Determination of the intervalence charge-transfer rate in mixed-valence arylamino-fluorene derivatives using EPR spectroscopy Article Swipe
Alessandro Agostini
,
Mirco Zerbetto
,
Davide Sartori
,
Samuel Zatta
,
Antonino Polimeno
,
Agostina Lina Capodilupo
,
Lorenzo Franco
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1063/5.0249934
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1063/5.0249934
Thermally activated electron-transfer processes are of interest for a variety of theoretical and technological applications. In organic mixed-valence (MV) systems, the intramolecular charge transfer between two redox centers offers valuable insights about the kinetics and energetics of electron hopping. We investigated the intramolecular charge transfer process in a series of MV organic molecules where two arylamino units are linked together by a variable length bridge. The experimental investigation is carried out by means of Electron Paramagnetic Resonance (EPR) spectroscopy on MV radical cations. The EPR spectra, recorded in a series of solvents at different temperatures, were adequately simulated using a multiple-site random jump model implemented in a software routine, providing the intramolecular charge transfer rate as the output. The dependence of the free energy of the electron transfer process on the solvent allowed us to identify a correlation between the energetic of the charge transfer and some solvent properties.
Related Topics
Concepts
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1063/5.0249934
- https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdf
- OA Status
- hybrid
- References
- 44
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4408530953
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W4408530953Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1063/5.0249934Digital Object Identifier
- Title
-
Determination of the intervalence charge-transfer rate in mixed-valence arylamino-fluorene derivatives using EPR spectroscopyWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2025Year of publication
- Publication date
-
2025-03-17Full publication date if available
- Authors
-
Alessandro Agostini, Mirco Zerbetto, Davide Sartori, Samuel Zatta, Antonino Polimeno, Agostina Lina Capodilupo, Lorenzo FrancoList of authors in order
- Landing page
-
https://doi.org/10.1063/5.0249934Publisher landing page
- PDF URL
-
https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdfDirect link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
hybridOpen access status per OpenAlex
- OA URL
-
https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdfDirect OA link when available
- Concepts
-
Intramolecular force, Electron paramagnetic resonance, Chemistry, Electron transfer, Valence (chemistry), Fluorene, Spectroscopy, Chemical physics, Molecule, Physical chemistry, Photochemistry, Nuclear magnetic resonance, Polymer, Organic chemistry, Physics, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
0Total citation count in OpenAlex
- References (count)
-
44Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W4408530953 |
|---|---|
| doi | https://doi.org/10.1063/5.0249934 |
| ids.doi | https://doi.org/10.1063/5.0249934 |
| ids.pmid | https://pubmed.ncbi.nlm.nih.gov/40094238 |
| ids.openalex | https://openalex.org/W4408530953 |
| fwci | 0.0 |
| type | article |
| title | Determination of the intervalence charge-transfer rate in mixed-valence arylamino-fluorene derivatives using EPR spectroscopy |
| awards[0].id | https://openalex.org/G8014692443 |
| awards[0].funder_id | https://openalex.org/F4320331528 |
| awards[0].display_name | |
| awards[0].funder_award_id | PNC0000007 |
| awards[0].funder_display_name | Ministero dell'Università e della Ricerca |
| awards[1].id | https://openalex.org/G8067344408 |
| awards[1].funder_id | https://openalex.org/F4320331528 |
| awards[1].display_name | |
| awards[1].funder_award_id | C93C22005230007 |
| awards[1].funder_display_name | Ministero dell'Università e della Ricerca |
| biblio.issue | 11 |
| biblio.volume | 162 |
| biblio.last_page | |
| biblio.first_page | |
| topics[0].id | https://openalex.org/T10611 |
| topics[0].field.id | https://openalex.org/fields/22 |
| topics[0].field.display_name | Engineering |
| topics[0].score | 0.9994999766349792 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/2208 |
| topics[0].subfield.display_name | Electrical and Electronic Engineering |
| topics[0].display_name | Organic Light-Emitting Diodes Research |
| topics[1].id | https://openalex.org/T11129 |
| topics[1].field.id | https://openalex.org/fields/16 |
| topics[1].field.display_name | Chemistry |
| topics[1].score | 0.9990000128746033 |
| topics[1].domain.id | https://openalex.org/domains/3 |
| topics[1].domain.display_name | Physical Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/1606 |
| topics[1].subfield.display_name | Physical and Theoretical Chemistry |
| topics[1].display_name | Photochemistry and Electron Transfer Studies |
| topics[2].id | https://openalex.org/T10660 |
| topics[2].field.id | https://openalex.org/fields/25 |
| topics[2].field.display_name | Materials Science |
| topics[2].score | 0.9980000257492065 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/2507 |
| topics[2].subfield.display_name | Polymers and Plastics |
| topics[2].display_name | Conducting polymers and applications |
| funders[0].id | https://openalex.org/F4320331528 |
| funders[0].ror | |
| funders[0].display_name | Ministero dell'Università e della Ricerca |
| is_xpac | False |
| apc_list.value | 3500 |
| apc_list.currency | USD |
| apc_list.value_usd | 3500 |
| apc_paid.value | 3500 |
| apc_paid.currency | USD |
| apc_paid.value_usd | 3500 |
| concepts[0].id | https://openalex.org/C75079739 |
| concepts[0].level | 2 |
| concepts[0].score | 0.8344511985778809 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q1571801 |
| concepts[0].display_name | Intramolecular force |
| concepts[1].id | https://openalex.org/C187961010 |
| concepts[1].level | 2 |
| concepts[1].score | 0.8293570280075073 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q260463 |
| concepts[1].display_name | Electron paramagnetic resonance |
| concepts[2].id | https://openalex.org/C185592680 |
| concepts[2].level | 0 |
| concepts[2].score | 0.654450535774231 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[2].display_name | Chemistry |
| concepts[3].id | https://openalex.org/C123669783 |
| concepts[3].level | 2 |
| concepts[3].score | 0.6291123628616333 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q902898 |
| concepts[3].display_name | Electron transfer |
| concepts[4].id | https://openalex.org/C168900304 |
| concepts[4].level | 2 |
| concepts[4].score | 0.5924347639083862 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q171407 |
| concepts[4].display_name | Valence (chemistry) |
| concepts[5].id | https://openalex.org/C2776211377 |
| concepts[5].level | 3 |
| concepts[5].score | 0.5713943243026733 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q417934 |
| concepts[5].display_name | Fluorene |
| concepts[6].id | https://openalex.org/C32891209 |
| concepts[6].level | 2 |
| concepts[6].score | 0.5155441761016846 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q483666 |
| concepts[6].display_name | Spectroscopy |
| concepts[7].id | https://openalex.org/C159467904 |
| concepts[7].level | 1 |
| concepts[7].score | 0.4676945209503174 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q2001702 |
| concepts[7].display_name | Chemical physics |
| concepts[8].id | https://openalex.org/C32909587 |
| concepts[8].level | 2 |
| concepts[8].score | 0.43285924196243286 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q11369 |
| concepts[8].display_name | Molecule |
| concepts[9].id | https://openalex.org/C147789679 |
| concepts[9].level | 1 |
| concepts[9].score | 0.36878547072410583 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q11372 |
| concepts[9].display_name | Physical chemistry |
| concepts[10].id | https://openalex.org/C75473681 |
| concepts[10].level | 1 |
| concepts[10].score | 0.33793288469314575 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q188651 |
| concepts[10].display_name | Photochemistry |
| concepts[11].id | https://openalex.org/C46141821 |
| concepts[11].level | 1 |
| concepts[11].score | 0.1504257321357727 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q209402 |
| concepts[11].display_name | Nuclear magnetic resonance |
| concepts[12].id | https://openalex.org/C521977710 |
| concepts[12].level | 2 |
| concepts[12].score | 0.12867999076843262 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q81163 |
| concepts[12].display_name | Polymer |
| concepts[13].id | https://openalex.org/C178790620 |
| concepts[13].level | 1 |
| concepts[13].score | 0.1278703510761261 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[13].display_name | Organic chemistry |
| concepts[14].id | https://openalex.org/C121332964 |
| concepts[14].level | 0 |
