A theory for diffusion-controlled reactions within nonequilibrium steady states Article Swipe

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YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.48550/arxiv.2505.22623

We study diffusion-controlled processes in nonequilibrium steady states, where standard rate theory assumptions break down. Using transition path theory, we generalize the relations between reactive probability fluxes and measures of the rate of the reaction. Stochastic thermodynamics analysis reveals how work constrains the enhancement of rates relative to their equilibrium values. An analytically solvable ion pairing model under a strong electric field illustrates and validates our approach and theory. These findings provide deeper insights into diffusion-controlled reaction dynamics beyond equilibrium.

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Type: preprint
Language: en
Landing Page: http://arxiv.org/abs/2505.22623
PDF: https://arxiv.org/pdf/2505.22623
OA Status: green
OpenAlex ID: https://openalex.org/W4414854748

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OpenAlex ID: https://openalex.org/W4414854748

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DOI: https://doi.org/10.48550/arxiv.2505.22623

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Title: A theory for diffusion-controlled reactions within nonequilibrium steady states

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Type: preprint

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Language: en

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Publication year: 2025

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Publication date: 2025-05-28

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Authors: Seokjin Moon, David T. Limmer

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Landing page: https://arxiv.org/abs/2505.22623

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PDF URL: https://arxiv.org/pdf/2505.22623

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Open access: Yes

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OA status: green

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OA URL: https://arxiv.org/pdf/2505.22623

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Cited by: 0

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