Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation Article Swipe

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Wanli Zhu , Sheng Zhang , Weigang Fan , Ying Yang , Hongliang Zhao , Wenwen Fei , Hong Bi , Jian He , Man‐Bo Li , Zhikun Wu ·

YOU? · · 2023 · Open Access · · DOI: https://doi.org/10.1021/prechem.3c00003

The emergence of metal nanoclusters with atomically precise compositions and structures provides an opportunity for in-depth investigation of catalysis mechanisms and structure-property correlations at the nanoscale. However, a serious problem for metal nanocluster catalysts is that the ligands inhibit the catalytic activity through deactivating the surface of the nanoclusters. Here, we introduce a novel catalytic mode for metal nanoclusters, in which the nanoclusters initiate the catalysis via single electron transfer (SET) without destroying the integrity of nanoclusters, providing a solution for the contradiction between activity and stability of metal nanoclusters. We illustrated that the novel activation mode featured low catalyst loading (0.01 mol %), high TOF, mild reaction conditions, and easy recycling of catalyst in alkyne hydroborylation, which often suffered from poor selectivity, low functional group tolerance, etc. Furthermore, the catalyst [Au₁Cu₁₄(TBBT)₁₂(PPh₃)₆]⁺ (TBBTH: p-tert-butylthiophenol) can be applied in highly efficient tandem processes such as hydroborylation-deuteration and hydroborylation-isomerization, demonstrating the utility of the introduced activation mode for metal nanoclusters.

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Nanoclusters Catalysis Metal Materials science Isomerization Nanotechnology Photochemistry Chemistry Chemical engineering Organic chemistry Metallurgy Engineering

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Type: article
Language: en
Landing Page: https://doi.org/10.1021/prechem.3c00003
OA Status: diamond
Cited By: 20
References: 46
Related Works: 10
OpenAlex ID: https://openalex.org/W4323039615

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OpenAlex ID: https://openalex.org/W4323039615

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DOI: https://doi.org/10.1021/prechem.3c00003

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Title: Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation

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Type: article

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Language: en

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Publication year: 2023

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Publication date: 2023-03-03

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Authors: Wanli Zhu, Sheng Zhang, Weigang Fan, Ying Yang, Hongliang Zhao, Wenwen Fei, Hong Bi, Jian He, Man‐Bo Li, Zhikun Wu

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Landing page: https://doi.org/10.1021/prechem.3c00003

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Open access: Yes

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OA status: diamond

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OA URL: https://doi.org/10.1021/prechem.3c00003

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Concepts: Nanoclusters, Catalysis, Metal, Materials science, Isomerization, Nanotechnology, Photochemistry, Chemistry, Chemical engineering, Organic chemistry, Metallurgy, Engineering

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Cited by: 20

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Citations by year (recent): 2025: 6, 2024: 13, 2023: 1

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References (count): 46

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Related works (count): 10

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abstract_inverted_index.activation	95, 153
abstract_inverted_index.atomically	6
abstract_inverted_index.destroying	72
abstract_inverted_index.functional	124
abstract_inverted_index.introduced	152
abstract_inverted_index.mechanisms	19
abstract_inverted_index.nanoscale.	25
abstract_inverted_index.structures	10
abstract_inverted_index.tolerance,	126
abstract_inverted_index.conditions,	108
abstract_inverted_index.illustrated	91
abstract_inverted_index.nanocluster	32
abstract_inverted_index.opportunity	13
abstract_inverted_index.Furthermore,	128
abstract_inverted_index.compositions	8
abstract_inverted_index.correlations	22
abstract_inverted_index.deactivating	43
abstract_inverted_index.nanoclusters	4, 62
abstract_inverted_index.selectivity,	122
abstract_inverted_index.contradiction	82
abstract_inverted_index.demonstrating	147
abstract_inverted_index.investigation	16
abstract_inverted_index.nanoclusters,	58, 76
abstract_inverted_index.nanoclusters.	48, 89, 157
abstract_inverted_index.hydroborylation,	116
abstract_inverted_index.structure-property	21
abstract_inverted_index.hydroborylation-deuteration	144
abstract_inverted_index.hydroborylation-isomerization,	146
abstract_inverted_index.<i>p</i>-<i>tert</i>-butylthiophenol)	133
abstract_inverted_index.[Au<sub>1</sub>Cu<sub>14</sub>(TBBT)<sub>12</sub>(PPh<sub>3</sub>)<sub>6</sub>]<sup>+</sup>	131
cited_by_percentile_year.max	99
cited_by_percentile_year.min	89
corresponding_author_ids	https://openalex.org/A5071069893, https://openalex.org/A5012795350
countries_distinct_count	2
institutions_distinct_count	10
corresponding_institution_ids	https://openalex.org/I143868143, https://openalex.org/I19820366, https://openalex.org/I4210154057
citation_normalized_percentile.value	0.88257159
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	True