Direct observation of photoinduced sequential spin transition in a halogen-bonded hybrid system by complementary ultrafast optical and electron probes Article Swipe

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Yifeng Jiang , Stuart A. Hayes , Simon F. Bittmann , Antoine Sarracini , Lai Chung Liu , Henrike M. Müller‐Werkmeister , Atsuhiro Miyawaki , Masaki Hada , Shinnosuke Nakano , Ryoya Takahashi , Samiran Banu , Shin‐ya Koshihara , Kazuyuki Takahashi , T. Ishikawa , R. J. Dwayne Miller ·

YOU? · · 2024 · Open Access · · DOI: https://doi.org/10.1038/s41467-024-48529-1

A detailed understanding of the ultrafast dynamics of halogen-bonded materials is desired for designing supramolecular materials and tuning various electronic properties by external stimuli. Here, a prototypical halogen-bonded multifunctional material containing spin crossover (SCO) cations and paramagnetic radical anions is studied as a model system of photo-switchable SCO hybrid systems using ultrafast electron diffraction and two complementary optical spectroscopic techniques. Our results reveal a sequential dynamics from SCO to radical dimer softening, uncovering a key transient intermediate state. In combination with quantum chemistry calculations, we demonstrate the presence of halogen bonds in the low- and high-temperature phases and propose their role during the photoinduced sequential dynamics, underscoring the significance of exploring ultrafast dynamics. Our research highlights the promising utility of halogen bonds in finely tuning functional properties across diverse photoactive multifunctional materials.

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Ultrashort pulse Halogen Chemical physics Halogen bond Materials science Supramolecular chemistry Spin crossover Photochemistry Electron Nanotechnology Chemistry Molecule Crystallography Physics Alkyl Organic chemistry Optics Laser Quantum mechanics

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Type: article
Language: en
Landing Page: https://doi.org/10.1038/s41467-024-48529-1
PDF: https://www.nature.com/articles/s41467-024-48529-1.pdf
OA Status: gold
Cited By: 2
References: 65
Related Works: 10
OpenAlex ID: https://openalex.org/W4399336486

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DOI: https://doi.org/10.1038/s41467-024-48529-1

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Title: Direct observation of photoinduced sequential spin transition in a halogen-bonded hybrid system by complementary ultrafast optical and electron probes

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Language: en

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Publication year: 2024

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Publication date: 2024-06-04

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Authors: Yifeng Jiang, Stuart A. Hayes, Simon F. Bittmann, Antoine Sarracini, Lai Chung Liu, Henrike M. Müller‐Werkmeister, Atsuhiro Miyawaki, Masaki Hada, Shinnosuke Nakano, Ryoya Takahashi, Samiran Banu, Shin‐ya Koshihara, Kazuyuki Takahashi, T. Ishikawa, R. J. Dwayne Miller

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Landing page: https://doi.org/10.1038/s41467-024-48529-1

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PDF URL: https://www.nature.com/articles/s41467-024-48529-1.pdf

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Concepts: Ultrashort pulse, Halogen, Chemical physics, Halogen bond, Materials science, Supramolecular chemistry, Spin crossover, Photochemistry, Electron, Nanotechnology, Chemistry, Molecule, Crystallography, Physics, Alkyl, Organic chemistry, Optics, Laser, Quantum mechanics

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Cited by: 2

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