Controlled Synthesis of “Reverse Pluronic”‐Type Block Copolyethers with High Molar Masses for the Preparation of Hydrogels with Improved Mechanical Properties Article Swipe
Felix Markus
,
Johanna R. Bruckner
,
Stefan Naumann
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1002/macp.201900437
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1002/macp.201900437
Hydrogels based on Pluronics (EO n/2 ‐PO m ‐EO n/2 , EO = ethylene oxide, PO = propylene oxide) have been frequently investigated, yet key limitations still remain, including a propensity for quick erosion and insufficient mechanical robustness. This issue can be alleviated by creating “reverse Pluronics” (PO n /2 ‐EO m ‐PO n /2 ), which is proposed to enable the formation of physical cross‐links via a micellar network. Until recently, however, efforts in this direction were aggravated by synthetic difficulties, specifically prohibiting the realization of poly(propylene oxide) (PPO)‐moieties with a high DP. In this study, an organocatalytic polymerization method is employed to synthesize “reverse Pluronics,” resulting in highly defined polymers ( Ð M ≤ 1.02–1.07, M n up to 35 000 g mol −1 ) with exceptionally long PPO blocks. The higher molar mass and the reverse constitution of the polyether combine to enable the generation of thermoresponsive hydrogels with a storage modulus that is increased tenfold relative to reference samples. Gelation temperature and maximum storage modulus ( G ′ max ) are readily influenced by the choice of the polyether (down to 5 wt%). The improved mechanical properties are accompanied by an increased resistance toward erosion in water. Isotactic enrichment is presented as an additional tuning parameter for hydrogel properties.
Related Topics
Concepts
Propylene oxide
Self-healing hydrogels
Poloxamer
Molar mass
Ethylene oxide
Polymer
Materials science
Chemical engineering
Copolymer
Polymer chemistry
Polymerization
Dynamic mechanical analysis
Composite material
Engineering
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/macp.201900437
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437
- OA Status
- hybrid
- Cited By
- 17
- References
- 49
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2999401529
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W2999401529Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/macp.201900437Digital Object Identifier
- Title
-
Controlled Synthesis of “Reverse Pluronic”‐Type Block Copolyethers with High Molar Masses for the Preparation of Hydrogels with Improved Mechanical PropertiesWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2020Year of publication
- Publication date
-
2020-01-09Full publication date if available
- Authors
-
Felix Markus, Johanna R. Bruckner, Stefan NaumannList of authors in order
- Landing page
-
https://doi.org/10.1002/macp.201900437Publisher landing page
- PDF URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
hybridOpen access status per OpenAlex
- OA URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437Direct OA link when available
- Concepts
-
Propylene oxide, Self-healing hydrogels, Poloxamer, Molar mass, Ethylene oxide, Polymer, Materials science, Chemical engineering, Copolymer, Polymer chemistry, Polymerization, Dynamic mechanical analysis, Composite material, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
17Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 5, 2024: 1, 2023: 3, 2022: 4, 2021: 2Per-year citation counts (last 5 years)
- References (count)
-
49Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W2999401529 |
|---|---|
| doi | https://doi.org/10.1002/macp.201900437 |
| ids.doi | https://doi.org/10.1002/macp.201900437 |
| ids.mag | 2999401529 |
| ids.openalex | https://openalex.org/W2999401529 |
| fwci | 1.3972058 |
| type | article |
| title | Controlled Synthesis of “Reverse Pluronic”‐Type Block Copolyethers with High Molar Masses for the Preparation of Hydrogels with Improved Mechanical Properties |
| awards[0].id | https://openalex.org/G8004822045 |
| awards[0].funder_id | https://openalex.org/F4320320879 |
| awards[0].display_name | |
| awards[0].funder_award_id | 358283783 (CRC 1333) |
| awards[0].funder_display_name | Deutsche Forschungsgemeinschaft |
| biblio.issue | 3 |
| biblio.volume | 221 |
| biblio.last_page | |
| biblio.first_page | |
| topics[0].id | https://openalex.org/T10405 |
| topics[0].field.id | https://openalex.org/fields/16 |
| topics[0].field.display_name | Chemistry |
| topics[0].score | 0.9998999834060669 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/1605 |
| topics[0].subfield.display_name | Organic Chemistry |
| topics[0].display_name | Advanced Polymer Synthesis and Characterization |
| topics[1].id | https://openalex.org/T10343 |
| topics[1].field.id | https://openalex.org/fields/13 |
| topics[1].field.display_name | Biochemistry, Genetics and Molecular Biology |
| topics[1].score | 0.9998000264167786 |
| topics[1].domain.id | https://openalex.org/domains/1 |
| topics[1].domain.display_name | Life Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/1313 |
| topics[1].subfield.display_name | Molecular Medicine |
| topics[1].display_name | Hydrogels: synthesis, properties, applications |
| topics[2].id | https://openalex.org/T10810 |
| topics[2].field.id | https://openalex.org/fields/25 |
| topics[2].field.display_name | Materials Science |
| topics[2].score | 0.9987999796867371 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/2507 |
| topics[2].subfield.display_name | Polymers and Plastics |
| topics[2].display_name | Polymer composites and self-healing |
| funders[0].id | https://openalex.org/F4320320879 |
| funders[0].ror | https://ror.org/018mejw64 |
| funders[0].display_name | Deutsche Forschungsgemeinschaft |
| is_xpac | False |
| apc_list.value | 4020 |
| apc_list.currency | USD |
| apc_list.value_usd | 4020 |
| apc_paid.value | 4020 |
| apc_paid.currency | USD |
| apc_paid.value_usd | 4020 |
| concepts[0].id | https://openalex.org/C2777505466 |
| concepts[0].level | 5 |
| concepts[0].score | 0.8632192015647888 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q727742 |
| concepts[0].display_name | Propylene oxide |
| concepts[1].id | https://openalex.org/C108586683 |
| concepts[1].level | 2 |
| concepts[1].score | 0.8503714799880981 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q17164826 |
| concepts[1].display_name | Self-healing hydrogels |
| concepts[2].id | https://openalex.org/C101335993 |
| concepts[2].level | 4 |
| concepts[2].score | 0.7650344371795654 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q408943 |
| concepts[2].display_name | Poloxamer |
| concepts[3].id | https://openalex.org/C196503311 |
| concepts[3].level | 3 |
| concepts[3].score | 0.6627455353736877 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q145623 |
| concepts[3].display_name | Molar mass |
| concepts[4].id | https://openalex.org/C2777801237 |
| concepts[4].level | 4 |
| concepts[4].score | 0.5608465075492859 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q407473 |
| concepts[4].display_name | Ethylene oxide |
| concepts[5].id | https://openalex.org/C521977710 |
| concepts[5].level | 2 |
| concepts[5].score | 0.553235650062561 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q81163 |
| concepts[5].display_name | Polymer |
| concepts[6].id | https://openalex.org/C192562407 |
| concepts[6].level | 0 |
| concepts[6].score | 0.549021303653717 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q228736 |
| concepts[6].display_name | Materials science |
| concepts[7].id | https://openalex.org/C42360764 |
| concepts[7].level | 1 |
| concepts[7].score | 0.542733371257782 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q83588 |
| concepts[7].display_name | Chemical engineering |
| concepts[8].id | https://openalex.org/C15920480 |
| concepts[8].level | 3 |
| concepts[8].score | 0.5064033269882202 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q421281 |
