Combustion Characterization and Kinetic Analysis of Mixed Sludge and Lignite Combustion Article Swipe
Yang Sun
,
Hui Sun
,
Tianhua Yang
,
Yiming Zhu
,
Rundong Li
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/acsomega.3c08541
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/acsomega.3c08541
To investigate the feasibility and reaction mechanism of combusting sewage sludge and brown coal in a mixture. Thermal behavior evaluation of combustion characteristics, interactions, and kinetic analysis of sludge-lignite mixture combustion by thermogravimetry (TG). The results showed that the combustion performance of the mixed samples was all in between that of the lignite and sludge samples. The combined combustion index gradually decreased with the increase in sludge mixing. The addition of sludge favors the ignition of the mixture but is not conducive to overall stable combustion. The synergies between the sludges, as assessed by the mass loss curves, are reflected in the ash removal and coke oxidation stages. When the mixture of sludge and lignite is burned at a ratio of 10 wt %, the calorific value can still reach 20.3 MJ/kg, which is only about 4.2% lower than that of burning lignite alone. Application of the kinetic models of FWO, Starink, KAS, and Friedman, in turn, determined a minimum average activation energy of only 132.50 kJ/mol. In addition, the reaction was judged to be a simple complexation reaction by analyzing the thermodynamic parameters (ΔG, ΔS, ΔH, and A), with the combustion process approaching thermodynamic equilibrium and forming stable products. The nucleation model A4.2 can be used as the best reaction mechanism model for sludge-lignite mixed combustion.
Related Topics
Concepts
Combustion
Sewage sludge
Thermogravimetry
Chemistry
Coal
Heat of combustion
Autoignition temperature
Chemical engineering
Ignition system
Waste management
Kinetic energy
Coke
Pulp and paper industry
Thermodynamics
Organic chemistry
Sewage treatment
Inorganic chemistry
Engineering
Physics
Quantum mechanics
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsomega.3c08541
- https://pubs.acs.org/doi/pdf/10.1021/acsomega.3c08541
- OA Status
- gold
- Cited By
- 8
- References
- 31
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4391450467
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4391450467Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsomega.3c08541Digital Object Identifier
- Title
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Combustion Characterization and Kinetic Analysis of Mixed Sludge and Lignite CombustionWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-02-01Full publication date if available
- Authors
-
Yang Sun, Hui Sun, Tianhua Yang, Yiming Zhu, Rundong LiList of authors in order
- Landing page
-
https://doi.org/10.1021/acsomega.3c08541Publisher landing page
- PDF URL
-
https://pubs.acs.org/doi/pdf/10.1021/acsomega.3c08541Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
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https://pubs.acs.org/doi/pdf/10.1021/acsomega.3c08541Direct OA link when available
- Concepts
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Combustion, Sewage sludge, Thermogravimetry, Chemistry, Coal, Heat of combustion, Autoignition temperature, Chemical engineering, Ignition system, Waste management, Kinetic energy, Coke, Pulp and paper industry, Thermodynamics, Organic chemistry, Sewage treatment, Inorganic chemistry, Engineering, Physics, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
8Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 7, 2024: 1Per-year citation counts (last 5 years)
- References (count)
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31Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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