Chromium and copper dual-doped zinc sulfide nanoparticles: Synthesis, structural, morphological and optical properties Article Swipe

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Annas Al-Sharabi , Ahmed AL-Osta , Adnan Alnehia , Abdel-Basit Al-Odayni ·

YOU? · · 2023 · Open Access · · DOI: https://doi.org/10.1016/j.rio.2023.100534

Copper (Cu) and chromium (Cr) dual-doped zinc sulfide (ZnS) nanoparticles (NPs) were fabricated via a chemical co-precipitation technique at 24±°C without any capping agent used. The obtained metal sulfides were characterize using transmission electron microscope (TEM), scanning electron microscope (SEM),energy-dispersive X-ray (EDX), X-ray diffraction (XRD), ultra-violet/visible (UV–Vis), and thermogravimetric analysis (TGA). The results revealed a Cr, Cu in ZnS lattice, grain size less than 5 nm, and unequal, aggregated spherical particles. Moreover, XRD analyses indicated that the dual ions penetrated the zinc sulfide without changing its cubic structure, the average size was nearly in the range 2.035–1.959 nm. Optical analysis displayed blue-shift after doping. The band gap values(Eg) were in the range of 4.79–4.89 eV. Thermal analysis shows that the synthesized sample is more stable in range 434–1029 °C. Based on these featured, it could be concluded that the synthesized Cu and Cr dual-doped ZnS NPs are beneficial for opto-electronic devices, and photocatalytic applications.

Related Topics

Zinc Sulfide

Materials Science

Chromium

Scanning Electron Microscope

Thermogravimetric Analysis

Nanoparticle

Copper

Transmission Electron Microscopy

Concepts

Zinc sulfide Materials science Zinc Chromium Scanning electron microscope Thermogravimetric analysis Nanoparticle Copper Sulfide Doping Transmission electron microscopy Copper sulfide Band gap Analytical Chemistry (journal) Photocatalysis Nuclear chemistry Chemical engineering Nanotechnology Metallurgy Chemistry Composite material Optoelectronics Organic chemistry Engineering Catalysis

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Type: article
Language: en
Landing Page: https://doi.org/10.1016/j.rio.2023.100534
OA Status: gold
Cited By: 9
References: 54
Related Works: 10
OpenAlex ID: https://openalex.org/W4386947336

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DOI: https://doi.org/10.1016/j.rio.2023.100534

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Title: Chromium and copper dual-doped zinc sulfide nanoparticles: Synthesis, structural, morphological and optical properties

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Language: en

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Publication year: 2023

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Publication date: 2023-09-22

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Authors: Annas Al-Sharabi, Ahmed AL-Osta, Adnan Alnehia, Abdel-Basit Al-Odayni

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Landing page: https://doi.org/10.1016/j.rio.2023.100534

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Concepts: Zinc sulfide, Materials science, Zinc, Chromium, Scanning electron microscope, Thermogravimetric analysis, Nanoparticle, Copper, Sulfide, Doping, Transmission electron microscopy, Copper sulfide, Band gap, Analytical Chemistry (journal), Photocatalysis, Nuclear chemistry, Chemical engineering, Nanotechnology, Metallurgy, Chemistry, Composite material, Optoelectronics, Organic chemistry, Engineering, Catalysis

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Cited by: 9

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