenced_works_count	0
abstract_inverted_index.A	27
abstract_inverted_index.a	7, 15
abstract_inverted_index.an	38
abstract_inverted_index.be	33
abstract_inverted_index.in	18, 37
abstract_inverted_index.of	1
abstract_inverted_index.to	14
abstract_inverted_index.are	23
abstract_inverted_index.can	32
abstract_inverted_index.the	20
abstract_inverted_index.cage	9
abstract_inverted_index.ions	22
abstract_inverted_index.made	34
abstract_inverted_index.with	3
abstract_inverted_index.CuBr2	36
abstract_inverted_index.[Cu8]	30
abstract_inverted_index.metal	21
abstract_inverted_index.using	35
abstract_inverted_index.which	19
abstract_inverted_index.whose	10
abstract_inverted_index.affords	6
abstract_inverted_index.cluster	31
abstract_inverted_index.related	29
abstract_inverted_index.Reaction	0
abstract_inverted_index.[CuII24]	8
abstract_inverted_index.conforms	13
abstract_inverted_index.coupled.	26
abstract_inverted_index.metallic	11
abstract_inverted_index.skeleton	12
abstract_inverted_index.strongly	24
abstract_inverted_index.identical	40
abstract_inverted_index.otherwise	39
abstract_inverted_index.reaction.	41
abstract_inverted_index.truncated	16
abstract_inverted_index.(H4TC[4]A)	5
abstract_inverted_index.octahedron	17
abstract_inverted_index.CuCl2·2H2O	2
abstract_inverted_index.structurally	28
abstract_inverted_index.antiferromagnetically	25
abstract_inverted_index.p-tert-butylthiacalix[4]arene	4
cited_by_percentile_year
countries_distinct_count	1
institutions_distinct_count	4
citation_normalized_percentile.value	0.04007768
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False