| concepts[8].display_name | Copolymer |
| concepts[9].id | https://openalex.org/C188027245 |
| concepts[9].level | 1 |
| concepts[9].score | 0.50042724609375 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q750446 |
| concepts[9].display_name | Polymer chemistry |
| concepts[10].id | https://openalex.org/C44228677 |
| concepts[10].level | 3 |
| concepts[10].score | 0.4978785514831543 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q181898 |
| concepts[10].display_name | Polymerization |
| concepts[11].id | https://openalex.org/C7055690 |
| concepts[11].level | 3 |
| concepts[11].score | 0.4614917039871216 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q900639 |
| concepts[11].display_name | Dynamic mechanical analysis |
| concepts[12].id | https://openalex.org/C159985019 |
| concepts[12].level | 1 |
| concepts[12].score | 0.2298654019832611 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q181790 |
| concepts[12].display_name | Composite material |
| concepts[13].id | https://openalex.org/C127413603 |
| concepts[13].level | 0 |
| concepts[13].score | 0.0 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q11023 |
| concepts[13].display_name | Engineering |
| keywords[0].id | https://openalex.org/keywords/propylene-oxide |
| keywords[0].score | 0.8632192015647888 |
| keywords[0].display_name | Propylene oxide |
| keywords[1].id | https://openalex.org/keywords/self-healing-hydrogels |
| keywords[1].score | 0.8503714799880981 |
| keywords[1].display_name | Self-healing hydrogels |
| keywords[2].id | https://openalex.org/keywords/poloxamer |
| keywords[2].score | 0.7650344371795654 |
| keywords[2].display_name | Poloxamer |
| keywords[3].id | https://openalex.org/keywords/molar-mass |
| keywords[3].score | 0.6627455353736877 |
| keywords[3].display_name | Molar mass |
| keywords[4].id | https://openalex.org/keywords/ethylene-oxide |
| keywords[4].score | 0.5608465075492859 |
| keywords[4].display_name | Ethylene oxide |
| keywords[5].id | https://openalex.org/keywords/polymer |
| keywords[5].score | 0.553235650062561 |
| keywords[5].display_name | Polymer |
| keywords[6].id | https://openalex.org/keywords/materials-science |
| keywords[6].score | 0.549021303653717 |
| keywords[6].display_name | Materials science |
| keywords[7].id | https://openalex.org/keywords/chemical-engineering |
| keywords[7].score | 0.542733371257782 |
| keywords[7].display_name | Chemical engineering |
| keywords[8].id | https://openalex.org/keywords/copolymer |
| keywords[8].score | 0.5064033269882202 |
| keywords[8].display_name | Copolymer |
| keywords[9].id | https://openalex.org/keywords/polymer-chemistry |
| keywords[9].score | 0.50042724609375 |
| keywords[9].display_name | Polymer chemistry |
| keywords[10].id | https://openalex.org/keywords/polymerization |
| keywords[10].score | 0.4978785514831543 |
| keywords[10].display_name | Polymerization |
| keywords[11].id | https://openalex.org/keywords/dynamic-mechanical-analysis |
| keywords[11].score | 0.4614917039871216 |
| keywords[11].display_name | Dynamic mechanical analysis |
| keywords[12].id | https://openalex.org/keywords/composite-material |
| keywords[12].score | 0.2298654019832611 |
| keywords[12].display_name | Composite material |
| language | en |
| locations[0].id | doi:10.1002/macp.201900437 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S124744586 |
| locations[0].source.issn | 1022-1352, 1521-3935 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | False |
| locations[0].source.issn_l | 1022-1352 |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | False |
| locations[0].source.display_name | Macromolecular Chemistry and Physics |
| locations[0].source.host_organization | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_name | Wiley |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_lineage_names | Wiley |
| locations[0].license | cc-by |
