Effect of Ionizing Radiation Applied to PLA Used as Compatibilizing Agent in Reinforced eGG Shell PBAT/PLA Bio-Based Composites Article Swipe
Elizabeth C.L. Cardoso
,
Duclerc Fernandes Parra
,
Sandra R. Scagliusi
,
Luiz Gustavo Hiroki Komatsu
,
Ademar B. Lugão
·
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.6000/1929-5995.2021.10.4
YOU?
·
· 2021
· Open Access
·
· DOI: https://doi.org/10.6000/1929-5995.2021.10.4
Bio-filler from eggshells as reinforcement of bio-based polymers are based on their benefits as adequate strength and stiffness, besides friendly, degradable and renewable environment. Eggshell is an agricultural waste considered as garbage, contributing to pollution; nevertheless, it can be transformed into bio-calcium carbonate, acquiring new values. As biodegradable polymers, there were chosen PLA (poly-lactic-acid) and PBAT (butylene adipate co-terephthalate), thermoplastics capable to be processed via conventional methods. PLA is a linear, aliphatic thermoplastic polyester, high in strength and modulus, but brittle. PBAT is a synthetic polymer, very flexible, based on fossil resources with high elongation at break, but low strength. It will be required the use of compatibilizers, for reducing interfacial tension exhibited by PLA/PBAT immiscible blend, considering their extreme glass transition temperatures: 62 o C for PLA and – 30 o C for PBAT. Herein it was used ionizing radiation for inducing compatibilization by free radicals, improving dispersion and adhesion of blend phases, without using chemical additives, at room temperature. PLA, acting as compatibilizer, was previously e-beam and gamma radiated, at 150 kGy. PBAT/PLA 50/50 blend with 15 phr of bio-filler from avian eggs 125 µm particle size and both compatibilizers were homogeneized in a co-rotating twin-screw extruder, within a temperature profile 120 to 145 o C, from hopper to die. Characterization involved: Differential Scanning Calorimeter, Thermogravimetric Analyses, Fourier Transform Infrared Spectroscopy, Wide Angle X-Ray Diffraction, Tensile Strength and Elongation at Break.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.6000/1929-5995.2021.10.4
- https://lifescienceglobal.com/pms/index.php/jrups/article/download/7207/3761
- OA Status
- diamond
- Cited By
- 2
- References
- 30
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3159363239
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Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W3159363239Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.6000/1929-5995.2021.10.4Digital Object Identifier
- Title
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Effect of Ionizing Radiation Applied to PLA Used as Compatibilizing Agent in Reinforced eGG Shell PBAT/PLA Bio-Based CompositesWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2021Year of publication
- Publication date
-
2021-03-03Full publication date if available
- Authors
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Elizabeth C.L. Cardoso, Duclerc Fernandes Parra, Sandra R. Scagliusi, Luiz Gustavo Hiroki Komatsu, Ademar B. LugãoList of authors in order
- Landing page
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https://doi.org/10.6000/1929-5995.2021.10.4Publisher landing page
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https://lifescienceglobal.com/pms/index.php/jrups/article/download/7207/3761Direct link to full text PDF
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YesWhether a free full text is available
- OA status
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diamondOpen access status per OpenAlex
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https://lifescienceglobal.com/pms/index.php/jrups/article/download/7207/3761Direct OA link when available
- Concepts
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Materials science, Composite material, Polylactic acid, Thermogravimetric analysis, Ultimate tensile strength, Dynamic mechanical analysis, Compatibilization, Polycarbonate, Polymer, Biodegradable polymer, Chemical engineering, Polymer blend, Copolymer, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
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2Total citation count in OpenAlex
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2025: 2Per-year citation counts (last 5 years)
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30Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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