Direct observation of core-shell structure and water uptake of individual submicron urban aerosol particles Article Swipe
YOU?
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· 2025
· Open Access
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· DOI: https://doi.org/10.5194/egusphere-2025-2301
Determining the particle chemical morphology is crucial for unraveling reactive uptake in atmospheric multiphase and heterogeneous chemistry. However, it remains challenging due to the complexity and inhomogeneity of aerosols particles. Using a scanning transmission X-ray microscopy (STXM) coupled with near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and an environmental cell, we imaged and quantified the chemical morphology and hygroscopic behavior of individual submicron urban aerosol particles. Results show that internally mixed particles composed of organic carbon and inorganic matter (OCIn) dominated the particle population (73.1 ± 7.4 %). At 86 % relative humidity, 41.6 % of the particles took up water, with OCIn particles constituting 76.8 % of these hygroscopic particles. Most particles exhibited a core-shell structure under both dry and humid conditions, with an inorganic core and an organic shell. Our findings provide direct observational evidence of the core-shell structure and water uptake behavior of typical urban aerosols, which underscore the importance of incorporating the core-shell structure into models for predicting the reactive uptake coefficient of heterogeneous reactions.
Related Topics
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.5194/egusphere-2025-2301
- https://egusphere.copernicus.org/preprints/2025/egusphere-2025-2301/egusphere-2025-2301.pdf
- OA Status
- gold
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4411181434
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4411181434Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.5194/egusphere-2025-2301Digital Object Identifier
- Title
-
Direct observation of core-shell structure and water uptake of individual submicron urban aerosol particlesWork title
- Type
-
preprintOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2025Year of publication
- Publication date
-
2025-06-10Full publication date if available
- Authors
-
Ruiqi Man, Y. C. Zhu, Zhijun Wu, Peter A. Alpert, Bingbing Wang, Jing Dou, Jie Chen, Yan Zheng, Yanli Ge, Qi Chen, Shiyi Chen, Xiangrui Kong, Markus Ammann, Min HuList of authors in order
- Landing page
-
https://doi.org/10.5194/egusphere-2025-2301Publisher landing page
- PDF URL
-
https://egusphere.copernicus.org/preprints/2025/egusphere-2025-2301/egusphere-2025-2301.pdfDirect link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://egusphere.copernicus.org/preprints/2025/egusphere-2025-2301/egusphere-2025-2301.pdfDirect OA link when available
- Concepts
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Aerosol, Core (optical fiber), Shell (structure), Materials science, Nanotechnology, Chemical physics, Environmental science, Atmospheric sciences, Physics, Meteorology, Composite materialTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
0Total citation count in OpenAlex
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.structure | 44, 117, 141, 158 |
| abstract_inverted_index.submicron | 63 |
| abstract_inverted_index.absorption | 42 |
| abstract_inverted_index.chemistry. | 17 |
| abstract_inverted_index.complexity | 25 |
| abstract_inverted_index.core-shell | 116, 140, 157 |
| abstract_inverted_index.importance | 153 |
| abstract_inverted_index.individual | 62 |
| abstract_inverted_index.internally | 70 |
| abstract_inverted_index.microscopy | 36 |
| abstract_inverted_index.morphology | 5, 57 |
| abstract_inverted_index.multiphase | 14 |
| abstract_inverted_index.particles. | 30, 66, 111 |
| abstract_inverted_index.population | 84 |
| abstract_inverted_index.predicting | 162 |
| abstract_inverted_index.quantified | 54 |
| abstract_inverted_index.reactions. | 169 |
| abstract_inverted_index.underscore | 151 |
| abstract_inverted_index.unraveling | 9 |
| abstract_inverted_index.Determining | 1 |
| abstract_inverted_index.atmospheric | 13 |
| abstract_inverted_index.challenging | 21 |
| abstract_inverted_index.coefficient | 166 |
| abstract_inverted_index.conditions, | 123 |
| abstract_inverted_index.hygroscopic | 59, 110 |
| abstract_inverted_index.constituting | 105 |
| abstract_inverted_index.spectroscopy | 46 |
| abstract_inverted_index.transmission | 34 |
| abstract_inverted_index.environmental | 49 |
| abstract_inverted_index.heterogeneous | 16, 168 |
| abstract_inverted_index.incorporating | 155 |
| abstract_inverted_index.inhomogeneity | 27 |
| abstract_inverted_index.observational | 136 |
| cited_by_percentile_year | |
| countries_distinct_count | 0 |
| institutions_distinct_count | 14 |
| citation_normalized_percentile.value | 0.23487494 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |