Closed-loop recycling of semi-aromatic polyesters upcycled from poly(ethylene terephthalate) Article Swipe
Jeffrey C. Foster
,
Jackie Zheng
,
Md Arifuzzaman
,
Md Anisur Rahman
,
Joshua T. Damron
,
Chao Guan
,
Ilja Popovs
,
Nick Galan
,
Zoriana Demchuk
,
Tomonori Saito
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1016/j.xcrp.2023.101734
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1016/j.xcrp.2023.101734
Plastics are critical in facilitating the comfort and quality of everyday life. Most plastics are discarded after a single use, wasting the energy and carbon consumed for their production and incurring environmental costs. Thus, closed-loop production and recycling processes are needed to mitigate energy and carbon loss toward a net-zero carbon economy. Here, we show that poly(ethylene terephthalate) (PET) can be efficiently deconstructed into small-molecule α,ω-dialkenenyl terephthalates using organocatalyzed transesterification. The resulting compounds can be polymerized by acyclic diene metathesis (ADMET) polymerization, affording unsaturated semi-aromatic polyesters with thermomechanical properties dependent on the monomer structure and the catalyst used for their synthesis. High-molecular-weight ADMET polymers form free-standing films that are ductile and tough with mechanical properties similar to widely used commodity plastics. Crucially, the ADMET polymers can be deconstructed to monomers using Retro-ADMET and re-polymerized by ADMET polymerization, establishing closed-loop circularity for a unique class of materials.
Related Topics
Concepts
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.xcrp.2023.101734
- OA Status
- gold
- Cited By
- 7
- References
- 50
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4389687611
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W4389687611Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1016/j.xcrp.2023.101734Digital Object Identifier
- Title
-
Closed-loop recycling of semi-aromatic polyesters upcycled from poly(ethylene terephthalate)Work title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2023Year of publication
- Publication date
-
2023-12-01Full publication date if available
- Authors
-
Jeffrey C. Foster, Jackie Zheng, Md Arifuzzaman, Md Anisur Rahman, Joshua T. Damron, Chao Guan, Ilja Popovs, Nick Galan, Zoriana Demchuk, Tomonori SaitoList of authors in order
- Landing page
-
https://doi.org/10.1016/j.xcrp.2023.101734Publisher landing page
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://doi.org/10.1016/j.xcrp.2023.101734Direct OA link when available
- Concepts
-
Polyester, Polymerization, Monomer, Materials science, Polymer, Ethylene, Lactide, Metathesis, Transesterification, Carbon fibers, Chemical engineering, Organic chemistry, Polymer chemistry, Catalysis, Polymer science, Chemistry, Composite material, Engineering, Composite numberTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
7Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 6, 2024: 1Per-year citation counts (last 5 years)
- References (count)
-
50Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W4389687611 |
|---|---|
| doi | https://doi.org/10.1016/j.xcrp.2023.101734 |
| ids.doi | https://doi.org/10.1016/j.xcrp.2023.101734 |
| ids.openalex | https://openalex.org/W4389687611 |
| fwci | 0.98806686 |
| type | article |
| title | Closed-loop recycling of semi-aromatic polyesters upcycled from poly(ethylene terephthalate) |
| biblio.issue | 12 |
| biblio.volume | 4 |
| biblio.last_page | 101734 |
| biblio.first_page | 101734 |
| topics[0].id | https://openalex.org/T10661 |
| topics[0].field.id | https://openalex.org/fields/25 |
| topics[0].field.display_name | Materials Science |
| topics[0].score | 0.9997000098228455 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/2502 |
| topics[0].subfield.display_name | Biomaterials |
| topics[0].display_name | biodegradable polymer synthesis and properties |
| topics[1].id | https://openalex.org/T11549 |
| topics[1].field.id | https://openalex.org/fields/16 |
| topics[1].field.display_name | Chemistry |
| topics[1].score | 0.9972000122070312 |
| topics[1].domain.id | https://openalex.org/domains/3 |
| topics[1].domain.display_name | Physical Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/1605 |
| topics[1].subfield.display_name | Organic Chemistry |
| topics[1].display_name | Synthetic Organic Chemistry Methods |
| topics[2].id | https://openalex.org/T11593 |
| topics[2].field.id | https://openalex.org/fields/15 |
| topics[2].field.display_name | Chemical Engineering |
| topics[2].score | 0.9922000169754028 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/1508 |
| topics[2].subfield.display_name | Process Chemistry and Technology |
| topics[2].display_name | Carbon dioxide utilization in catalysis |
| funders[0].id | https://openalex.org/F4320306084 |
| funders[0].ror | https://ror.org/01bj3aw27 |
| funders[0].display_name | U.S. Department of Energy |
| funders[1].id | https://openalex.org/F4320316892 |
| funders[1].ror | https://ror.org/04nza6677 |
| funders[1].display_name | UT-Battelle |
| funders[2].id | https://openalex.org/F4320332359 |
| funders[2].ror | https://ror.org/00mmn6b08 |
| funders[2].display_name | Office of Science |
| funders[3].id | https://openalex.org/F4320337480 |
| funders[3].ror | https://ror.org/05mg91w61 |
| funders[3].display_name | Basic Energy Sciences |
| funders[4].id | https://openalex.org/F4320338483 |
| funders[4].ror | |
| funders[4].display_name | Division of Materials Sciences and Engineering |
| is_xpac | False |
| apc_list.value | 5200 |
| apc_list.currency | USD |
| apc_list.value_usd | 5200 |
| apc_paid.value | 5200 |
| apc_paid.currency | USD |
| apc_paid.value_usd | 5200 |
| concepts[0].id | https://openalex.org/C119394753 |
| concepts[0].level | 2 |
| concepts[0].score | 0.7952176928520203 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q188245 |
| concepts[0].display_name | Polyester |
| concepts[1].id | https://openalex.org/C44228677 |
| concepts[1].level | 3 |
| concepts[1].score | 0.6875001192092896 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q181898 |
| concepts[1].display_name | Polymerization |
| concepts[2].id | https://openalex.org/C166940927 |
| concepts[2].level | 3 |
| concepts[2].score | 0.6578750610351562 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q178827 |
| concepts[2].display_name | Monomer |
| concepts[3].id | https://openalex.org/C192562407 |
| concepts[3].level | 0 |
| concepts[3].score | 0.6162797808647156 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q228736 |
| concepts[3].display_name | Materials science |
| concepts[4].id | https://openalex.org/C521977710 |
| concepts[4].level | 2 |
| concepts[4].score | 0.610864520072937 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q81163 |
| concepts[4].display_name | Polymer |
| concepts[5].id | https://openalex.org/C2778597550 |
| concepts[5].level | 3 |
| concepts[5].score | 0.5156341791152954 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q151313 |
| concepts[5].display_name | Ethylene |
| concepts[6].id | https://openalex.org/C2776743539 |
| concepts[6].level | 4 |
| concepts[6].score | 0.4876748323440552 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q421313 |
| concepts[6].display_name | Lactide |
| concepts[7].id | https://openalex.org/C153914509 |
| concepts[7].level | 4 |
| concepts[7].score | 0.47550779581069946 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q191090 |
| concepts[7].display_name | Metathesis |
| concepts[8].id | https://openalex.org/C2777241282 |
| concepts[8].level | 3 |
| concepts[8].score | 0.47162890434265137 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q591576 |
| concepts[8].display_name | Transesterification |
| concepts[9].id | https://openalex.org/C140205800 |
| concepts[9].level | 3 |
| concepts[9].score | 0.44854092597961426 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q5860 |
| concepts[9].display_name | Carbon fibers |
| concepts[10].id | https://openalex.org/C42360764 |
| concepts[10].level | 1 |
| concepts[10].score | 0.4010152816772461 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q83588 |
| concepts[10].display_name | Chemical engineering |
| concepts[11].id | https://openalex.org/C178790620 |
| concepts[11].level | 1 |
| concepts[11].score | 0.39756056666374207 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[11].display_name | Organic chemistry |
| concepts[12].id | https://openalex.org/C188027245 |
| concepts[12].level | 1 |
| concepts[12].score | 0.38548243045806885 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q750446 |
| concepts[12].display_name | Polymer chemistry |
| concepts[13].id | https://openalex.org/C161790260 |
| concepts[13].level | 2 |
| concepts[13].score | 0.3564099371433258 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q82264 |
| concepts[13].display_name | Catalysis |
