Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO2 capture from synthetic gas containing CO2 and H2 Article Swipe
Ili Khairunnisa Shamsudin
,
Imad A. Idris
,
Anas Abdullah
,
Jeong Hyun Kim
,
Mohd Roslee Othman
·
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.1063/1.5117117
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.1063/1.5117117
A well-defined Zr-metal organic framework (UiO-66) was developed using a rapid sol-gel reflux method and activated by solvent exchange, drying and heating. The activation process with an exchangeable guest solvent produced Zr-MOF with high surface area by removal of almost all the guest and terephthalic acid molecules from the pores, thereby enhancing its capacity for adsorption. The results showed that UiO-66 was synthesized in octahedral crystals of n formed s es of 6 63 m with specific surface area of 313 m2/g. The sample, known to exhibit high chemical and thermal stability of up to 500 C demonstrated strong affinity for carbon dioxide with adsorption capacity of 428.7 cc (CO2) g 1 at STP. Results from pressure swing adsorption (PSA) experiment with synthesis gas feed mixture containing 15 vol.% of CO2 and 85 vol.% indicate that the as–synthesized sample has the potential for effective CO2/H2 separation.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1063/1.5117117
- https://aip.scitation.org/doi/pdf/10.1063/1.5117117
- OA Status
- bronze
- Cited By
- 8
- References
- 25
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2964239290
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2964239290Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1063/1.5117117Digital Object Identifier
- Title
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Development of microporous Zr-MOF UiO-66 by sol-gel synthesis for CO2 capture from synthetic gas containing CO2 and H2Work title
- Type
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articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
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2019Year of publication
- Publication date
-
2019-01-01Full publication date if available
- Authors
-
Ili Khairunnisa Shamsudin, Imad A. Idris, Anas Abdullah, Jeong Hyun Kim, Mohd Roslee OthmanList of authors in order
- Landing page
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https://doi.org/10.1063/1.5117117Publisher landing page
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https://aip.scitation.org/doi/pdf/10.1063/1.5117117Direct link to full text PDF
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YesWhether a free full text is available
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bronzeOpen access status per OpenAlex
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https://aip.scitation.org/doi/pdf/10.1063/1.5117117Direct OA link when available
- Concepts
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Microporous material, Adsorption, Terephthalic acid, Solvent, Chemical engineering, Metal-organic framework, Thermal stability, Specific surface area, Materials science, Gas separation, Inorganic chemistry, Chemistry, Organic chemistry, Catalysis, Engineering, Polyester, Biochemistry, MembraneTop concepts (fields/topics) attached by OpenAlex
- Cited by
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8Total citation count in OpenAlex
- Citations by year (recent)
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2025: 2, 2024: 2, 2023: 1, 2022: 1, 2021: 1Per-year citation counts (last 5 years)
- References (count)
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25Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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