Cobalt-based catalyst for ammonia synthesis under ambient conditions via transient confinement Article Swipe
Keran Lv
,
M. Xu
,
Xin Yang
,
Ching‐Ming Wei
,
Jikai Sun
,
Xu Fang
,
Tie Yu
,
Zhenyu Li
,
Wei Deng
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1038/s41467-025-63145-3
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1038/s41467-025-63145-3
The Haber-Bosch process is used for industrial ammonia production worldwide, and it accounts for ~2% of the global energy consumption and 1.3% anthropogenic carbon footprint. Ammonia synthesis under ambient conditions with minimum carbon emission is highly desired, but it is still in the initial stage. Herein, we report a cobalt-based catalyst for ammonia continuous synthesis under ambient conditions via mechanochemistry. To describe mechanochemistry of ammonia synthesis, density functional theory (DFT) calculation was carried out and a transient confinement was discovered. 5 dual side models with Fe, Co, Ni, Cu, Ag have been set up and the Co dual side model exhibits the highest transient confinement effect with the maximum energy barrier reducing from 1.3 eV to 0.62 eV. The experiment confirmed cobalt powders in mechanochemical synthesis of ammonia showed the highest catalytic activity. By using the Co catalyst, up to 13.7 μmol·gcat-1·h-1 ammonia has been achieved under ambient conditions, and the cobalt-based catalyst can maintain its activity more than 350 h without deactivation. This represents the longest lifespan for ammonia synthesis among all the various methods reported under room temperature and atmospheric pressure to the best of our knowledge, which is also 10 times longer than the recent reported FeCs catalysts via mechanocatalysis under ambient conditions. This study suggests that continuous mechano-synthesis of ammonia under ambient condition is valuable.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1038/s41467-025-63145-3
- https://www.nature.com/articles/s41467-025-63145-3.pdf
- OA Status
- gold
- Cited By
- 2
- References
- 47
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4413449554
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4413449554Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1038/s41467-025-63145-3Digital Object Identifier
- Title
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Cobalt-based catalyst for ammonia synthesis under ambient conditions via transient confinementWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-08-23Full publication date if available
- Authors
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Keran Lv, M. Xu, Xin Yang, Ching‐Ming Wei, Jikai Sun, Xu Fang, Tie Yu, Zhenyu Li, Wei DengList of authors in order
- Landing page
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https://doi.org/10.1038/s41467-025-63145-3Publisher landing page
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https://www.nature.com/articles/s41467-025-63145-3.pdfDirect link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://www.nature.com/articles/s41467-025-63145-3.pdfDirect OA link when available
- Concepts
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Cobalt, Catalysis, Ammonia production, Ammonia, Transient (computer programming), Materials science, Chemical engineering, Chemistry, Inorganic chemistry, Computer science, Organic chemistry, Engineering, Operating systemTop concepts (fields/topics) attached by OpenAlex
- Cited by
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2Total citation count in OpenAlex
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2025: 2Per-year citation counts (last 5 years)
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47Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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