| locations[0].pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437 |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | https://openalex.org/licenses/cc-by |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | Macromolecular Chemistry and Physics |
| locations[0].landing_page_url | https://doi.org/10.1002/macp.201900437 |
| indexed_in | crossref |
| authorships[0].author.id | https://openalex.org/A5069450690 |
| authorships[0].author.orcid | |
| authorships[0].author.display_name | Felix Markus |
| authorships[0].countries | DE |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I100066346 |
| authorships[0].affiliations[0].raw_affiliation_string | Institute of Polymer Chemistry University of Stuttgart 70569 Stuttgart Germany |
| authorships[0].institutions[0].id | https://openalex.org/I100066346 |
| authorships[0].institutions[0].ror | https://ror.org/04vnq7t77 |
| authorships[0].institutions[0].type | education |
| authorships[0].institutions[0].lineage | https://openalex.org/I100066346 |
| authorships[0].institutions[0].country_code | DE |
| authorships[0].institutions[0].display_name | University of Stuttgart |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Felix Markus |
| authorships[0].is_corresponding | True |
| authorships[0].raw_affiliation_strings | Institute of Polymer Chemistry University of Stuttgart 70569 Stuttgart Germany |
| authorships[1].author.id | https://openalex.org/A5005537281 |
| authorships[1].author.orcid | https://orcid.org/0000-0001-7183-6532 |
| authorships[1].author.display_name | Johanna R. Bruckner |
| authorships[1].countries | DE |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I100066346 |
| authorships[1].affiliations[0].raw_affiliation_string | Institute of Physical Chemistry University of Stuttgart 70569 Stuttgart Germany |
| authorships[1].institutions[0].id | https://openalex.org/I100066346 |
| authorships[1].institutions[0].ror | https://ror.org/04vnq7t77 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I100066346 |
| authorships[1].institutions[0].country_code | DE |
| authorships[1].institutions[0].display_name | University of Stuttgart |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Johanna R. Bruckner |
| authorships[1].is_corresponding | True |
| authorships[1].raw_affiliation_strings | Institute of Physical Chemistry University of Stuttgart 70569 Stuttgart Germany |
| authorships[2].author.id | https://openalex.org/A5089460963 |
| authorships[2].author.orcid | https://orcid.org/0000-0003-2014-4434 |
| authorships[2].author.display_name | Stefan Naumann |
| authorships[2].countries | DE |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I100066346 |
| authorships[2].affiliations[0].raw_affiliation_string | Institute of Polymer Chemistry University of Stuttgart 70569 Stuttgart Germany |
| authorships[2].institutions[0].id | https://openalex.org/I100066346 |
| authorships[2].institutions[0].ror | https://ror.org/04vnq7t77 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I100066346 |
| authorships[2].institutions[0].country_code | DE |
| authorships[2].institutions[0].display_name | University of Stuttgart |
| authorships[2].author_position | last |
| authorships[2].raw_author_name | Stefan Naumann |
| authorships[2].is_corresponding | True |
| authorships[2].raw_affiliation_strings | Institute of Polymer Chemistry University of Stuttgart 70569 Stuttgart Germany |
| has_content.pdf | True |
| has_content.grobid_xml | True |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437 |
| open_access.oa_status | hybrid |
| open_access.any_repository_has_fulltext | False |
| created_date | 2025-10-10T00:00:00 |
| display_name | Controlled Synthesis of “Reverse Pluronic”‐Type Block Copolyethers with High Molar Masses for the Preparation of Hydrogels with Improved Mechanical Properties |
| has_fulltext | True |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T10405 |
| primary_topic.field.id | https://openalex.org/fields/16 |
| primary_topic.field.display_name | Chemistry |
| primary_topic.score | 0.9998999834060669 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/1605 |