| concepts[14].score | 0.05685216188430786 |
| concepts[14].wikidata | https://www.wikidata.org/wiki/Q413 |
| concepts[14].display_name | Physics |
| concepts[15].id | https://openalex.org/C62520636 |
| concepts[15].level | 1 |
| concepts[15].score | 0.0 |
| concepts[15].wikidata | https://www.wikidata.org/wiki/Q944 |
| concepts[15].display_name | Quantum mechanics |
| keywords[0].id | https://openalex.org/keywords/intramolecular-force |
| keywords[0].score | 0.8344511985778809 |
| keywords[0].display_name | Intramolecular force |
| keywords[1].id | https://openalex.org/keywords/electron-paramagnetic-resonance |
| keywords[1].score | 0.8293570280075073 |
| keywords[1].display_name | Electron paramagnetic resonance |
| keywords[2].id | https://openalex.org/keywords/chemistry |
| keywords[2].score | 0.654450535774231 |
| keywords[2].display_name | Chemistry |
| keywords[3].id | https://openalex.org/keywords/electron-transfer |
| keywords[3].score | 0.6291123628616333 |
| keywords[3].display_name | Electron transfer |
| keywords[4].id | https://openalex.org/keywords/valence |
| keywords[4].score | 0.5924347639083862 |
| keywords[4].display_name | Valence (chemistry) |
| keywords[5].id | https://openalex.org/keywords/fluorene |
| keywords[5].score | 0.5713943243026733 |
| keywords[5].display_name | Fluorene |
| keywords[6].id | https://openalex.org/keywords/spectroscopy |
| keywords[6].score | 0.5155441761016846 |
| keywords[6].display_name | Spectroscopy |
| keywords[7].id | https://openalex.org/keywords/chemical-physics |
| keywords[7].score | 0.4676945209503174 |
| keywords[7].display_name | Chemical physics |
| keywords[8].id | https://openalex.org/keywords/molecule |
| keywords[8].score | 0.43285924196243286 |
| keywords[8].display_name | Molecule |
| keywords[9].id | https://openalex.org/keywords/physical-chemistry |
| keywords[9].score | 0.36878547072410583 |
| keywords[9].display_name | Physical chemistry |
| keywords[10].id | https://openalex.org/keywords/photochemistry |
| keywords[10].score | 0.33793288469314575 |
| keywords[10].display_name | Photochemistry |
| keywords[11].id | https://openalex.org/keywords/nuclear-magnetic-resonance |
| keywords[11].score | 0.1504257321357727 |
| keywords[11].display_name | Nuclear magnetic resonance |
| keywords[12].id | https://openalex.org/keywords/polymer |
| keywords[12].score | 0.12867999076843262 |
| keywords[12].display_name | Polymer |
| keywords[13].id | https://openalex.org/keywords/organic-chemistry |
| keywords[13].score | 0.1278703510761261 |
| keywords[13].display_name | Organic chemistry |
| keywords[14].id | https://openalex.org/keywords/physics |
| keywords[14].score | 0.05685216188430786 |
| keywords[14].display_name | Physics |
| language | en |
| locations[0].id | doi:10.1063/5.0249934 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S77047749 |
| locations[0].source.issn | 0021-9606, 1089-7690, 1520-9032 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | False |
| locations[0].source.issn_l | 0021-9606 |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | False |
| locations[0].source.display_name | The Journal of Chemical Physics |
| locations[0].source.host_organization | https://openalex.org/P4310320257 |
| locations[0].source.host_organization_name | American Institute of Physics |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310320257 |
| locations[0].source.host_organization_lineage_names | American Institute of Physics |
| locations[0].license | cc-by |
| locations[0].pdf_url | https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdf |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | https://openalex.org/licenses/cc-by |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | The Journal of Chemical Physics |
| locations[0].landing_page_url | https://doi.org/10.1063/5.0249934 |
| locations[1].id | pmid:40094238 |
| locations[1].is_oa | False |
| locations[1].source.id | https://openalex.org/S4306525036 |
| locations[1].source.issn | |
| locations[1].source.type | repository |
| locations[1].source.is_oa | False |
| locations[1].source.issn_l | |
| locations[1].source.is_core | False |
| locations[1].source.is_in_doaj | False |
| locations[1].source.display_name | PubMed |
| locations[1].source.host_organization | https://openalex.org/I1299303238 |
| locations[1].source.host_organization_name | National Institutes of Health |
| locations[1].source.host_organization_lineage | https://openalex.org/I1299303238 |
| locations[1].license | |