| concepts[14].id | https://openalex.org/C126348684 |
| concepts[14].level | 1 |
| concepts[14].score | 0.34980013966560364 |
| concepts[14].wikidata | https://www.wikidata.org/wiki/Q3456979 |
| concepts[14].display_name | Polymer science |
| concepts[15].id | https://openalex.org/C185592680 |
| concepts[15].level | 0 |
| concepts[15].score | 0.2730472683906555 |
| concepts[15].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[15].display_name | Chemistry |
| concepts[16].id | https://openalex.org/C159985019 |
| concepts[16].level | 1 |
| concepts[16].score | 0.20089414715766907 |
| concepts[16].wikidata | https://www.wikidata.org/wiki/Q181790 |
| concepts[16].display_name | Composite material |
| concepts[17].id | https://openalex.org/C127413603 |
| concepts[17].level | 0 |
| concepts[17].score | 0.0 |
| concepts[17].wikidata | https://www.wikidata.org/wiki/Q11023 |
| concepts[17].display_name | Engineering |
| concepts[18].id | https://openalex.org/C104779481 |
| concepts[18].level | 2 |
| concepts[18].score | 0.0 |
| concepts[18].wikidata | https://www.wikidata.org/wiki/Q50707 |
| concepts[18].display_name | Composite number |
| keywords[0].id | https://openalex.org/keywords/polyester |
| keywords[0].score | 0.7952176928520203 |
| keywords[0].display_name | Polyester |
| keywords[1].id | https://openalex.org/keywords/polymerization |
| keywords[1].score | 0.6875001192092896 |
| keywords[1].display_name | Polymerization |
| keywords[2].id | https://openalex.org/keywords/monomer |
| keywords[2].score | 0.6578750610351562 |
| keywords[2].display_name | Monomer |
| keywords[3].id | https://openalex.org/keywords/materials-science |
| keywords[3].score | 0.6162797808647156 |
| keywords[3].display_name | Materials science |
| keywords[4].id | https://openalex.org/keywords/polymer |
| keywords[4].score | 0.610864520072937 |
| keywords[4].display_name | Polymer |
| keywords[5].id | https://openalex.org/keywords/ethylene |
| keywords[5].score | 0.5156341791152954 |
| keywords[5].display_name | Ethylene |
| keywords[6].id | https://openalex.org/keywords/lactide |
| keywords[6].score | 0.4876748323440552 |
| keywords[6].display_name | Lactide |
| keywords[7].id | https://openalex.org/keywords/metathesis |
| keywords[7].score | 0.47550779581069946 |
| keywords[7].display_name | Metathesis |
| keywords[8].id | https://openalex.org/keywords/transesterification |
| keywords[8].score | 0.47162890434265137 |
| keywords[8].display_name | Transesterification |
| keywords[9].id | https://openalex.org/keywords/carbon-fibers |
| keywords[9].score | 0.44854092597961426 |
| keywords[9].display_name | Carbon fibers |
| keywords[10].id | https://openalex.org/keywords/chemical-engineering |
| keywords[10].score | 0.4010152816772461 |
| keywords[10].display_name | Chemical engineering |
| keywords[11].id | https://openalex.org/keywords/organic-chemistry |
| keywords[11].score | 0.39756056666374207 |
| keywords[11].display_name | Organic chemistry |
| keywords[12].id | https://openalex.org/keywords/polymer-chemistry |
| keywords[12].score | 0.38548243045806885 |
| keywords[12].display_name | Polymer chemistry |
| keywords[13].id | https://openalex.org/keywords/catalysis |
| keywords[13].score | 0.3564099371433258 |
| keywords[13].display_name | Catalysis |
| keywords[14].id | https://openalex.org/keywords/polymer-science |
| keywords[14].score | 0.34980013966560364 |
| keywords[14].display_name | Polymer science |
| keywords[15].id | https://openalex.org/keywords/chemistry |
| keywords[15].score | 0.2730472683906555 |
| keywords[15].display_name | Chemistry |
| keywords[16].id | https://openalex.org/keywords/composite-material |
| keywords[16].score | 0.20089414715766907 |
| keywords[16].display_name | Composite material |
| language | en |
| locations[0].id | doi:10.1016/j.xcrp.2023.101734 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S4210216867 |
| locations[0].source.issn | 2666-3864 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | True |
| locations[0].source.issn_l | 2666-3864 |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | True |
| locations[0].source.display_name | Cell Reports Physical Science |
| locations[0].source.host_organization | https://openalex.org/P4310320990 |
| locations[0].source.host_organization_name | Elsevier BV |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310320990 |
| locations[0].source.host_organization_lineage_names | Elsevier BV |
| locations[0].license | cc-by-nc-nd |
| locations[0].pdf_url | |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | https://openalex.org/licenses/cc-by-nc-nd |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | Cell Reports Physical Science |
| locations[0].landing_page_url | https://doi.org/10.1016/j.xcrp.2023.101734 |
| locations[1].id | pmh:oai:osti.gov:2229819 |
| locations[1].is_oa | True |
| locations[1].source.id | https://openalex.org/S4306402487 |
| locations[1].source.issn | |
| locations[1].source.type | repository |
| locations[1].source.is_oa | False |
| locations[1].source.issn_l | |
| locations[1].source.is_core | False |
| locations[1].source.is_in_doaj | False |
| locations[1].source.display_name | OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) |
| locations[1].source.host_organization | https://openalex.org/I139351228 |
| locations[1].source.host_organization_name | Office of Scientific and Technical Information |
| locations[1].source.host_organization_lineage | https://openalex.org/I139351228 |
| locations[1].license | |
| locations[1].pdf_url | |
| locations[1].version | submittedVersion |
| locations[1].raw_type | |
| locations[1].license_id | |
| locations[1].is_accepted | False |
| locations[1].is_published | False |
| locations[1].raw_source_name | |
| locations[1].landing_page_url | https://www.osti.gov/biblio/2229819 |
| locations[2].id | pmh:oai:osti.gov:2281145 |
| locations[2].is_oa | True |
| locations[2].source.id | https://openalex.org/S4306402487 |
| locations[2].source.issn | |
| locations[2].source.type | repository |
| locations[2].source.is_oa | False |
| locations[2].source.issn_l | |
| locations[2].source.is_core | False |
| locations[2].source.is_in_doaj | False |
| locations[2].source.display_name | OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) |
| locations[2].source.host_organization | https://openalex.org/I139351228 |
| locations[2].source.host_organization_name | Office of Scientific and Technical Information |
| locations[2].source.host_organization_lineage | https://openalex.org/I139351228 |
| locations[2].license | |
| locations[2].pdf_url | |
| locations[2].version | submittedVersion |
| locations[2].raw_type | |
| locations[2].license_id | |
| locations[2].is_accepted | False |
| locations[2].is_published | False |
| locations[2].raw_source_name | |
| locations[2].landing_page_url | https://www.osti.gov/biblio/2281145 |
| indexed_in | crossref, doaj |
| authorships[0].author.id | https://openalex.org/A5054366623 |
| authorships[0].author.orcid | https://orcid.org/0000-0002-9097-8680 |
| authorships[0].author.display_name | Jeffrey C. Foster |
| authorships[0].countries | US |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[0].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[0].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[0].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[0].institutions[0].type | facility |
| authorships[0].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[0].institutions[0].country_code | US |
| authorships[0].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Jeffrey C. Foster |
| authorships[0].is_corresponding | True |
| authorships[0].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[1].author.id | https://openalex.org/A5008239903 |
| authorships[1].author.orcid | |
| authorships[1].author.display_name | Jackie Zheng |
| authorships[1].countries | US |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I75027704 |
| authorships[1].affiliations[0].raw_affiliation_string | The Bredesen Center for Interdisciplinary Research and Graduate Education, University of Tennessee, Knoxville, TN 37996, USA |
| authorships[1].institutions[0].id | https://openalex.org/I75027704 |
| authorships[1].institutions[0].ror | https://ror.org/020f3ap87 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I75027704 |
| authorships[1].institutions[0].country_code | US |
| authorships[1].institutions[0].display_name | University of Tennessee at Knoxville |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Jackie Zheng |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | The Bredesen Center for Interdisciplinary Research and Graduate Education, University of Tennessee, Knoxville, TN 37996, USA |
| authorships[2].author.id | https://openalex.org/A5027584079 |
| authorships[2].author.orcid | https://orcid.org/0000-0003-3056-8636 |
| authorships[2].author.display_name | Md Arifuzzaman |
