A Review of Sample Analysis at Mars-Evolved Gas Analysis Laboratory Analog Work Supporting the Presence of Perchlorates and Chlorates in Gale Crater, Mars Article Swipe
J. V. Clark
,
B. Sutter
,
P. D. Archer
,
D. W. Ming
,
E. B. Rampe
,
A. C. McAdam
,
R. Navarro‐González
,
J. L. Eigenbrode
,
D. P. Glavin
,
María‐Paz Zorzano
,
Javier Martín‐Torres
,
R. V. Morris
,
Valerie Tu
,
S. J. Ralston
,
P. R. Mahaffy
·
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.3390/min11050475
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.3390/min11050475
The Sample Analysis at Mars (SAM) instrument on the Curiosity rover has detected evidence of oxychlorine compounds (i.e., perchlorates and chlorates) in Gale crater, which has implications for past habitability, diagenesis, aqueous processes, interpretation of in situ organic analyses, understanding the martian chlorine cycle, and hazards and resources for future human exploration. Pure oxychlorines and mixtures of oxychlorines with Mars-analog phases have been analyzed for their oxygen (O2) and hydrogen chloride (HCl) releases on SAM laboratory analog instruments in order to constrain which phases are present in Gale crater. These studies demonstrated that oxychlorines evolve O2 releases with peaks between ~200 and 600 °C, although the thermal decomposition temperatures and the amount of evolved O2 decrease when iron phases are present in the sample. Mg and Fe oxychlorines decompose into oxides and release HCl between ~200 and 542 °C. Ca, Na, and K oxychlorines thermally decompose into chlorides and do not evolve HCl by themselves. However, the chlorides (original or from oxychlorine decomposition) can react with water-evolving phases (e.g., phyllosilicates) in the sample and evolve HCl within the temperature range of SAM (<~870 °C). These laboratory analog studies support that the SAM detection of oxychlorine phases is consistent with the presence of Mg, Ca, Na, and K perchlorate and/or chlorate along with possible contributions from adsorbed oxychlorines in Gale crater samples.
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Metadata
- Type
- review
- Language
- en
- Landing Page
- https://doi.org/10.3390/min11050475
- https://www.mdpi.com/2075-163X/11/5/475/pdf?version=1621593089
- OA Status
- gold
- Cited By
- 23
- References
- 98
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3159492449
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W3159492449Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/min11050475Digital Object Identifier
- Title
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A Review of Sample Analysis at Mars-Evolved Gas Analysis Laboratory Analog Work Supporting the Presence of Perchlorates and Chlorates in Gale Crater, MarsWork title
- Type
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reviewOpenAlex work type
- Language
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enPrimary language
- Publication year
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2021Year of publication
- Publication date
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2021-04-30Full publication date if available
- Authors
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J. V. Clark, B. Sutter, P. D. Archer, D. W. Ming, E. B. Rampe, A. C. McAdam, R. Navarro‐González, J. L. Eigenbrode, D. P. Glavin, María‐Paz Zorzano, Javier Martín‐Torres, R. V. Morris, Valerie Tu, S. J. Ralston, P. R. MahaffyList of authors in order
- Landing page
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https://doi.org/10.3390/min11050475Publisher landing page
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https://www.mdpi.com/2075-163X/11/5/475/pdf?version=1621593089Direct link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
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https://www.mdpi.com/2075-163X/11/5/475/pdf?version=1621593089Direct OA link when available
- Concepts
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Mars Exploration Program, Impact crater, Perchlorate, Astrobiology, Martian, Chemistry, Hydrogen chloride, Fumarole, Crater lake, Mineralogy, Environmental chemistry, Analytical Chemistry (journal), Inorganic chemistry, Organic chemistry, Physics, IonTop concepts (fields/topics) attached by OpenAlex
- Cited by
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23Total citation count in OpenAlex
- Citations by year (recent)
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2025: 4, 2024: 6, 2023: 5, 2022: 8Per-year citation counts (last 5 years)
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98Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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