Decoupling of Light and Dark Reactions in a 2D Niobium Tungstate for Light-Induced Charge Storage and On-Demand Hydrogen Evolution Article Swipe
YOU?
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· 2024
· Open Access
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· DOI: https://doi.org/10.1021/jacs.4c04140
The direct coupling of light harvesting and charge storage in a single material opens new avenues to light storing devices. Here we demonstrate the decoupling of light and dark reactions in the two-dimensional layered niobium tungstate (TBA)+(NbWO6)- for on-demand hydrogen evolution and solar battery energy storage. Light illumination drives Li+/H+ photointercalation into the (TBA)+(NbWO6)- photoanode, leading to small polaron formation assisted by structural distortions on the WOx sublattice, along with a light-induced decrease in material resistance over 2 orders of magnitude compared to the dark. The photogenerated electrons can be extracted on demand to produce solar hydrogen upon the addition of a Pt catalyst. Alternatively, they can be stored for over 20 h under oxygen-free conditions after 365 nm UV illumination for only 10 min, thus featuring a solar battery anode with promising capacity and long-term stability. The optoionic effects described herein offer new insights to overcome the intermittency of solar irradiation, while inspiring applications at the interface of solar energy conversion and energy storage, including solar batteries, "dark" photocatalysis, solar battolyzers, and photomemory devices.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/jacs.4c04140
- OA Status
- hybrid
- Cited By
- 11
- References
- 35
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4402253600
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4402253600Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/jacs.4c04140Digital Object Identifier
- Title
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Decoupling of Light and Dark Reactions in a 2D Niobium Tungstate for Light-Induced Charge Storage and On-Demand Hydrogen EvolutionWork title
- Type
-
articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
-
2024-09-04Full publication date if available
- Authors
-
Yang Wang, Yu‐Te Chan, Takayoshi Oshima, Viola Duppel, Sebastian Bette, Kathrin Küster, Andreas Gouder, Christoph Scheurer, Bettina V. LotschList of authors in order
- Landing page
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https://doi.org/10.1021/jacs.4c04140Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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hybridOpen access status per OpenAlex
- OA URL
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https://doi.org/10.1021/jacs.4c04140Direct OA link when available
- Concepts
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Chemistry, Tungstate, Decoupling (probability), Niobium, Charge (physics), Hydrogen storage, Hydrogen, Optoelectronics, Inorganic chemistry, Physics, Organic chemistry, Particle physics, Control engineering, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
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11Total citation count in OpenAlex
- Citations by year (recent)
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2025: 10, 2024: 1Per-year citation counts (last 5 years)
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35Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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