Effect of MXene as nucleating agent on crystallization behaviour and thermal stability of PET nanocomposites Article Swipe
Yue Yin
,
Runbo Zhang
,
Weiping Wu
,
Zhiqing Liang
,
Jinliang Li
,
Geng Li
,
Jeffrey Xu Yu
,
Xiaoru Gao
,
Xingwei Du
,
Haipeng Wu
,
Yunlong Sun
,
Jun Li
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1088/1742-6596/3061/1/012026
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1088/1742-6596/3061/1/012026
MXene (Ti 3 C 2 T x ) nanosheets were synthesised by selective etching of the Ti 3 AlC 2 MAX phase and subsequently incorporated into polyethylene terephthalate (PET) via solution blending to afford PET/MXene nanocomposites. Owing to their high specific surface area and abundant surface terminations, MXene sheets acted as efficient heterogeneous nucleation sites within the PET matrix. Consequently, the crystallisation peak temperature ( T c ) of the nanocomposite containing 1 wt % MXene (PET-MX-1) rose from 186.4 °C to 212.6 °C and the overall crystallisation rate was markedly accelerated with respect to neat PET. Non-isothermal kinetic analysis confirmed that MXene lowered the apparent crystallisation activation energy and thus enhanced crystallisation kinetics, while thermogravimetric measurements revealed a modest improvement in thermal stability. These findings demonstrate that the introduction of trace amounts of MXene offers a simple yet effective strategy for tailoring the crystallisation behaviour and thermal performance of PET, thereby expanding its potential for high-performance engineering applications.
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- article
- Language
- en
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- https://doi.org/10.1088/1742-6596/3061/1/012026
- OA Status
- diamond
- References
- 22
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https://doi.org/10.1088/1742-6596/3061/1/012026Digital Object Identifier
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Effect of MXene as nucleating agent on crystallization behaviour and thermal stability of PET nanocompositesWork title
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articleOpenAlex work type
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enPrimary language
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2025Year of publication
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2025-08-01Full publication date if available
- Authors
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Yue Yin, Runbo Zhang, Weiping Wu, Zhiqing Liang, Jinliang Li, Geng Li, Jeffrey Xu Yu, Xiaoru Gao, Xingwei Du, Haipeng Wu, Yunlong Sun, Jun LiList of authors in order
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diamondOpen access status per OpenAlex
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https://doi.org/10.1088/1742-6596/3061/1/012026Direct OA link when available
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Crystallization, Nanocomposite, Thermal stability, Materials science, Nucleation, Chemical engineering, Thermal, Composite material, Chemistry, Thermodynamics, Organic chemistry, Engineering, PhysicsTop concepts (fields/topics) attached by OpenAlex
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0Total citation count in OpenAlex
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10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.within | 56 |
| abstract_inverted_index.amounts | 133 |
| abstract_inverted_index.etching | 14 |
| abstract_inverted_index.kinetic | 99 |
| abstract_inverted_index.lowered | 104 |
| abstract_inverted_index.matrix. | 59 |
| abstract_inverted_index.overall | 87 |
| abstract_inverted_index.respect | 94 |
| abstract_inverted_index.surface | 42, 46 |
| abstract_inverted_index.thereby | 152 |
| abstract_inverted_index.thermal | 123, 148 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.abundant | 45 |
| abstract_inverted_index.analysis | 100 |
| abstract_inverted_index.apparent | 106 |
| abstract_inverted_index.blending | 32 |
| abstract_inverted_index.enhanced | 112 |
| abstract_inverted_index.findings | 126 |
| abstract_inverted_index.markedly | 91 |
| abstract_inverted_index.revealed | 118 |
| abstract_inverted_index.solution | 31 |
| abstract_inverted_index.specific | 41 |
| abstract_inverted_index.strategy | 141 |
| abstract_inverted_index.PET/MXene | 35 |
| abstract_inverted_index.behaviour | 146 |
| abstract_inverted_index.confirmed | 101 |
| abstract_inverted_index.effective | 140 |
| abstract_inverted_index.efficient | 52 |
| abstract_inverted_index.expanding | 153 |
| abstract_inverted_index.kinetics, | 114 |
| abstract_inverted_index.potential | 155 |
| abstract_inverted_index.selective | 13 |
| abstract_inverted_index.tailoring | 143 |
| abstract_inverted_index.(PET-MX-1) | 77 |
| abstract_inverted_index.activation | 108 |
| abstract_inverted_index.containing | 72 |
| abstract_inverted_index.nanosheets | 9 |
| abstract_inverted_index.nucleation | 54 |
| abstract_inverted_index.stability. | 124 |
| abstract_inverted_index.accelerated | 92 |
| abstract_inverted_index.demonstrate | 127 |
| abstract_inverted_index.engineering | 158 |
| abstract_inverted_index.improvement | 121 |
| abstract_inverted_index.performance | 149 |
| abstract_inverted_index.synthesised | 11 |
| abstract_inverted_index.temperature | 64 |
| abstract_inverted_index.incorporated | 25 |
| abstract_inverted_index.introduction | 130 |
| abstract_inverted_index.measurements | 117 |
| abstract_inverted_index.polyethylene | 27 |
| abstract_inverted_index.subsequently | 24 |
| abstract_inverted_index.Consequently, | 60 |
| abstract_inverted_index.applications. | 159 |
| abstract_inverted_index.heterogeneous | 53 |
| abstract_inverted_index.nanocomposite | 71 |
| abstract_inverted_index.terephthalate | 28 |
| abstract_inverted_index.terminations, | 47 |
| abstract_inverted_index.Non-isothermal | 98 |
| abstract_inverted_index.crystallisation | 62, 88, 107, 113, 145 |
| abstract_inverted_index.nanocomposites. | 36 |
| abstract_inverted_index.high-performance | 157 |
| abstract_inverted_index.thermogravimetric | 116 |
| cited_by_percentile_year | |
| countries_distinct_count | 0 |
| institutions_distinct_count | 12 |
| citation_normalized_percentile.value | 0.3431114 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |