A Simple Synthesis of an N‐Doped Carbon ORR Catalyst: Hierarchical Micro/Meso/Macro Porosity and Graphitic Shells Article Swipe
YOU?
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· 2015
· Open Access
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· DOI: https://doi.org/10.1002/chem.201504568
Replacing platinum as an oxygen reduction catalyst is an important scientific and technological challenge. Herein we report a simple synthesis of a complex carbon with very good oxygen reduction reaction (ORR) activity at pH 13. Pyrolysis of magnesium nitrilotriacetate yields a carbon with hierarchical micro/meso/macro porosity, resulting from in situ templating by spontaneously forming MgO nanoparticles and from etching by pyrolysis gases. The mesopores are lined with highly graphitic shells. The high ORR activity is attributed to a good balance between high specific surface area and mass transport through the hierarchical porosity, and to improved electronic conductivity through the graphitic shells. This novel carbon has a high surface area (1320 m 2 g −1 ), and high nitrogen content for a single precursor synthesis (∼6 %). Importantly, its synthesis is both cheap and easily scalable.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/chem.201504568
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.201504568
- OA Status
- bronze
- Cited By
- 93
- References
- 37
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2177057464
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2177057464Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/chem.201504568Digital Object Identifier
- Title
-
A Simple Synthesis of an N‐Doped Carbon ORR Catalyst: Hierarchical Micro/Meso/Macro Porosity and Graphitic ShellsWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2015Year of publication
- Publication date
-
2015-11-17Full publication date if available
- Authors
-
David Eisenberg, Wowa Stroek, Norbert J. Geels, C.S. Sandu, Adam Heller, Ning Yan, Gadi RothenbergList of authors in order
- Landing page
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https://doi.org/10.1002/chem.201504568Publisher landing page
- PDF URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.201504568Direct link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
-
bronzeOpen access status per OpenAlex
- OA URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.201504568Direct OA link when available
- Concepts
-
Pyrolysis, Catalysis, Carbon fibers, Porosity, Mesoporous material, Materials science, Specific surface area, Chemical engineering, Nanoparticle, Nanotechnology, Inorganic chemistry, Chemistry, Organic chemistry, Composite material, Composite number, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
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93Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 2, 2024: 3, 2023: 6, 2022: 10, 2021: 9Per-year citation counts (last 5 years)
- References (count)
-
37Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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