| locations[1].pdf_url | |
| locations[1].version | publishedVersion |
| locations[1].raw_type | |
| locations[1].license_id | |
| locations[1].is_accepted | True |
| locations[1].is_published | True |
| locations[1].raw_source_name | The Journal of chemical physics |
| locations[1].landing_page_url | https://pubmed.ncbi.nlm.nih.gov/40094238 |
| locations[2].id | pmh:oai:www.research.unipd.it:11577/3554054 |
| locations[2].is_oa | True |
| locations[2].source.id | https://openalex.org/S4306402448 |
| locations[2].source.issn | |
| locations[2].source.type | repository |
| locations[2].source.is_oa | False |
| locations[2].source.issn_l | |
| locations[2].source.is_core | False |
| locations[2].source.is_in_doaj | False |
| locations[2].source.display_name | Padua Research Archive (University of Padua) |
| locations[2].source.host_organization | https://openalex.org/I138689650 |
| locations[2].source.host_organization_name | University of Padua |
| locations[2].source.host_organization_lineage | https://openalex.org/I138689650 |
| locations[2].license | other-oa |
| locations[2].pdf_url | |
| locations[2].version | submittedVersion |
| locations[2].raw_type | info:eu-repo/semantics/article |
| locations[2].license_id | https://openalex.org/licenses/other-oa |
| locations[2].is_accepted | False |
| locations[2].is_published | False |
| locations[2].raw_source_name | |
| locations[2].landing_page_url | https://hdl.handle.net/11577/3554054 |
| indexed_in | crossref, pubmed |
| authorships[0].author.id | https://openalex.org/A5027413114 |
| authorships[0].author.orcid | https://orcid.org/0000-0002-8877-315X |
| authorships[0].author.display_name | Alessandro Agostini |
| authorships[0].countries | IT |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I138689650 |
| authorships[0].affiliations[0].raw_affiliation_string | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[0].institutions[0].id | https://openalex.org/I138689650 |
| authorships[0].institutions[0].ror | https://ror.org/00240q980 |
| authorships[0].institutions[0].type | education |
| authorships[0].institutions[0].lineage | https://openalex.org/I138689650 |
| authorships[0].institutions[0].country_code | IT |
| authorships[0].institutions[0].display_name | University of Padua |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Alessandro Agostini |
| authorships[0].is_corresponding | False |
| authorships[0].raw_affiliation_strings | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[1].author.id | https://openalex.org/A5020306387 |
| authorships[1].author.orcid | https://orcid.org/0000-0003-2173-9018 |
| authorships[1].author.display_name | Mirco Zerbetto |
| authorships[1].countries | IT |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I138689650 |
| authorships[1].affiliations[0].raw_affiliation_string | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[1].institutions[0].id | https://openalex.org/I138689650 |
| authorships[1].institutions[0].ror | https://ror.org/00240q980 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I138689650 |
| authorships[1].institutions[0].country_code | IT |
| authorships[1].institutions[0].display_name | University of Padua |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Mirco Zerbetto |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[2].author.id | https://openalex.org/A5116662297 |
| authorships[2].author.orcid | |
| authorships[2].author.display_name | Davide Sartori |
| authorships[2].countries | IT |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I138689650 |
| authorships[2].affiliations[0].raw_affiliation_string | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[2].institutions[0].id | https://openalex.org/I138689650 |
| authorships[2].institutions[0].ror | https://ror.org/00240q980 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I138689650 |
| authorships[2].institutions[0].country_code | IT |
| authorships[2].institutions[0].display_name | University of Padua |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Davide Sartori |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[3].author.id | https://openalex.org/A5092567077 |
| authorships[3].author.orcid | |
| authorships[3].author.display_name | Samuel Zatta |
| authorships[3].countries | IT |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I138689650 |
| authorships[3].affiliations[0].raw_affiliation_string | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[3].institutions[0].id | https://openalex.org/I138689650 |
| authorships[3].institutions[0].ror | https://ror.org/00240q980 |
| authorships[3].institutions[0].type | education |
| authorships[3].institutions[0].lineage | https://openalex.org/I138689650 |
| authorships[3].institutions[0].country_code | IT |
| authorships[3].institutions[0].display_name | University of Padua |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Samuel Zatta |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[4].author.id | https://openalex.org/A5047587975 |
| authorships[4].author.orcid | https://orcid.org/0000-0001-6441-3689 |
| authorships[4].author.display_name | Antonino Polimeno |
| authorships[4].countries | IT |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I138689650 |
| authorships[4].affiliations[0].raw_affiliation_string | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[4].institutions[0].id | https://openalex.org/I138689650 |
| authorships[4].institutions[0].ror | https://ror.org/00240q980 |
| authorships[4].institutions[0].type | education |
| authorships[4].institutions[0].lineage | https://openalex.org/I138689650 |
| authorships[4].institutions[0].country_code | IT |
| authorships[4].institutions[0].display_name | University of Padua |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Antonino Polimeno |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[5].author.id | https://openalex.org/A5011644331 |
| authorships[5].author.orcid | https://orcid.org/0000-0003-4755-4011 |
| authorships[5].author.display_name | Agostina Lina Capodilupo |
| authorships[5].countries | IT |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I4210091015 |
| authorships[5].affiliations[0].raw_affiliation_string | CNR-NANOTEC Institute of Nanotechnology, c/o Campus Ecotekne, Via Monteroni, 73100 Lecce, Italy |
| authorships[5].institutions[0].id | https://openalex.org/I4210091015 |
| authorships[5].institutions[0].ror | https://ror.org/00bc51d88 |
| authorships[5].institutions[0].type | facility |
| authorships[5].institutions[0].lineage | https://openalex.org/I4210091015, https://openalex.org/I4210155236 |
| authorships[5].institutions[0].country_code | IT |
| authorships[5].institutions[0].display_name | Istituto di Nanotecnologia |
| authorships[5].author_position | middle |
| authorships[5].raw_author_name | Agostina Lina Capodilupo |
| authorships[5].is_corresponding | False |
| authorships[5].raw_affiliation_strings | CNR-NANOTEC Institute of Nanotechnology, c/o Campus Ecotekne, Via Monteroni, 73100 Lecce, Italy |
| authorships[6].author.id | https://openalex.org/A5078606132 |
| authorships[6].author.orcid | https://orcid.org/0000-0003-3548-4423 |
| authorships[6].author.display_name | Lorenzo Franco |
| authorships[6].countries | IT |
| authorships[6].affiliations[0].institution_ids | https://openalex.org/I138689650 |
| authorships[6].affiliations[0].raw_affiliation_string | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| authorships[6].institutions[0].id | https://openalex.org/I138689650 |
| authorships[6].institutions[0].ror | https://ror.org/00240q980 |
| authorships[6].institutions[0].type | education |
| authorships[6].institutions[0].lineage | https://openalex.org/I138689650 |
| authorships[6].institutions[0].country_code | IT |
| authorships[6].institutions[0].display_name | University of Padua |
| authorships[6].author_position | last |
| authorships[6].raw_author_name | Lorenzo Franco |
| authorships[6].is_corresponding | False |
| authorships[6].raw_affiliation_strings | Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy |
| has_content.pdf | True |
| has_content.grobid_xml | False |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdf |
| open_access.oa_status | hybrid |
| open_access.any_repository_has_fulltext | False |
| created_date | 2025-10-10T00:00:00 |
| display_name | Determination of the intervalence charge-transfer rate in mixed-valence arylamino-fluorene derivatives using EPR spectroscopy |
| has_fulltext | False |
| is_retracted | False |
| updated_date | 2025-11-06T06:51:31.235846 |
| primary_topic.id | https://openalex.org/T10611 |
| primary_topic.field.id | https://openalex.org/fields/22 |
| primary_topic.field.display_name | Engineering |
| primary_topic.score | 0.9994999766349792 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/2208 |
| primary_topic.subfield.display_name | Electrical and Electronic Engineering |
| primary_topic.display_name | Organic Light-Emitting Diodes Research |
| related_works | https://openalex.org/W2012612523, https://openalex.org/W3015923159, https://openalex.org/W2092624719, https://openalex.org/W2010759031, https://openalex.org/W3142667992, https://openalex.org/W2895520617, https://openalex.org/W3115196230, https://openalex.org/W2066271730, https://openalex.org/W1970953740, https://openalex.org/W1985676851 |
| cited_by_count | 0 |
| locations_count | 3 |
| best_oa_location.id | doi:10.1063/5.0249934 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S77047749 |
| best_oa_location.source.issn | 0021-9606, 1089-7690, 1520-9032 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | False |
| best_oa_location.source.issn_l | 0021-9606 |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | False |
| best_oa_location.source.display_name | The Journal of Chemical Physics |
| best_oa_location.source.host_organization | https://openalex.org/P4310320257 |
| best_oa_location.source.host_organization_name | American Institute of Physics |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310320257 |
| best_oa_location.source.host_organization_lineage_names | American Institute of Physics |
| best_oa_location.license | cc-by |
| best_oa_location.pdf_url | https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdf |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | https://openalex.org/licenses/cc-by |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | The Journal of Chemical Physics |
| best_oa_location.landing_page_url | https://doi.org/10.1063/5.0249934 |
| primary_location.id | doi:10.1063/5.0249934 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S77047749 |
| primary_location.source.issn | 0021-9606, 1089-7690, 1520-9032 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | False |
| primary_location.source.issn_l | 0021-9606 |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | False |
| primary_location.source.display_name | The Journal of Chemical Physics |
| primary_location.source.host_organization | https://openalex.org/P4310320257 |
| primary_location.source.host_organization_name | American Institute of Physics |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310320257 |
| primary_location.source.host_organization_lineage_names | American Institute of Physics |
| primary_location.license | cc-by |
| primary_location.pdf_url | https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/5.0249934/20441248/114303_1_5.0249934.pdf |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | https://openalex.org/licenses/cc-by |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | The Journal of Chemical Physics |
| primary_location.landing_page_url | https://doi.org/10.1063/5.0249934 |
| publication_date | 2025-03-17 |
| publication_year | 2025 |
| referenced_works | https://openalex.org/W2996794239, https://openalex.org/W2001004606, https://openalex.org/W4323869345, https://openalex.org/W1997418114, https://openalex.org/W2045960816, https://openalex.org/W2202098509, https://openalex.org/W2137143835, https://openalex.org/W2138289499, https://openalex.org/W2469752349, https://openalex.org/W2606854257, https://openalex.org/W2021644247, https://openalex.org/W2801857725, https://openalex.org/W4402759511, https://openalex.org/W4385383405, https://openalex.org/W4210745493, https://openalex.org/W2467235894, https://openalex.org/W2887256796, https://openalex.org/W4400965009, https://openalex.org/W2733548062, https://openalex.org/W2530367706, https://openalex.org/W2407432290, https://openalex.org/W2793628223, https://openalex.org/W2069474336, https://openalex.org/W2281847788, https://openalex.org/W3159882207, https://openalex.org/W2078613773, https://openalex.org/W1974127696, https://openalex.org/W2153754246, https://openalex.org/W2032451767, https://openalex.org/W2952407772, https://openalex.org/W2913555712, https://openalex.org/W2982255342, https://openalex.org/W4250522622, https://openalex.org/W4231836685, https://openalex.org/W2323902508, https://openalex.org/W2068920247, https://openalex.org/W3009361645, https://openalex.org/W2951206313, https://openalex.org/W2327987494, https://openalex.org/W3197360079, https://openalex.org/W2089662946, https://openalex.org/W2147207908, https://openalex.org/W2904831290, https://openalex.org/W2797629760 |
| referenced_works_count | 44 |
| abstract_inverted_index.a | 8, 47, 61, 88, 99, 106, 136 |
| abstract_inverted_index.In | 15 |
| abstract_inverted_index.MV | 50, 80 |
| abstract_inverted_index.We | 39 |
| abstract_inverted_index.as | 115 |
| abstract_inverted_index.at | 92 |
| abstract_inverted_index.by | 60, 71 |
| abstract_inverted_index.in | 46, 87, 105 |
| abstract_inverted_index.is | 68 |
| abstract_inverted_index.of | 5, 10, 36, 49, 73, 90, 120, 124, 141 |
| abstract_inverted_index.on | 79, 129 |
| abstract_inverted_index.to | 134 |
| abstract_inverted_index.us | 133 |
| abstract_inverted_index.EPR | 84 |
| abstract_inverted_index.The | 65, 83, 118 |
| abstract_inverted_index.and | 12, 34, 145 |
| abstract_inverted_index.are | 4, 57 |
| abstract_inverted_index.for | 7 |
| abstract_inverted_index.out | 70 |
| abstract_inverted_index.the | 20, 32, 41, 110, 116, 121, 125, 130, 139, 142 |
| abstract_inverted_index.two | 25, 54 |
| abstract_inverted_index.(MV) | 18 |
| abstract_inverted_index.free | 122 |
| abstract_inverted_index.jump | 102 |
| abstract_inverted_index.rate | 114 |
| abstract_inverted_index.some | 146 |
| abstract_inverted_index.were | 95 |
| abstract_inverted_index.(EPR) | 77 |
| abstract_inverted_index.about | 31 |
| abstract_inverted_index.means | 72 |
| abstract_inverted_index.model | 103 |
| abstract_inverted_index.redox | 26 |
| abstract_inverted_index.units | 56 |
| abstract_inverted_index.using | 98 |
| abstract_inverted_index.where | 53 |
| abstract_inverted_index.charge | 22, 43, 112, 143 |
| abstract_inverted_index.energy | 123 |
| abstract_inverted_index.length | 63 |
| abstract_inverted_index.linked | 58 |
| abstract_inverted_index.offers | 28 |
| abstract_inverted_index.random | 101 |
| abstract_inverted_index.series | 48, 89 |
| abstract_inverted_index.allowed | 132 |
| abstract_inverted_index.between | 24, 138 |
| abstract_inverted_index.bridge. | 64 |
| abstract_inverted_index.carried | 69 |
| abstract_inverted_index.centers | 27 |
| abstract_inverted_index.organic | 16, 51 |
| abstract_inverted_index.output. | 117 |
| abstract_inverted_index.process | 45, 128 |
| abstract_inverted_index.radical | 81 |
| abstract_inverted_index.solvent | 131, 147 |
| abstract_inverted_index.variety | 9 |
| abstract_inverted_index.Electron | 74 |
| abstract_inverted_index.cations. | 82 |
| abstract_inverted_index.electron | 37, 126 |
| abstract_inverted_index.hopping. | 38 |
| abstract_inverted_index.identify | 135 |
| abstract_inverted_index.insights | 30 |
| abstract_inverted_index.interest | 6 |
| abstract_inverted_index.kinetics | 33 |
| abstract_inverted_index.recorded | 86 |
| abstract_inverted_index.routine, | 108 |
| abstract_inverted_index.software | 107 |
| abstract_inverted_index.solvents | 91 |
| abstract_inverted_index.spectra, | 85 |
| abstract_inverted_index.systems, | 19 |
| abstract_inverted_index.together | 59 |
| abstract_inverted_index.transfer | 23, 44, 113, 127, 144 |
| abstract_inverted_index.valuable | 29 |
| abstract_inverted_index.variable | 62 |
| abstract_inverted_index.Resonance | 76 |
| abstract_inverted_index.Thermally | 0 |
| abstract_inverted_index.activated | 1 |
| abstract_inverted_index.arylamino | 55 |
| abstract_inverted_index.different | 93 |
| abstract_inverted_index.energetic | 140 |
| abstract_inverted_index.molecules | 52 |
| abstract_inverted_index.processes | 3 |
| abstract_inverted_index.providing | 109 |
| abstract_inverted_index.simulated | 97 |
| abstract_inverted_index.adequately | 96 |
| abstract_inverted_index.dependence | 119 |
| abstract_inverted_index.energetics | 35 |
| abstract_inverted_index.correlation | 137 |
| abstract_inverted_index.implemented | 104 |
| abstract_inverted_index.properties. | 148 |
| abstract_inverted_index.theoretical | 11 |
| abstract_inverted_index.Paramagnetic | 75 |
| abstract_inverted_index.experimental | 66 |
| abstract_inverted_index.investigated | 40 |
| abstract_inverted_index.spectroscopy | 78 |
| abstract_inverted_index.applications. | 14 |
| abstract_inverted_index.investigation | 67 |
| abstract_inverted_index.mixed-valence | 17 |
| abstract_inverted_index.multiple-site | 100 |
| abstract_inverted_index.technological | 13 |
| abstract_inverted_index.temperatures, | 94 |
| abstract_inverted_index.intramolecular | 21, 42, 111 |
| abstract_inverted_index.electron-transfer | 2 |
| cited_by_percentile_year | |
| countries_distinct_count | 1 |
| institutions_distinct_count | 7 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/7 |
| sustainable_development_goals[0].score | 0.7799999713897705 |
| sustainable_development_goals[0].display_name | Affordable and clean energy |
| citation_normalized_percentile.value | 0.07937603 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |