Comment on acp-2022-309 Please check rate constant Article Swipe
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· 2022
· Open Access
·
· DOI: https://doi.org/10.5194/acp-2022-309-rc1
Fires emit sufficient sulfur to affect local and regional air quality and climate. This study analyzes SO2 emission factors and variability in smoke plumes from US wild and agricultural fires, and their relationship to sulfate and hydroxymethanesulfonate (HMS) formation. Observed SO2 emission factors for various fuel types show good agreement with the latest reviews of biomass burning emission factors, producing an emission factor range of 0.47–1.2 g SO2 kg-1 C in the emissions. These emission factors vary with geographic location in a way that suggests that deposition of coal burning emissions and application of sulfur-containing fertilizers likely play a role in the larger observed values, which are primarily associated with agricultural burning. A 0-D box model generally reproduces the observed trends of SO2 and total sulfate (inorganic + organic) in aging wildfire plumes. In many cases, modeled HMS is consistent with the observed organosulfur concentrations. However, a comparison of observed organosulfur and modeled HMS suggests that multiple organosulfur compounds are likely responsible for the observations, but that the chemistry of these compounds yield similar production and loss rates to that of HMS, resulting in good agreement with the modeled results. We provide suggestions for constraining the organosulfur compounds observed during these flights and we show that the chemistry of HMS can allow for organosulfur to act as a S(IV) reservoir under conditions of increased pH (>6) and liquid water content (>10-7 g m-3). This can facilitate long-range transport of sulfur emissions resulting in increased SO2 and eventually sulfate in transported smoke.
Related Topics
- Type
- peer-review
- Language
- en
- Landing Page
- https://doi.org/10.5194/acp-2022-309-rc1
- https://acp.copernicus.org/preprints/acp-2022-309/acp-2022-309.pdf
- OA Status
- gold
- References
- 29
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4280641798
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4280641798Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.5194/acp-2022-309-rc1Digital Object Identifier
- Title
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Comment on acp-2022-309 Please check rate constantWork title
- Type
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peer-reviewOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2022Year of publication
- Publication date
-
2022-05-19Full publication date if available
- Authors
-
Pamela S. Rickly, Hongyu Guo, Pedro Campuzano‐Jost, J. L. Jiménez, Glenn M. Wolfe, Ryan Bennett, Ilann Bourgeois, John D. Crounse, Jack E. Dibb, Joshua P. DiGangi, Glenn S. Diskin, Maximilian Dollner, Emily Gargulinski, Samuel R. Hall, Hannah S. Halliday, T. F. Hanisco, Reem A. Hannun, J. Liao, Richard H. Moore, Benjamin A. Nault, J. B. Nowak, Claire Robinson, Thomas B. Ryerson, Kevin J. Sanchez, Manuel Schöberl, A. J. Soja, Jason M. St. Clair, K. L. Thornhill, Kirk Ullmann, P. O. Wennberg, Bernadett Weinzierl, Elizabeth B. Wiggins, Edward L. Winstead, Andrew W. RollinsList of authors in order
- Landing page
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https://doi.org/10.5194/acp-2022-309-rc1Publisher landing page
- PDF URL
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https://acp.copernicus.org/preprints/acp-2022-309/acp-2022-309.pdfDirect link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
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https://acp.copernicus.org/preprints/acp-2022-309/acp-2022-309.pdfDirect OA link when available
- Concepts
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Organosulfur compounds, Sulfur, Sulfate, Chemistry, Air quality index, Yield (engineering), Environmental science, Environmental chemistry, Coal, Atmospheric sciences, Meteorology, Thermodynamics, Organic chemistry, Geology, Geography, PhysicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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0Total citation count in OpenAlex
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29Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.under | 220 |
| abstract_inverted_index.water | 228 |
| abstract_inverted_index.which | 105 |
| abstract_inverted_index.yield | 172 |
| abstract_inverted_index.(>10-7 | 230 |
| abstract_inverted_index.affect | 5 |
| abstract_inverted_index.cases, | 135 |
| abstract_inverted_index.during | 199 |
| abstract_inverted_index.factor | 62 |
| abstract_inverted_index.fires, | 29 |
| abstract_inverted_index.larger | 102 |
| abstract_inverted_index.latest | 52 |
| abstract_inverted_index.likely | 96, 160 |
| abstract_inverted_index.liquid | 227 |
| abstract_inverted_index.plumes | 23 |
| abstract_inverted_index.smoke. | 250 |
| abstract_inverted_index.sulfur | 3, 239 |
| abstract_inverted_index.trends | 120 |
| abstract_inverted_index.biomass | 55 |
| abstract_inverted_index.burning | 56, 89 |
| abstract_inverted_index.content | 229 |
| abstract_inverted_index.factors | 18, 42, 75 |
| abstract_inverted_index.flights | 201 |
| abstract_inverted_index.modeled | 136, 152, 188 |
| abstract_inverted_index.plumes. | 132 |
| abstract_inverted_index.provide | 191 |
| abstract_inverted_index.quality | 10 |
| abstract_inverted_index.reviews | 53 |
| abstract_inverted_index.similar | 173 |
| abstract_inverted_index.sulfate | 34, 125, 247 |
| abstract_inverted_index.values, | 104 |
| abstract_inverted_index.various | 44 |
| abstract_inverted_index.However, | 145 |
| abstract_inverted_index.Observed | 39 |
| abstract_inverted_index.analyzes | 15 |
| abstract_inverted_index.burning. | 111 |
| abstract_inverted_index.climate. | 12 |
| abstract_inverted_index.emission | 17, 41, 57, 61, 74 |
| abstract_inverted_index.factors, | 58 |
| abstract_inverted_index.location | 79 |
| abstract_inverted_index.multiple | 156 |
| abstract_inverted_index.observed | 103, 119, 142, 149, 198 |
| abstract_inverted_index.organic) | 128 |
| abstract_inverted_index.regional | 8 |
| abstract_inverted_index.results. | 189 |
| abstract_inverted_index.suggests | 84, 154 |
| abstract_inverted_index.wildfire | 131 |
| abstract_inverted_index.agreement | 49, 185 |
| abstract_inverted_index.chemistry | 168, 207 |
| abstract_inverted_index.compounds | 158, 171, 197 |
| abstract_inverted_index.emissions | 90, 240 |
| abstract_inverted_index.generally | 116 |
| abstract_inverted_index.increased | 223, 243 |
| abstract_inverted_index.primarily | 107 |
| abstract_inverted_index.producing | 59 |
| abstract_inverted_index.reservoir | 219 |
| abstract_inverted_index.resulting | 182, 241 |
| abstract_inverted_index.transport | 237 |
| abstract_inverted_index.(inorganic | 126 |
| abstract_inverted_index.0.47–1.2 | 65 |
| abstract_inverted_index.associated | 108 |
| abstract_inverted_index.comparison | 147 |
| abstract_inverted_index.conditions | 221 |
| abstract_inverted_index.consistent | 139 |
| abstract_inverted_index.deposition | 86 |
| abstract_inverted_index.emissions. | 72 |
| abstract_inverted_index.eventually | 246 |
| abstract_inverted_index.facilitate | 235 |
| abstract_inverted_index.formation. | 38 |
| abstract_inverted_index.geographic | 78 |
| abstract_inverted_index.long-range | 236 |
| abstract_inverted_index.production | 174 |
| abstract_inverted_index.reproduces | 117 |
| abstract_inverted_index.sufficient | 2 |
| abstract_inverted_index.application | 92 |
| abstract_inverted_index.fertilizers | 95 |
| abstract_inverted_index.responsible | 161 |
| abstract_inverted_index.suggestions | 192 |
| abstract_inverted_index.transported | 249 |
| abstract_inverted_index.variability | 20 |
| abstract_inverted_index.agricultural | 28, 110 |
| abstract_inverted_index.constraining | 194 |
| abstract_inverted_index.organosulfur | 143, 150, 157, 196, 213 |
| abstract_inverted_index.relationship | 32 |
| abstract_inverted_index.observations, | 164 |
| abstract_inverted_index.concentrations. | 144 |
| abstract_inverted_index.sulfur-containing | 94 |
| abstract_inverted_index.hydroxymethanesulfonate | 36 |
| cited_by_percentile_year | |
| corresponding_author_ids | https://openalex.org/A5058310539, https://openalex.org/A5067747711, https://openalex.org/A5019922675, https://openalex.org/A5034102495, https://openalex.org/A5081595136, https://openalex.org/A5050316507, https://openalex.org/A5085143453, https://openalex.org/A5047651633, https://openalex.org/A5038894954, https://openalex.org/A5056528553, https://openalex.org/A5048666769, https://openalex.org/A5042024011, https://openalex.org/A5021926648, https://openalex.org/A5061008777, https://openalex.org/A5025491485, https://openalex.org/A5005329534, https://openalex.org/A5056983166, https://openalex.org/A5000988946, https://openalex.org/A5086524930, https://openalex.org/A5000133773 |
| countries_distinct_count | 2 |
| institutions_distinct_count | 34 |
| corresponding_institution_ids | https://openalex.org/I122411786, https://openalex.org/I129774422, https://openalex.org/I1302368450, https://openalex.org/I1306266525, https://openalex.org/I1309191912, https://openalex.org/I1319063186, https://openalex.org/I161675122, https://openalex.org/I188538660, https://openalex.org/I4210111149, https://openalex.org/I4210132178, https://openalex.org/I79272384 |
| citation_normalized_percentile |