| primary_topic.subfield.display_name | Organic Chemistry |
| primary_topic.display_name | Advanced Polymer Synthesis and Characterization |
| related_works | https://openalex.org/W1994563888, https://openalex.org/W1971310741, https://openalex.org/W2378335354, https://openalex.org/W1975848776, https://openalex.org/W2079296755, https://openalex.org/W2002926106, https://openalex.org/W4231521870, https://openalex.org/W4233393473, https://openalex.org/W2784424816, https://openalex.org/W2735530573 |
| cited_by_count | 17 |
| counts_by_year[0].year | 2025 |
| counts_by_year[0].cited_by_count | 5 |
| counts_by_year[1].year | 2024 |
| counts_by_year[1].cited_by_count | 1 |
| counts_by_year[2].year | 2023 |
| counts_by_year[2].cited_by_count | 3 |
| counts_by_year[3].year | 2022 |
| counts_by_year[3].cited_by_count | 4 |
| counts_by_year[4].year | 2021 |
| counts_by_year[4].cited_by_count | 2 |
| counts_by_year[5].year | 2020 |
| counts_by_year[5].cited_by_count | 2 |
| locations_count | 1 |
| best_oa_location.id | doi:10.1002/macp.201900437 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S124744586 |
| best_oa_location.source.issn | 1022-1352, 1521-3935 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | False |
| best_oa_location.source.issn_l | 1022-1352 |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | False |
| best_oa_location.source.display_name | Macromolecular Chemistry and Physics |
| best_oa_location.source.host_organization | https://openalex.org/P4310320595 |
| best_oa_location.source.host_organization_name | Wiley |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| best_oa_location.source.host_organization_lineage_names | Wiley |
| best_oa_location.license | cc-by |
| best_oa_location.pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437 |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | https://openalex.org/licenses/cc-by |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | Macromolecular Chemistry and Physics |
| best_oa_location.landing_page_url | https://doi.org/10.1002/macp.201900437 |
| primary_location.id | doi:10.1002/macp.201900437 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S124744586 |
| primary_location.source.issn | 1022-1352, 1521-3935 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | False |
| primary_location.source.issn_l | 1022-1352 |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | False |
| primary_location.source.display_name | Macromolecular Chemistry and Physics |
| primary_location.source.host_organization | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_name | Wiley |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_lineage_names | Wiley |
| primary_location.license | cc-by |
| primary_location.pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201900437 |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | https://openalex.org/licenses/cc-by |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | Macromolecular Chemistry and Physics |
| primary_location.landing_page_url | https://doi.org/10.1002/macp.201900437 |
| publication_date | 2020-01-09 |
| publication_year | 2020 |
| referenced_works | https://openalex.org/W2209408609, https://openalex.org/W2061232589, https://openalex.org/W1985631236, https://openalex.org/W2060835907, https://openalex.org/W2155630620, https://openalex.org/W2044512869, https://openalex.org/W2724361225, https://openalex.org/W1965542060, https://openalex.org/W1972121081, https://openalex.org/W2087470424, https://openalex.org/W2042682599, https://openalex.org/W1969604041, https://openalex.org/W1999275329, https://openalex.org/W2018129867, https://openalex.org/W2088219568, https://openalex.org/W1967629812, https://openalex.org/W1996058036, https://openalex.org/W2161579429, https://openalex.org/W1972217729, https://openalex.org/W2065830568, https://openalex.org/W2002411960, https://openalex.org/W2909944178, https://openalex.org/W2896242238, https://openalex.org/W2945686669, https://openalex.org/W2131507508, https://openalex.org/W2782488034, https://openalex.org/W2179180981, https://openalex.org/W2743445903, https://openalex.org/W2747366464, https://openalex.org/W2808867872, https://openalex.org/W2910182793, https://openalex.org/W2054609339, https://openalex.org/W1978949214, https://openalex.org/W2087451989, https://openalex.org/W2052483389, https://openalex.org/W2007080192, https://openalex.org/W2015346163, https://openalex.org/W2621982759, https://openalex.org/W2121590436, https://openalex.org/W2945492040, https://openalex.org/W253334427, https://openalex.org/W1505936474, https://openalex.org/W1843091404, https://openalex.org/W2042993819, https://openalex.org/W1989636089, https://openalex.org/W2944340538, https://openalex.org/W2945332317, https://openalex.org/W2034111016, https://openalex.org/W2037102328 |
| referenced_works_count | 49 |
| abstract_inverted_index.( | 113, 170 |
| abstract_inverted_index.) | 127, 174 |
| abstract_inverted_index., | 11 |
| abstract_inverted_index.5 | 186 |
| abstract_inverted_index.= | 13, 17 |
| abstract_inverted_index.G | 171 |
| abstract_inverted_index.M | 115, 118 |
| abstract_inverted_index.a | 30, 68, 92, 153 |
| abstract_inverted_index.g | 124 |
| abstract_inverted_index.m | 8, 52 |
| abstract_inverted_index.n | 49, 54, 119 |
| abstract_inverted_index.), | 56 |
| abstract_inverted_index./2 | 50, 55 |
| abstract_inverted_index.35 | 122 |
| abstract_inverted_index.EO | 12 |
| abstract_inverted_index.In | 95 |
| abstract_inverted_index.PO | 16 |
| abstract_inverted_index.an | 98, 195, 207 |
| abstract_inverted_index.as | 206 |
| abstract_inverted_index.be | 42 |
| abstract_inverted_index.by | 44, 80, 178, 194 |
| abstract_inverted_index.in | 75, 109, 200 |
| abstract_inverted_index.is | 58, 102, 157, 204 |
| abstract_inverted_index.of | 64, 87, 141, 149, 181 |
| abstract_inverted_index.on | 3 |
| abstract_inverted_index.to | 60, 104, 121, 145, 161, 185 |
| abstract_inverted_index.up | 120 |
| abstract_inverted_index.Ð | 114 |
| abstract_inverted_index.(EO | 5 |
| abstract_inverted_index.(PO | 48 |
| abstract_inverted_index.000 | 123 |
| abstract_inverted_index.DP. | 94 |
| abstract_inverted_index.PPO | 131 |
| abstract_inverted_index.The | 133, 188 |
| abstract_inverted_index.and | 35, 137, 166 |
| abstract_inverted_index.are | 175, 192 |
| abstract_inverted_index.can | 41 |
| abstract_inverted_index.for | 32, 211 |
| abstract_inverted_index.key | 25 |
| abstract_inverted_index.max | 173 |
| abstract_inverted_index.mol | 125 |
| abstract_inverted_index.n/2 | 6, 10 |
| abstract_inverted_index.the | 62, 85, 138, 142, 147, 179, 182 |
| abstract_inverted_index.via | 67 |
| abstract_inverted_index.yet | 24 |
| abstract_inverted_index.′ | 172 |
| abstract_inverted_index.≤ | 116 |
| abstract_inverted_index.This | 39 |
| abstract_inverted_index.been | 21 |
| abstract_inverted_index.have | 20 |
| abstract_inverted_index.high | 93 |
| abstract_inverted_index.long | 130 |
| abstract_inverted_index.mass | 136 |
| abstract_inverted_index.that | 156 |
| abstract_inverted_index.this | 76, 96 |
| abstract_inverted_index.were | 78 |
| abstract_inverted_index.with | 91, 128, 152 |
| abstract_inverted_index.−1 | 126 |
| abstract_inverted_index.(down | 184 |
| abstract_inverted_index.Until | 71 |
| abstract_inverted_index.based | 2 |
| abstract_inverted_index.issue | 40 |
| abstract_inverted_index.molar | 135 |
| abstract_inverted_index.quick | 33 |
| abstract_inverted_index.still | 27 |
| abstract_inverted_index.which | 57 |
| abstract_inverted_index.wt%). | 187 |
| abstract_inverted_index.‐EO | 9, 51 |
| abstract_inverted_index.‐PO | 7, 53 |
| abstract_inverted_index.choice | 180 |
| abstract_inverted_index.enable | 61, 146 |
| abstract_inverted_index.higher | 134 |
| abstract_inverted_index.highly | 110 |
| abstract_inverted_index.method | 101 |
| abstract_inverted_index.oxide) | 19, 89 |
| abstract_inverted_index.oxide, | 15 |
| abstract_inverted_index.study, | 97 |
