Direct Oxidative Azo Coupling of Anilines Using a Self-Assembled Flower-like CuCo2O4 Material as a Catalyst under Aerobic Conditions Article Swipe
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· 2020
· Open Access
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· DOI: https://doi.org/10.1021/acsomega.0c03562
Herein, we report the synthesis of a self-assembled flower-like CuCo2O4 material by the oxalate decomposition method. The crystalline structure and morphology of the material have been analyzed by powder X-ray diffraction, Raman spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray measurement techniques. The self-assembled flower-like CuCo2O4 material showed remarkable catalytic activity in the direct aerobic oxidative azo coupling of anilines under oxidant and other additive-free reaction conditions. The mechanistic insight of CuCo2O4 in the oxidative azo coupling reaction has been established by density functional theory calculations, which disclosed that the absorption and dissociation of areal oxygen preferentially take place at the Cu site and dissociation of aniline takes place at the Co site. Thus, the Cu and Co sites of CuCo2O4 exert a cooperative effect on the direct oxidative azo coupling reactions through the selective activation of anilines and aerobic oxygen. The CuCo2O4 material was recovered from the reaction mixture and reused for at least eight runs without appreciable loss of catalytic activity.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsomega.0c03562
- https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03562
- OA Status
- gold
- Cited By
- 30
- References
- 68
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3105285076
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W3105285076Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsomega.0c03562Digital Object Identifier
- Title
-
Direct Oxidative Azo Coupling of Anilines Using a Self-Assembled Flower-like CuCo2O4 Material as a Catalyst under Aerobic ConditionsWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2020Year of publication
- Publication date
-
2020-11-17Full publication date if available
- Authors
-
Ashok R. Patel, Geetika Patel, G. Maity, Shiv P. Patel, Sumantra Bhattacharya, Anjaneyulu Putta, Subhash BanerjeeList of authors in order
- Landing page
-
https://doi.org/10.1021/acsomega.0c03562Publisher landing page
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https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03562Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03562Direct OA link when available
- Concepts
-
Catalysis, Aniline, Oxidative coupling of methane, Dissociation (chemistry), Chemistry, Transmission electron microscopy, Raman spectroscopy, Density functional theory, Photochemistry, Oxidative phosphorylation, Oxygen, Oxalate, Inorganic chemistry, Nuclear chemistry, Organic chemistry, Materials science, Nanotechnology, Computational chemistry, Physics, Optics, BiochemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
30Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 11, 2024: 6, 2023: 5, 2022: 4, 2021: 4Per-year citation counts (last 5 years)
- References (count)
-
68Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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