Chemically Tailored Semiconductor Moiré Superlattices of Janus Heterobilayers Article Swipe
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· 2024
· Open Access
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· DOI: https://doi.org/10.1002/sstr.202300514
Janus monolayers of transition metal dichalcogenides (TMDCs) are promising building blocks for moiré superlattices because of their built‐in electric field and clean fabrication process. In particular, Janus TMDC monolayers can be chemically converted from conventional TMDC monolayers by atomic substitution, enabling the direct formation of lattice‐mismatched heterobilayers from TMDC bilayers. However, the moiré superlattices of Janus heterobilayers have not been studied experimentally. Herein, this work reports the fabrication and characterization of semiconductor moiré superlattices in chemically tailored Janus heterobilayers. The MoSSe/MoSe 2 (or WSSe/WSe 2 ) Janus heterobilayers are prepared by replacing the top layer Se atoms with S atoms in MoSe 2 (or WSe 2 ) bilayer using H 2 plasma treatment. Scanning transmission electron microscopy reveals that an average moiré period of about 14 nm formed due to lattice mismatch resulting from the chalcogen substitutions. The cryogenic photoluminescence spectra show sharp, near‐infrared emissions, which are attributed to excitons trapped by moiré potentials based on comparison with theoretical calculations. The Janus‐based heterostructures provide a long‐period moiré system with built‐in potential even for nontwisted heterobilayers, allowing the functionalization of confined and correlated electron systems.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/sstr.202300514
- OA Status
- gold
- Cited By
- 3
- References
- 71
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4392345732
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4392345732Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/sstr.202300514Digital Object Identifier
- Title
-
Chemically Tailored Semiconductor Moiré Superlattices of Janus HeterobilayersWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
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2024-03-01Full publication date if available
- Authors
-
Wenjin Zhang, Zheng Liu, Hiroshi Nakajo, Soma Aoki, Haonan Wang, Yanlin Wang, Yanlin Gao, Mina Maruyama, Takuto Kawakami, Yasuyuki Makino, Masahiko Kaneda, Tongmin Chen, Kohei Aso, Tomoya Ogawa, Takahiko Endo, Yusuke Nakanishi, Kenji Watanabe, Takashi Taniguchi, Yoshifumi Oshima, Yukiko Yamada‐Takamura, Mikito Koshino, Susumu Okada, Kazunari Matsuda, Toshiaki Kato, Yasumitsu MiyataList of authors in order
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https://doi.org/10.1002/sstr.202300514Publisher landing page
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://doi.org/10.1002/sstr.202300514Direct OA link when available
- Concepts
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Janus, Superlattice, Materials science, Moiré pattern, Semiconductor, Optoelectronics, Nanotechnology, Engineering physics, Optics, PhysicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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3Total citation count in OpenAlex
- Citations by year (recent)
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2025: 3Per-year citation counts (last 5 years)
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71Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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