Correlation between mechanical properties and ionic conductivity of polycrystalline sodium superionic conductors: A relative density-dominant relationship Article Swipe
YOU?
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· 2024
· Open Access
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· DOI: https://doi.org/10.1016/j.mtener.2024.101644
Sodium superionic conductors (NASICON) are pivotal for the functionality and safety of solid-state sodium batteries. Their mechanical properties and ionic conductivity are key performance metrics, yet their correlation remains inadequately understood. Addressing this gap is vital for concurrent enhancements in both properties. This study summarizes recent literature on the sintered polycrystalline NASICON solid electrolyte Na1+xZr2SixP3-xO12 (NZSP, 0≤x ≤ 3), focusing on its mechanical properties and ionic conductivity, and identifies a positive correlation between these properties at ambient temperatures. Microstructural analysis reveals that a range of factors, including relative density, grain size, secondary phases, and crystal structures significantly influence the properties of NZSP. Notably, an increase in relative density uniquely contributes to simultaneous enhancements in both hardness and ionic conductivity. Consequently, future research should prioritize enhancing the relative density of NZSP, potentially by employing advanced sintering techniques such as spark plasma sintering (SPS) and microwave-assisted sintering. The correlation between mechanical properties and ionic conductivity observed in NZSP is also evident in other oxide solid electrolytes, such as garnet Li7La3Zr2O12 (LLZO). This investigation not only suggests a potential linkage between these crucial properties but also guides subsequent strategies for refining polycrystalline oxide solid electrolytes for advanced battery technologies.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.mtener.2024.101644
- OA Status
- hybrid
- Cited By
- 21
- References
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- Related Works
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- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W4400313799Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1016/j.mtener.2024.101644Digital Object Identifier
- Title
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Correlation between mechanical properties and ionic conductivity of polycrystalline sodium superionic conductors: A relative density-dominant relationshipWork title
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-07-04Full publication date if available
- Authors
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Eric Jianfeng Cheng, Tao Yang, Yuanzhuo Liu, Linjiang Chai, Regina García-Méndez, Eric Kazyak, Zhenyu Fu, Guoqiang Luo, Fei Chen, Ryoji Inada, Vlad Badilita, Huanan Duan, Ziyun Wang, Jiaqian Qin, Hao Li, Shin‐ichi Orimo, Hidemi KatoList of authors in order
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https://doi.org/10.1016/j.mtener.2024.101644Publisher landing page
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hybridOpen access status per OpenAlex
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https://doi.org/10.1016/j.mtener.2024.101644Direct OA link when available
- Concepts
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Materials science, Fast ion conductor, Ionic conductivity, Spark plasma sintering, Electrolyte, Relative density, Sintering, Crystallite, Conductivity, Ionic bonding, Electrical conductor, Composite material, Ion, Metallurgy, Electrode, Physical chemistry, Chemistry, Organic chemistryTop concepts (fields/topics) attached by OpenAlex
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21Total citation count in OpenAlex
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2025: 16, 2024: 5Per-year citation counts (last 5 years)
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81Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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