Accelerated Synthesis and Discovery of Covalent Organic Framework Photocatalysts for Hydrogen Peroxide Production Article Swipe

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Wei Zhao , Peiyao Yan , Boyu Li , Mounib Bahri , Lunjie Liu , Xiang Zhou , Rob Clowes , Nigel D. Browning , Yue Wu , John W. Ward , Andrew I. Cooper ·

YOU? · · 2022 · Open Access · · DOI: https://doi.org/10.1021/jacs.2c02666

A high-throughput sonochemical synthesis and testing strategy was developed to discover covalent organic frameworks (COFs) for photocatalysis. In total, 76 conjugated polymers were synthesized, including 60 crystalline COFs of which 18 were previously unreported. These COFs were then screened for photocatalytic hydrogen peroxide (H₂O₂) production using water and oxygen. One of these COFs, sonoCOF-F2, was found to be an excellent photocatalyst for photocatalytic H₂O₂ production even in the absence of sacrificial donors. However, after long-term photocatalytic tests (96 h), the imine sonoCOF-F2 transformed into an amide-linked COF with reduced crystallinity and loss of electronic conjugation, decreasing the photocatalytic activity. When benzyl alcohol was introduced to form a two-phase catalytic system, the photostability of sonoCOF-F2 was greatly enhanced, leading to stable H₂O₂ production for at least 1 week.

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Photocatalysis Chemistry Hydrogen peroxide Covalent bond Imine Catalysis Crystallinity Conjugated system Amide Polymer Combinatorial chemistry Photochemistry Organic chemistry Crystallography

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Type: article
Language: en
Landing Page: https://doi.org/10.1021/jacs.2c02666
OA Status: hybrid
Cited By: 470
References: 29
Related Works: 10
OpenAlex ID: https://openalex.org/W4281652983

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DOI: https://doi.org/10.1021/jacs.2c02666

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Title: Accelerated Synthesis and Discovery of Covalent Organic Framework Photocatalysts for Hydrogen Peroxide Production

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Language: en

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Publication year: 2022

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Publication date: 2022-05-30

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Authors: Wei Zhao, Peiyao Yan, Boyu Li, Mounib Bahri, Lunjie Liu, Xiang Zhou, Rob Clowes, Nigel D. Browning, Yue Wu, John W. Ward, Andrew I. Cooper

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Landing page: https://doi.org/10.1021/jacs.2c02666

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Concepts: Photocatalysis, Chemistry, Hydrogen peroxide, Covalent bond, Imine, Catalysis, Crystallinity, Conjugated system, Amide, Polymer, Combinatorial chemistry, Photochemistry, Organic chemistry, Crystallography

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Cited by: 470

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