| abstract_inverted_index.toward | 198 |
| abstract_inverted_index.tuning | 209 |
| abstract_inverted_index.water. | 201 |
| abstract_inverted_index.blocks. | 132 |
| abstract_inverted_index.combine | 144 |
| abstract_inverted_index.defined | 111 |
| abstract_inverted_index.efforts | 74 |
| abstract_inverted_index.erosion | 34, 199 |
| abstract_inverted_index.maximum | 167 |
| abstract_inverted_index.modulus | 155, 169 |
| abstract_inverted_index.readily | 176 |
| abstract_inverted_index.remain, | 28 |
| abstract_inverted_index.reverse | 139 |
| abstract_inverted_index.storage | 154, 168 |
| abstract_inverted_index.tenfold | 159 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.Gelation | 164 |
| abstract_inverted_index.creating | 45 |
| abstract_inverted_index.employed | 103 |
| abstract_inverted_index.ethylene | 14 |
| abstract_inverted_index.however, | 73 |
| abstract_inverted_index.hydrogel | 212 |
| abstract_inverted_index.improved | 189 |
| abstract_inverted_index.micellar | 69 |
| abstract_inverted_index.network. | 70 |
| abstract_inverted_index.physical | 65 |
| abstract_inverted_index.polymers | 112 |
| abstract_inverted_index.proposed | 59 |
| abstract_inverted_index.relative | 160 |
| abstract_inverted_index.samples. | 163 |
| abstract_inverted_index.Hydrogels | 1 |
| abstract_inverted_index.Isotactic | 202 |
| abstract_inverted_index.Pluronics | 4 |
| abstract_inverted_index.direction | 77 |
| abstract_inverted_index.formation | 63 |
| abstract_inverted_index.hydrogels | 151 |
| abstract_inverted_index.including | 29 |
| abstract_inverted_index.increased | 158, 196 |
| abstract_inverted_index.parameter | 210 |
| abstract_inverted_index.polyether | 143, 183 |
| abstract_inverted_index.presented | 205 |
| abstract_inverted_index.propylene | 18 |
| abstract_inverted_index.recently, | 72 |
| abstract_inverted_index.reference | 162 |
| abstract_inverted_index.resulting | 108 |
| abstract_inverted_index.synthetic | 81 |
| abstract_inverted_index.additional | 208 |
| abstract_inverted_index.aggravated | 79 |
| abstract_inverted_index.alleviated | 43 |
| abstract_inverted_index.enrichment | 203 |
| abstract_inverted_index.frequently | 22 |
| abstract_inverted_index.generation | 148 |
| abstract_inverted_index.influenced | 177 |
| abstract_inverted_index.mechanical | 37, 190 |
| abstract_inverted_index.propensity | 31 |
| abstract_inverted_index.properties | 191 |
| abstract_inverted_index.resistance | 197 |
| abstract_inverted_index.synthesize | 105 |
| abstract_inverted_index.“reverse | 46, 106 |
| abstract_inverted_index.accompanied | 193 |
| abstract_inverted_index.limitations | 26 |
| abstract_inverted_index.prohibiting | 84 |
| abstract_inverted_index.properties. | 213 |
| abstract_inverted_index.realization | 86 |
| abstract_inverted_index.robustness. | 38 |
| abstract_inverted_index.temperature | 165 |
| abstract_inverted_index.1.02–1.07, | 117 |
| abstract_inverted_index.Pluronics” | 47 |
| abstract_inverted_index.constitution | 140 |
| abstract_inverted_index.insufficient | 36 |
| abstract_inverted_index.specifically | 83 |
| abstract_inverted_index.Pluronics,” | 107 |
| abstract_inverted_index.cross‐links | 66 |
| abstract_inverted_index.difficulties, | 82 |
| abstract_inverted_index.exceptionally | 129 |
| abstract_inverted_index.investigated, | 23 |
| abstract_inverted_index.poly(propylene | 88 |
| abstract_inverted_index.polymerization | 100 |
| abstract_inverted_index.organocatalytic | 99 |
| abstract_inverted_index.(PPO)‐moieties | 90 |
| abstract_inverted_index.thermoresponsive | 150 |
| cited_by_percentile_year.max | 98 |
| cited_by_percentile_year.min | 90 |
| corresponding_author_ids | https://openalex.org/A5069450690, https://openalex.org/A5089460963, https://openalex.org/A5005537281 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 3 |
| corresponding_institution_ids | https://openalex.org/I100066346 |
| citation_normalized_percentile.value | 0.74745944 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |