Binary Metallic CuCo5S8 Anode for High Volumetric Sodium‐Ion Storage Article Swipe
Da Hui
,
Jingyi Liu
,
Feilong L. Pan
,
Nan Chen
,
Zhixuan Wei
,
Yi Zeng
,
Shiyu Yao
,
Fei Du
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/chem.202302244
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/chem.202302244
With the rapid improvement of compact smart devices, fabricating anode materials with high volumetric capacity has gained substantial interest for future sodium‐ion batteries (SIBs) applications. Herein, a novel bimetal sulfide CuCo 5 S 8 material is proposed with enhanced volumetric capacity due to the intrinsic metallic electronic conductivity of the material and multi‐electron transfer during electrochemical procedures. Due to the intrinsic metallic behavior, the conducting additive (CA) could be removed from the electrode fabrication without scarifying the high rate capability. The CA‐free CuCo 5 S 8 electrode can achieve a high volumetric capacity of 1436.4 mA h cm −3 at a current density of 0.2 A g −1 and 100 % capacity retention over 2000 cycles in SIBs, outperforming most metal chalcogenides, owing to the enhanced electrode density. Reversible conversion reactions are revealed by combined measurements for sodium systems. The proposed new strategy offers a viable approach for developing innovative anode materials with high‐volumetric capacity.
Related Topics
Concepts
Anode
Bimetal
Materials science
Electrode
Electrochemistry
Fabrication
Battery (electricity)
Metal
Sulfide
Sodium
Current density
Sodium-ion battery
Chemical engineering
Optoelectronics
Nanotechnology
Composite material
Metallurgy
Chemistry
Thermodynamics
Alternative medicine
Power (physics)
Faraday efficiency
Physical chemistry
Pathology
Quantum mechanics
Medicine
Physics
Engineering
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/chem.202302244
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.202302244
- OA Status
- bronze
- Cited By
- 1
- References
- 62
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4386047058
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4386047058Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/chem.202302244Digital Object Identifier
- Title
-
Binary Metallic CuCo5S8 Anode for High Volumetric Sodium‐Ion StorageWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2023Year of publication
- Publication date
-
2023-08-21Full publication date if available
- Authors
-
Da Hui, Jingyi Liu, Feilong L. Pan, Nan Chen, Zhixuan Wei, Yi Zeng, Shiyu Yao, Fei DuList of authors in order
- Landing page
-
https://doi.org/10.1002/chem.202302244Publisher landing page
- PDF URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.202302244Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
bronzeOpen access status per OpenAlex
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-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/chem.202302244Direct OA link when available
- Concepts
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Anode, Bimetal, Materials science, Electrode, Electrochemistry, Fabrication, Battery (electricity), Metal, Sulfide, Sodium, Current density, Sodium-ion battery, Chemical engineering, Optoelectronics, Nanotechnology, Composite material, Metallurgy, Chemistry, Thermodynamics, Alternative medicine, Power (physics), Faraday efficiency, Physical chemistry, Pathology, Quantum mechanics, Medicine, Physics, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
1Total citation count in OpenAlex
- Citations by year (recent)
-
2024: 1Per-year citation counts (last 5 years)
- References (count)
-
62Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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