Binding Modes of High Stoichiometry Guest Complexes with a Co8L12 Cage Uncovered by Mass Spectrometry Article Swipe
Related Concepts
Stoichiometry
Cage
Mass spectrometry
Chemistry
Binding site
Crystallography
Chromatography
Physical chemistry
Biochemistry
Mathematics
Combinatorics
Daniel L. Stares
,
Cristina Mozaceanu
,
Michael D. Ward
,
Christoph A. Schalley
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2023-98j7g
· OA: W4386288078
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2023-98j7g
· OA: W4386288078
We demonstrate how different modes of guest binding to a Co8L12 cubic cage host can be determined using ESI-MS. High stoichiometry guest binding was observed, with binding modes which showed the guests preferentially binding externally, but internal guest inclusion was also seen at higher guest loading.
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