Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra‐Framework Anions in Pore‐Space‐Partitioned Metal–Organic Frameworks Article Swipe
Anh N. Hong
,
Yanxiang Wang
,
Yichong Chen
,
Huajun Yang
,
Emily Kusumoputro
,
Xianhui Bu
,
Pingyun Feng
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/chem.202203547
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1002/chem.202203547
A multi‐stage core‐expansion method is proposed here as one component of the integrative binding‐site/extender/core‐expansion ( BEC ) strategy. The conceptual deconstruction of the partitioning ligand into three editable parts draws our focus onto progressive core expansion and allows the optimization of both acetylene uptake and selectivity. The effectiveness of this strategy is shown through a family of eight cationic pore‐partitioned materials containing three different partitioning ligands and various counter anions. The optimized structure, Co 3 ‐cpt‐tph‐Cl (Hcpt=4‐(p‐carboxyphenyl)‐1,2,4‐triazole, H‐tph=(2,5,8‐tri‐(4‐pyridyl)‐1,3,4,6,7,9‐hexaazaphenalene) with the largest surface area and highest C 2 H 2 uptake capacity (200 cm 3 /g at 298 K), also exhibits (desirably) the lowest CO 2 uptake and hence the highest C 2 H 2 /CO 2 selectivity. The successful boost in both C 2 H 2 capacity and IAST selectivity allows Co 3 ‐cpt‐tph‐Cl to rank among the best crystalline porous materials, ionic MOFs in particular, for C 2 H 2 uptake and C 2 H 2 /CO 2 experimental breakthrough separation.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/chem.202203547
- OA Status
- green
- Cited By
- 17
- References
- 39
- Related Works
- 10
- OpenAlex ID
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All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4310708700Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/chem.202203547Digital Object Identifier
- Title
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Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra‐Framework Anions in Pore‐Space‐Partitioned Metal–Organic FrameworksWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2022Year of publication
- Publication date
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2022-12-05Full publication date if available
- Authors
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Anh N. Hong, Yanxiang Wang, Yichong Chen, Huajun Yang, Emily Kusumoputro, Xianhui Bu, Pingyun FengList of authors in order
- Landing page
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https://doi.org/10.1002/chem.202203547Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
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https://www.osti.gov/biblio/2205469Direct OA link when available
- Concepts
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Acetylene, Selectivity, Metal-organic framework, Space (punctuation), Characterisation of pore space in soil, Chemistry, Chemical engineering, Materials science, Organic chemistry, Computer science, Catalysis, Engineering, Adsorption, Porosity, Operating systemTop concepts (fields/topics) attached by OpenAlex
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17Total citation count in OpenAlex
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2025: 7, 2024: 8, 2023: 2Per-year citation counts (last 5 years)
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39Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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