Denitrogenative dismantling of heteroaromatics by nucleophilic substitution reactions with diazomethyl compounds Article Swipe

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Soumen Biswas , Claire Empel , Luis Mario Sanchez‐Palestino , Hadi D. Arman , René M. Koenigs , Michael P. Doyle ·

YOU? · · 2024 · Open Access · · DOI: https://doi.org/10.1039/d4sc01578a

We report divergent reactions of 1,2,3-triazines and 1,2,3-triazine 1-oxides with diazomethyl compounds, the former yielding diazovinylketoesters, and the latter giving rise to pyrazole derivatives through extrusion of ethyl cyanocarboxylate and N 2 O.

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Nucleophilic substitution Pyrazole Chemistry Extrusion Substitution reaction Substitution (logic) Medicinal chemistry Triazine Nucleophilic aromatic substitution Nucleophile Stereochemistry Organic chemistry Catalysis Materials science Computer science Metallurgy Programming language

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Type: article
Language: en
Landing Page: https://doi.org/10.1039/d4sc01578a
OA Status: diamond
References: 44
Related Works: 10
OpenAlex ID: https://openalex.org/W4399735671

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DOI: https://doi.org/10.1039/d4sc01578a

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Title: Denitrogenative dismantling of heteroaromatics by nucleophilic substitution reactions with diazomethyl compounds

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Language: en

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Publication year: 2024

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Publication date: 2024-01-01

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Authors: Soumen Biswas, Claire Empel, Luis Mario Sanchez‐Palestino, Hadi D. Arman, René M. Koenigs, Michael P. Doyle

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Landing page: https://doi.org/10.1039/d4sc01578a

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Concepts: Nucleophilic substitution, Pyrazole, Chemistry, Extrusion, Substitution reaction, Substitution (logic), Medicinal chemistry, Triazine, Nucleophilic aromatic substitution, Nucleophile, Stereochemistry, Organic chemistry, Catalysis, Materials science, Computer science, Metallurgy, Programming language

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