| authorships[2].countries | US |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[2].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[2].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[2].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[2].institutions[0].type | facility |
| authorships[2].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[2].institutions[0].country_code | US |
| authorships[2].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Md Arifuzzaman |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[3].author.id | https://openalex.org/A5091847201 |
| authorships[3].author.orcid | https://orcid.org/0000-0002-7190-9751 |
| authorships[3].author.display_name | Md Anisur Rahman |
| authorships[3].countries | US |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[3].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[3].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[3].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[3].institutions[0].type | facility |
| authorships[3].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[3].institutions[0].country_code | US |
| authorships[3].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Md Anisur Rahman |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[4].author.id | https://openalex.org/A5071143092 |
| authorships[4].author.orcid | https://orcid.org/0000-0003-3409-0190 |
| authorships[4].author.display_name | Joshua T. Damron |
| authorships[4].countries | US |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[4].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[4].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[4].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[4].institutions[0].type | facility |
| authorships[4].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[4].institutions[0].country_code | US |
| authorships[4].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Joshua T. Damron |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[5].author.id | https://openalex.org/A5026994176 |
| authorships[5].author.orcid | https://orcid.org/0000-0002-9430-3488 |
| authorships[5].author.display_name | Chao Guan |
| authorships[5].countries | US |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[5].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[5].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[5].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[5].institutions[0].type | facility |
| authorships[5].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[5].institutions[0].country_code | US |
| authorships[5].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[5].author_position | middle |
| authorships[5].raw_author_name | Chao Guan |
| authorships[5].is_corresponding | False |
| authorships[5].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[6].author.id | https://openalex.org/A5044457875 |
| authorships[6].author.orcid | https://orcid.org/0000-0002-9767-3353 |
| authorships[6].author.display_name | Ilja Popovs |
| authorships[6].countries | US |
| authorships[6].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[6].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[6].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[6].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[6].institutions[0].type | facility |
| authorships[6].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[6].institutions[0].country_code | US |
| authorships[6].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[6].author_position | middle |
| authorships[6].raw_author_name | Ilja Popovs |
| authorships[6].is_corresponding | False |
| authorships[6].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[7].author.id | https://openalex.org/A5093483995 |
| authorships[7].author.orcid | |
| authorships[7].author.display_name | Nick Galan |
| authorships[7].countries | US |
| authorships[7].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[7].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[7].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[7].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[7].institutions[0].type | facility |
| authorships[7].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[7].institutions[0].country_code | US |
| authorships[7].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[7].author_position | middle |
| authorships[7].raw_author_name | Nick Galan |
| authorships[7].is_corresponding | False |
| authorships[7].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[8].author.id | https://openalex.org/A5069308042 |
| authorships[8].author.orcid | https://orcid.org/0000-0003-2629-2235 |
| authorships[8].author.display_name | Zoriana Demchuk |
| authorships[8].countries | US |
| authorships[8].affiliations[0].institution_ids | https://openalex.org/I1289243028 |
| authorships[8].affiliations[0].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[8].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[8].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[8].institutions[0].type | facility |
| authorships[8].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[8].institutions[0].country_code | US |
| authorships[8].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[8].author_position | middle |
| authorships[8].raw_author_name | Zoriana Demchuk |
| authorships[8].is_corresponding | False |
| authorships[8].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[9].author.id | https://openalex.org/A5026783306 |
| authorships[9].author.orcid | https://orcid.org/0000-0002-4536-7530 |
| authorships[9].author.display_name | Tomonori Saito |
| authorships[9].countries | US |
| authorships[9].affiliations[0].institution_ids | https://openalex.org/I75027704 |
| authorships[9].affiliations[0].raw_affiliation_string | The Bredesen Center for Interdisciplinary Research and Graduate Education, University of Tennessee, Knoxville, TN 37996, USA |
| authorships[9].affiliations[1].institution_ids | https://openalex.org/I1289243028 |
| authorships[9].affiliations[1].raw_affiliation_string | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA |
| authorships[9].institutions[0].id | https://openalex.org/I1289243028 |
| authorships[9].institutions[0].ror | https://ror.org/01qz5mb56 |
| authorships[9].institutions[0].type | facility |
| authorships[9].institutions[0].lineage | https://openalex.org/I1289243028, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I4210159294 |
| authorships[9].institutions[0].country_code | US |
| authorships[9].institutions[0].display_name | Oak Ridge National Laboratory |
| authorships[9].institutions[1].id | https://openalex.org/I75027704 |
| authorships[9].institutions[1].ror | https://ror.org/020f3ap87 |
| authorships[9].institutions[1].type | education |
| authorships[9].institutions[1].lineage | https://openalex.org/I75027704 |
| authorships[9].institutions[1].country_code | US |
| authorships[9].institutions[1].display_name | University of Tennessee at Knoxville |
| authorships[9].author_position | last |
| authorships[9].raw_author_name | Tomonori Saito |
| authorships[9].is_corresponding | True |
| authorships[9].raw_affiliation_strings | Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA, The Bredesen Center for Interdisciplinary Research and Graduate Education, University of Tennessee, Knoxville, TN 37996, USA |
| has_content.pdf | False |
| has_content.grobid_xml | False |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://doi.org/10.1016/j.xcrp.2023.101734 |
| open_access.oa_status | gold |
| open_access.any_repository_has_fulltext | False |
| created_date | 2025-10-10T00:00:00 |
| display_name | Closed-loop recycling of semi-aromatic polyesters upcycled from poly(ethylene terephthalate) |
| has_fulltext | False |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T10661 |
| primary_topic.field.id | https://openalex.org/fields/25 |
| primary_topic.field.display_name | Materials Science |
| primary_topic.score | 0.9997000098228455 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/2502 |
| primary_topic.subfield.display_name | Biomaterials |
| primary_topic.display_name | biodegradable polymer synthesis and properties |
| related_works | https://openalex.org/W2355985250, https://openalex.org/W2151247174, https://openalex.org/W2348803601, https://openalex.org/W2626433236, https://openalex.org/W4249838083, https://openalex.org/W2333598093, https://openalex.org/W2369804782, https://openalex.org/W2976637636, https://openalex.org/W2068210661, https://openalex.org/W2800077356 |
| cited_by_count | 7 |
| counts_by_year[0].year | 2025 |
| counts_by_year[0].cited_by_count | 6 |
| counts_by_year[1].year | 2024 |
| counts_by_year[1].cited_by_count | 1 |
| locations_count | 3 |
| best_oa_location.id | doi:10.1016/j.xcrp.2023.101734 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S4210216867 |
| best_oa_location.source.issn | 2666-3864 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | True |
| best_oa_location.source.issn_l | 2666-3864 |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | True |
| best_oa_location.source.display_name | Cell Reports Physical Science |
| best_oa_location.source.host_organization | https://openalex.org/P4310320990 |
| best_oa_location.source.host_organization_name | Elsevier BV |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310320990 |
| best_oa_location.source.host_organization_lineage_names | Elsevier BV |
| best_oa_location.license | cc-by-nc-nd |
| best_oa_location.pdf_url | |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | https://openalex.org/licenses/cc-by-nc-nd |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | Cell Reports Physical Science |
| best_oa_location.landing_page_url | https://doi.org/10.1016/j.xcrp.2023.101734 |
| primary_location.id | doi:10.1016/j.xcrp.2023.101734 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S4210216867 |
| primary_location.source.issn | 2666-3864 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | True |
| primary_location.source.issn_l | 2666-3864 |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | True |
| primary_location.source.display_name | Cell Reports Physical Science |
| primary_location.source.host_organization | https://openalex.org/P4310320990 |
| primary_location.source.host_organization_name | Elsevier BV |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310320990 |
| primary_location.source.host_organization_lineage_names | Elsevier BV |
| primary_location.license | cc-by-nc-nd |
| primary_location.pdf_url | |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | https://openalex.org/licenses/cc-by-nc-nd |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | Cell Reports Physical Science |
| primary_location.landing_page_url | https://doi.org/10.1016/j.xcrp.2023.101734 |
| publication_date | 2023-12-01 |
| publication_year | 2023 |
| referenced_works | https://openalex.org/W3123866115, https://openalex.org/W2621679044, https://openalex.org/W4324130041, https://openalex.org/W2896839961, https://openalex.org/W3185856877, https://openalex.org/W4305040595, https://openalex.org/W3112078479, https://openalex.org/W3162093860, https://openalex.org/W4385186681, https://openalex.org/W4298088356, https://openalex.org/W4214776853, https://openalex.org/W3121051028, https://openalex.org/W4283781873, https://openalex.org/W4284667159, https://openalex.org/W1964285425, https://openalex.org/W2060555295, https://openalex.org/W4307228151, https://openalex.org/W6665823542, https://openalex.org/W1978903633, https://openalex.org/W1980482262, https://openalex.org/W2159905107, https://openalex.org/W6684247704, https://openalex.org/W2147409350, https://openalex.org/W2109169221, https://openalex.org/W2345451978, https://openalex.org/W2094331432, https://openalex.org/W2741695479, https://openalex.org/W2951962196, https://openalex.org/W3210027771, https://openalex.org/W3011179685, https://openalex.org/W2121224257, https://openalex.org/W2994881927, https://openalex.org/W2588920172, https://openalex.org/W4362661829, https://openalex.org/W3133455371, https://openalex.org/W2806274231, https://openalex.org/W2320916039, https://openalex.org/W2300793326, https://openalex.org/W4280583620, https://openalex.org/W2131265123, https://openalex.org/W2054171792, https://openalex.org/W2038363471, https://openalex.org/W2059869727, https://openalex.org/W2088649278, https://openalex.org/W2002148165, https://openalex.org/W2762848563, https://openalex.org/W4205644558, https://openalex.org/W3195608265, https://openalex.org/W2164058321, https://openalex.org/W2949382326 |
| referenced_works_count | 50 |
| abstract_inverted_index.a | 17, 48, 141 |
| abstract_inverted_index.be | 60, 74, 126 |
| abstract_inverted_index.by | 76, 134 |
| abstract_inverted_index.in | 3 |
| abstract_inverted_index.of | 9, 144 |
| abstract_inverted_index.on | 90 |
| abstract_inverted_index.to | 41, 116, 128 |
| abstract_inverted_index.we | 53 |
| abstract_inverted_index.The | 70 |
| abstract_inverted_index.and | 7, 23, 29, 36, 44, 94, 110, 132 |
| abstract_inverted_index.are | 1, 14, 39, 108 |
| abstract_inverted_index.can | 59, 73, 125 |
| abstract_inverted_index.for | 26, 98, 140 |
| abstract_inverted_index.the | 5, 21, 91, 95, 122 |
| abstract_inverted_index.Most | 12 |
| abstract_inverted_index.form | 104 |
| abstract_inverted_index.into | 63 |
| abstract_inverted_index.loss | 46 |
| abstract_inverted_index.show | 54 |
| abstract_inverted_index.that | 55, 107 |
| abstract_inverted_index.use, | 19 |
| abstract_inverted_index.used | 97, 118 |
| abstract_inverted_index.with | 86, 112 |
| abstract_inverted_index.(PET) | 58 |
| abstract_inverted_index.ADMET | 102, 123, 135 |
| abstract_inverted_index.Here, | 52 |
| abstract_inverted_index.Thus, | 33 |
| abstract_inverted_index.after | 16 |
| abstract_inverted_index.class | 143 |
| abstract_inverted_index.diene | 78 |
| abstract_inverted_index.films | 106 |
| abstract_inverted_index.life. | 11 |
| abstract_inverted_index.their | 27, 99 |
| abstract_inverted_index.tough | 111 |
| abstract_inverted_index.using | 67, 130 |
| abstract_inverted_index.carbon | 24, 45, 50 |
| abstract_inverted_index.costs. | 32 |
| abstract_inverted_index.energy | 22, 43 |
| abstract_inverted_index.needed | 40 |
| abstract_inverted_index.single | 18 |
| abstract_inverted_index.toward | 47 |
| abstract_inverted_index.unique | 142 |
| abstract_inverted_index.widely | 117 |
| abstract_inverted_index.(ADMET) | 80 |
| abstract_inverted_index.acyclic | 77 |
| abstract_inverted_index.comfort | 6 |
| abstract_inverted_index.ductile | 109 |
| abstract_inverted_index.monomer | 92 |
| abstract_inverted_index.quality | 8 |
| abstract_inverted_index.similar | 115 |
| abstract_inverted_index.wasting | 20 |
| abstract_inverted_index.Plastics | 0 |
| abstract_inverted_index.catalyst | 96 |
| abstract_inverted_index.consumed | 25 |
| abstract_inverted_index.critical | 2 |
| abstract_inverted_index.economy. | 51 |
| abstract_inverted_index.everyday | 10 |
| abstract_inverted_index.mitigate | 42 |
| abstract_inverted_index.monomers | 129 |
| abstract_inverted_index.net-zero | 49 |
| abstract_inverted_index.plastics | 13 |
| abstract_inverted_index.polymers | 103, 124 |
| abstract_inverted_index.affording | 82 |
| abstract_inverted_index.commodity | 119 |
| abstract_inverted_index.compounds | 72 |
| abstract_inverted_index.dependent | 89 |
| abstract_inverted_index.discarded | 15 |
| abstract_inverted_index.incurring | 30 |
| abstract_inverted_index.plastics. | 120 |
| abstract_inverted_index.processes | 38 |
| abstract_inverted_index.recycling | 37 |
| abstract_inverted_index.resulting | 71 |
| abstract_inverted_index.structure | 93 |
| abstract_inverted_index.Crucially, | 121 |
| abstract_inverted_index.materials. | 145 |
| abstract_inverted_index.mechanical | 113 |
| abstract_inverted_index.metathesis | 79 |
| abstract_inverted_index.polyesters | 85 |
| abstract_inverted_index.production | 28, 35 |
| abstract_inverted_index.properties | 88, 114 |
| abstract_inverted_index.synthesis. | 100 |
| abstract_inverted_index.Retro-ADMET | 131 |
| abstract_inverted_index.circularity | 139 |
| abstract_inverted_index.closed-loop | 34, 138 |
| abstract_inverted_index.efficiently | 61 |
| abstract_inverted_index.polymerized | 75 |
| abstract_inverted_index.unsaturated | 83 |
| abstract_inverted_index.establishing | 137 |
| abstract_inverted_index.facilitating | 4 |
| abstract_inverted_index.deconstructed | 62, 127 |
| abstract_inverted_index.environmental | 31 |
| abstract_inverted_index.free-standing | 105 |
| abstract_inverted_index.poly(ethylene | 56 |
| abstract_inverted_index.semi-aromatic | 84 |
| abstract_inverted_index.re-polymerized | 133 |
| abstract_inverted_index.small-molecule | 64 |
| abstract_inverted_index.terephthalate) | 57 |
| abstract_inverted_index.terephthalates | 66 |
| abstract_inverted_index.organocatalyzed | 68 |
| abstract_inverted_index.polymerization, | 81, 136 |
| abstract_inverted_index.thermomechanical | 87 |
| abstract_inverted_index.α,ω-dialkenenyl | 65 |
| abstract_inverted_index.transesterification. | 69 |
| abstract_inverted_index.High-molecular-weight | 101 |
| cited_by_percentile_year.max | 99 |
| cited_by_percentile_year.min | 90 |
| corresponding_author_ids | https://openalex.org/A5026783306, https://openalex.org/A5054366623 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 10 |
| corresponding_institution_ids | https://openalex.org/I1289243028, https://openalex.org/I75027704 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/12 |
| sustainable_development_goals[0].score | 0.5600000023841858 |
| sustainable_development_goals[0].display_name | Responsible consumption and production |
| citation_normalized_percentile.value | 0.70462633 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |