Composition-, temperature- and pressure-induced transitions between high-pressure stabilized perovskite phases of the (1-x)BiFe0.5Sc0.5O3 - xLaFe0.5Sc0.5O3 series Article Swipe
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· 2023
· Open Access
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· DOI: https://doi.org/10.1016/j.jssc.2023.123937
Crystal structures of the high-pressure synthesized perovskite phases of the (1-x)BiFe0.5Sc0.5O3-xLaFe0.5Sc0.5O3 (0¼ x - 1) system and their temperature and pressure behaviours were studied using laboratory and synchrotron Xray diffractions as well as neutron diffraction. At room temperature, the as-prepared phases with x < 0.05 have an antipolar structure with the Pnma symmetry and with the √2ap x 4ap x2√2ap superstructure (where ap is the pseudocubic perovskite unit-cell parameter). An incommensurately modulated phase with the Imma(00γ)s00 superspace group is observed for 0.10 ¼ x < 0.33, while a non-polar Pnma phase (√2apx 2ap x √2ap) is stable when x > 0.34. The antipolar Pnma phase in the as-prepared samples with composition corresponding to x ¼ 0 transforms into the polar Ima2 one via irreversible annealing-caused transformation accompanied by a formation of a high-temperature intermediate polar R3c polymorph, while the antipolar Pnma phase in samples with x ¼ \n0.05 is stable until the decomposition temperature. In the solid solutions with 0.10 ¼ x < 0.33, increasing temperature was found to result in a reversible transformation of the Imma(00γ)s00 phase into a non-polar Pnma one. The transition temperature decreases with increasing x. A hydrostatic pressure of few GPa was also shown to induce a reversible Imma(00γ)s00 → Pnma transformation.
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- Language
- en
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- OA Status
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- References
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https://openalex.org/W4321768945Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1016/j.jssc.2023.123937Digital Object Identifier
- Title
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Composition-, temperature- and pressure-induced transitions between high-pressure stabilized perovskite phases of the (1-x)BiFe0.5Sc0.5O3 - xLaFe0.5Sc0.5O3 seriesWork title
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articleOpenAlex work type
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enPrimary language
- Publication year
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2023Year of publication
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2023-02-24Full publication date if available
- Authors
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Andrei N. Salak, J.P. Cardoso, D. D. Khalyavin, Antoine Barbier, Pierre Fertey, Sergey M. Mikhalev, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, Andrius Stanulis, R. RamanauskasList of authors in order
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https://doi.org/10.1016/j.jssc.2023.123937Publisher landing page
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https://ars.els-cdn.com/content/image/1-s2.0-S0022459623001056-ga1_lrg.jpgDirect link to full text PDF
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hybridOpen access status per OpenAlex
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https://ars.els-cdn.com/content/image/1-s2.0-S0022459623001056-ga1_lrg.jpgDirect OA link when available
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Crystallography, Perovskite (structure), Superstructure, Phase (matter), Materials science, Phase transition, Chemistry, Diffraction, Synchrotron, Analytical Chemistry (journal), Thermodynamics, Organic chemistry, Chromatography, Nuclear physics, Physics, OpticsTop concepts (fields/topics) attached by OpenAlex
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10Other works algorithmically related by OpenAlex
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