Distinguishing Heterogeneous and Homogeneous CE Mechanisms: Theoretical Insights into Square-Wave Voltammetry Article Swipe
Valentin Mirčeski
,
Rubin Gulaboski
,
Richard G. Compton
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpcc.2c07298
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpcc.2c07298
A theoretical study of an electrode mechanism where the electrode reaction (E) is preceded by a chemical reaction that takes place solely at the electrode surface (Chet) is presented under conditions of square-wave voltammetry (SWV). Rigorous mathematical solutions in the form of integral equations derived by means of Laplace transforms are presented for the surface concentration of all species involved in the electrode mechanism, yielding explicit recurrent formulas for the simulation of the voltammetric response. The theory approximately predicts that the chemical reaction starts at the beginning of the voltammetric experiment, disregarding its occurrence in the short time period between inserting the electrode in the solution until starting the voltammetric experiment. It is demonstrated that SWV can differentiate between the common CE mechanism, where C is a homogeneous chemical reaction taking place in the vicinity of the electrode, and the current ChetE mechanism, which is relevant for plethora of electrocatalytic processes at electrodes modified with catalytically active enzymes and/or noble-metal nanoparticles, as well as for electrocatalytic processes of fundamental importance such as CO2, N2, O2, and H+ reductions
Related Topics
Concepts
Electrode
Voltammetry
Laplace transform
Homogeneous
Square wave
Cyclic voltammetry
Reaction mechanism
Chemistry
Chemical reaction
Noble metal
Electrochemistry
Analytical Chemistry (journal)
Metal
Materials science
Thermodynamics
Physical chemistry
Catalysis
Physics
Mathematical analysis
Mathematics
Quantum mechanics
Chromatography
Organic chemistry
Voltage
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.jpcc.2c07298
- https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.2c07298
- OA Status
- hybrid
- Cited By
- 4
- References
- 36
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4319458383
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4319458383Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.jpcc.2c07298Digital Object Identifier
- Title
-
Distinguishing Heterogeneous and Homogeneous CE Mechanisms: Theoretical Insights into Square-Wave VoltammetryWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2023Year of publication
- Publication date
-
2023-02-08Full publication date if available
- Authors
-
Valentin Mirčeski, Rubin Gulaboski, Richard G. ComptonList of authors in order
- Landing page
-
https://doi.org/10.1021/acs.jpcc.2c07298Publisher landing page
- PDF URL
-
https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.2c07298Direct link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
-
hybridOpen access status per OpenAlex
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https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.2c07298Direct OA link when available
- Concepts
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Electrode, Voltammetry, Laplace transform, Homogeneous, Square wave, Cyclic voltammetry, Reaction mechanism, Chemistry, Chemical reaction, Noble metal, Electrochemistry, Analytical Chemistry (journal), Metal, Materials science, Thermodynamics, Physical chemistry, Catalysis, Physics, Mathematical analysis, Mathematics, Quantum mechanics, Chromatography, Organic chemistry, VoltageTop concepts (fields/topics) attached by OpenAlex
- Cited by
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4Total citation count in OpenAlex
- Citations by year (recent)
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2025: 2, 2024: 1, 2023: 1Per-year citation counts (last 5 years)
- References (count)
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36Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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