Constructing Nanocaged Enzymes for Synergistic Catalysis of CO2 Reduction Article Swipe
Zhichao Jia
,
Jianan Dang
,
Guobin Wen
,
Dengsong Zhang
,
Zhongwei Chen
,
Zhengyu Bai
,
Lin Yang
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/advs.202300752
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/advs.202300752
Promoting the activity of biological enzymes under in vitro environment is a promising technique for bioelectrocatalytic reactions, such as the conversion of carbon dioxide (CO 2 ) into valuable chemicals, which is a promising strategy to address the environmental issue of CO 2 in the atmosphere; however, this technique remains challenging. Herein, a nanocage structure for enzyme confinement is synthesized to enable the in situ encapsulation of formate dehydrogenase (FDH) in a porous metal–organic framework, which acts as a coenzyme and boosts the hybrid synergistic catalysis using enzymes. This study reveals that the synthesized FDH@ZIF‐8 nanocage‐structured hybrid (CSH) catalyst exhibits an improved catalytic ability of the enzymes and increases the hydrophobicity of the electrode and its affinity to CO 2 . Thus, CSH can trap CO 2 and control its microenvironments. The CSH catalyst boosts the conversion rate of CO 2 to formic acid (HCOOH) to 28 times higher than that when using pure FDH. The in situ attenuated total reflectance surface‐enhanced infrared absorption spectroscopy (ATR‐SEIRAS) spectra indicates that OCHO* is the key intermediate. Density functional theory (DFT) calculations show that CSH has extremely low overpotential and is particularly effective for producing formate. This protection architecture for enzymes considerably promotes their biological application under in vitro environments.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/advs.202300752
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/advs.202300752
- OA Status
- gold
- Cited By
- 8
- References
- 64
- Related Works
- 10
- OpenAlex ID
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All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4376121317Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/advs.202300752Digital Object Identifier
- Title
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Constructing Nanocaged Enzymes for Synergistic Catalysis of CO2 ReductionWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-05-10Full publication date if available
- Authors
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Zhichao Jia, Jianan Dang, Guobin Wen, Dengsong Zhang, Zhongwei Chen, Zhengyu Bai, Lin YangList of authors in order
- Landing page
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https://doi.org/10.1002/advs.202300752Publisher landing page
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/advs.202300752Direct link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/advs.202300752Direct OA link when available
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Catalysis, Chemistry, Reduction (mathematics), Enzyme, Chemical engineering, Combinatorial chemistry, Materials science, Organic chemistry, Engineering, Mathematics, GeometryTop concepts (fields/topics) attached by OpenAlex
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8Total citation count in OpenAlex
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2025: 3, 2024: 4, 2023: 1Per-year citation counts (last 5 years)
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64Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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