Effect of Transitional Metals (Mn and Ni) Substitution in LiCoPO4 Olivines Article Swipe

PDF

Oriele Palumbo , Jessica Manzi , Daniele Meggiolaro , Francesco Vitucci , F. Trequattrini , Mariangela Curcio , A. Paolone , Sergio Brutti ·

YOU? · · 2020 · Open Access · · DOI: https://doi.org/10.3390/molecules25030601

Transition metal substitution is a key strategy to optimize the functional properties of advanced crystalline materials used as positive electrodes in secondary lithium batteries (LIBs). Here we investigate the structural alterations in the olivine lattice of Mn and Ni substituted LiCoPO4 phase and the impact on performance in LIBs. X-ray diffraction (XRD) and extended X-ray absorption experiments have been carried out in order to highlight the structural alterations induced by partial substitution of cobalt by manganese and nickel. XRD analysis suggests that substitution induces an expansion of the lattices and an increase of the antisite disorder between lithium and transition metal ions in the structure. XAS data highlight negligible electronic disorder but a relevant modulation in the local coordination around the different metal ions. Moreover, galvanostatic tests showed poor reversibility of the redox reaction compared to the pure LCP sample, and this failure is discussed in detail in view of the observed remarkable structural changes.

Related Topics

$Diffraction$

Concepts

Manganese Transition metal Materials science Cobalt Lithium (medication) Nickel X-ray absorption spectroscopy Redox Metal Diffraction Phase (matter) Crystallography Inorganic chemistry Absorption spectroscopy Chemistry Catalysis Metallurgy Medicine Endocrinology Biochemistry Physics Quantum mechanics Organic chemistry Optics

Metadata

Type: article
Language: en
Landing Page: https://doi.org/10.3390/molecules25030601
PDF: https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273
OA Status: gold
Cited By: 1
References: 29
Related Works: 10
OpenAlex ID: https://openalex.org/W3004091342

All OpenAlex metadata

Raw OpenAlex JSON

OpenAlex ID: https://openalex.org/W3004091342

Canonical identifier for this work in OpenAlex
DOI: https://doi.org/10.3390/molecules25030601

Digital Object Identifier
Title: Effect of Transitional Metals (Mn and Ni) Substitution in LiCoPO4 Olivines

Work title
Type: article

OpenAlex work type
Language: en

Primary language
Publication year: 2020

Year of publication
Publication date: 2020-01-30

Full publication date if available
Authors: Oriele Palumbo, Jessica Manzi, Daniele Meggiolaro, Francesco Vitucci, F. Trequattrini, Mariangela Curcio, A. Paolone, Sergio Brutti

List of authors in order
Landing page: https://doi.org/10.3390/molecules25030601

Publisher landing page
PDF URL: https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273

Direct link to full text PDF
Open access: Yes

Whether a free full text is available
OA status: gold

Open access status per OpenAlex
OA URL: https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273

Direct OA link when available
Concepts: Manganese, Transition metal, Materials science, Cobalt, Lithium (medication), Nickel, X-ray absorption spectroscopy, Redox, Metal, Diffraction, Phase (matter), Crystallography, Inorganic chemistry, Absorption spectroscopy, Chemistry, Catalysis, Metallurgy, Medicine, Endocrinology, Biochemistry, Physics, Quantum mechanics, Organic chemistry, Optics

Top concepts (fields/topics) attached by OpenAlex
Cited by: 1

Total citation count in OpenAlex
Citations by year (recent): 2023: 1

Per-year citation counts (last 5 years)
References (count): 29

Number of works referenced by this work
Related works (count): 10

Other works algorithmically related by OpenAlex

Full payload

id	https://openalex.org/W3004091342
doi	https://doi.org/10.3390/molecules25030601
ids.doi	https://doi.org/10.3390/molecules25030601
ids.mag	3004091342
ids.pmid	https://pubmed.ncbi.nlm.nih.gov/32019178
ids.openalex	https://openalex.org/W3004091342
fwci	0.09820437
mesh[0].qualifier_ui	Q000737
mesh[0].descriptor_ui	D003035
mesh[0].is_major_topic	False
mesh[0].qualifier_name	chemistry
mesh[0].descriptor_name	Cobalt
mesh[1].qualifier_ui
mesh[1].descriptor_ui	D004566
mesh[1].is_major_topic	True
mesh[1].qualifier_name
mesh[1].descriptor_name	Electrodes
mesh[2].qualifier_ui
mesh[2].descriptor_ui	D004581
mesh[2].is_major_topic	False
mesh[2].qualifier_name
mesh[2].descriptor_name	Electronics
mesh[3].qualifier_ui	Q000737
mesh[3].descriptor_ui	D058085
mesh[3].is_major_topic	False
mesh[3].qualifier_name	chemistry
mesh[3].descriptor_name	Iron Compounds
mesh[4].qualifier_ui	Q000737
mesh[4].descriptor_ui	D017616
mesh[4].is_major_topic	False
mesh[4].qualifier_name	chemistry
mesh[4].descriptor_name	Magnesium Compounds
mesh[5].qualifier_ui	Q000737
mesh[5].descriptor_ui	D008345
mesh[5].is_major_topic	False
mesh[5].qualifier_name	chemistry
mesh[5].descriptor_name	Manganese
mesh[6].qualifier_ui	Q000737
mesh[6].descriptor_ui	D009532
mesh[6].is_major_topic	False
mesh[6].qualifier_name	chemistry
mesh[6].descriptor_name	Nickel
mesh[7].qualifier_ui	Q000737
mesh[7].descriptor_ui	D010087
mesh[7].is_major_topic	False
mesh[7].qualifier_name	chemistry
mesh[7].descriptor_name	Oxides
mesh[8].qualifier_ui	Q000737
mesh[8].descriptor_ui	D010710
mesh[8].is_major_topic	False
mesh[8].qualifier_name	chemistry
mesh[8].descriptor_name	Phosphates
mesh[9].qualifier_ui	Q000737
mesh[9].descriptor_ui	D017640
mesh[9].is_major_topic	False
mesh[9].qualifier_name	chemistry
mesh[9].descriptor_name	Silicates
mesh[10].qualifier_ui	Q000737
mesh[10].descriptor_ui	D003035
mesh[10].is_major_topic	False
mesh[10].qualifier_name	chemistry
mesh[10].descriptor_name	Cobalt
mesh[11].qualifier_ui
mesh[11].descriptor_ui	D004566
mesh[11].is_major_topic	True
mesh[11].qualifier_name
mesh[11].descriptor_name	Electrodes
mesh[12].qualifier_ui
mesh[12].descriptor_ui	D004581
mesh[12].is_major_topic	False
mesh[12].qualifier_name
mesh[12].descriptor_name	Electronics
mesh[13].qualifier_ui	Q000737
mesh[13].descriptor_ui	D058085
mesh[13].is_major_topic	False
mesh[13].qualifier_name	chemistry
mesh[13].descriptor_name	Iron Compounds
mesh[14].qualifier_ui	Q000737
mesh[14].descriptor_ui	D017616
mesh[14].is_major_topic	False
mesh[14].qualifier_name	chemistry
mesh[14].descriptor_name	Magnesium Compounds
mesh[15].qualifier_ui	Q000737
mesh[15].descriptor_ui	D008345
mesh[15].is_major_topic	False
mesh[15].qualifier_name	chemistry
mesh[15].descriptor_name	Manganese
mesh[16].qualifier_ui	Q000737
mesh[16].descriptor_ui	D009532
mesh[16].is_major_topic	False
mesh[16].qualifier_name	chemistry
mesh[16].descriptor_name	Nickel
mesh[17].qualifier_ui	Q000737
mesh[17].descriptor_ui	D010087
mesh[17].is_major_topic	False
mesh[17].qualifier_name	chemistry
mesh[17].descriptor_name	Oxides
mesh[18].qualifier_ui	Q000737
mesh[18].descriptor_ui	D010710
mesh[18].is_major_topic	False
mesh[18].qualifier_name	chemistry
mesh[18].descriptor_name	Phosphates
mesh[19].qualifier_ui	Q000737
mesh[19].descriptor_ui	D017640
mesh[19].is_major_topic	False
mesh[19].qualifier_name	chemistry
mesh[19].descriptor_name	Silicates
type	article
title	Effect of Transitional Metals (Mn and Ni) Substitution in LiCoPO4 Olivines
biblio.issue	3
biblio.volume	25
biblio.last_page	601
biblio.first_page	601
topics[0].id	https://openalex.org/T10018
topics[0].field.id	https://openalex.org/fields/22
topics[0].field.display_name	Engineering
topics[0].score	1.0
topics[0].domain.id	https://openalex.org/domains/3
topics[0].domain.display_name	Physical Sciences
topics[0].subfield.id	https://openalex.org/subfields/2208
topics[0].subfield.display_name	Electrical and Electronic Engineering
topics[0].display_name	Advancements in Battery Materials
topics[1].id	https://openalex.org/T10281
topics[1].field.id	https://openalex.org/fields/22
topics[1].field.display_name	Engineering
topics[1].score	0.9998999834060669
topics[1].domain.id	https://openalex.org/domains/3
topics[1].domain.display_name	Physical Sciences
topics[1].subfield.id	https://openalex.org/subfields/2208
topics[1].subfield.display_name	Electrical and Electronic Engineering
topics[1].display_name	Advanced Battery Materials and Technologies
topics[2].id	https://openalex.org/T11091
topics[2].field.id	https://openalex.org/fields/22
topics[2].field.display_name	Engineering
topics[2].score	0.998199999332428
topics[2].domain.id	https://openalex.org/domains/3
topics[2].domain.display_name	Physical Sciences
topics[2].subfield.id	https://openalex.org/subfields/2210
topics[2].subfield.display_name	Mechanical Engineering
topics[2].display_name	Extraction and Separation Processes
is_xpac	False
apc_list.value	2300
apc_list.currency	CHF
apc_list.value_usd	2490
apc_paid.value	2300
apc_paid.currency	CHF
apc_paid.value_usd	2490
concepts[0].id	https://openalex.org/C528890316
concepts[0].level	2
concepts[0].score	0.7428721189498901
concepts[0].wikidata	https://www.wikidata.org/wiki/Q731
concepts[0].display_name	Manganese
concepts[1].id	https://openalex.org/C106773901
concepts[1].level	3
concepts[1].score	0.6970722675323486
concepts[1].wikidata	https://www.wikidata.org/wiki/Q19588
concepts[1].display_name	Transition metal
concepts[2].id	https://openalex.org/C192562407
concepts[2].level	0
concepts[2].score	0.6334049105644226
concepts[2].wikidata	https://www.wikidata.org/wiki/Q228736
concepts[2].display_name	Materials science
concepts[3].id	https://openalex.org/C515602321
concepts[3].level	2
concepts[3].score	0.6159858703613281
concepts[3].wikidata	https://www.wikidata.org/wiki/Q740
concepts[3].display_name	Cobalt
concepts[4].id	https://openalex.org/C2778541603
concepts[4].level	2
concepts[4].score	0.5880902409553528
concepts[4].wikidata	https://www.wikidata.org/wiki/Q152763
concepts[4].display_name	Lithium (medication)
concepts[5].id	https://openalex.org/C504270822
concepts[5].level	2
concepts[5].score	0.553741455078125
concepts[5].wikidata	https://www.wikidata.org/wiki/Q744
concepts[5].display_name	Nickel
concepts[6].id	https://openalex.org/C62284982
concepts[6].level	3
concepts[6].score	0.5327131152153015
concepts[6].wikidata	https://www.wikidata.org/wiki/Q903103
concepts[6].display_name	X-ray absorption spectroscopy
concepts[7].id	https://openalex.org/C55904794
concepts[7].level	2
concepts[7].score	0.4951845705509186
concepts[7].wikidata	https://www.wikidata.org/wiki/Q82682
concepts[7].display_name	Redox
concepts[8].id	https://openalex.org/C544153396
concepts[8].level	2
concepts[8].score	0.4664565622806549
concepts[8].wikidata	https://www.wikidata.org/wiki/Q11426
concepts[8].display_name	Metal
concepts[9].id	https://openalex.org/C207114421
concepts[9].level	2
concepts[9].score	0.4609108567237854
concepts[9].wikidata	https://www.wikidata.org/wiki/Q133900
concepts[9].display_name	Diffraction
concepts[10].id	https://openalex.org/C44280652
concepts[10].level	2
concepts[10].score	0.4265303611755371
concepts[10].wikidata	https://www.wikidata.org/wiki/Q104837
concepts[10].display_name	Phase (matter)
concepts[11].id	https://openalex.org/C8010536
concepts[11].level	1
concepts[11].score	0.41720911860466003
concepts[11].wikidata	https://www.wikidata.org/wiki/Q160398
concepts[11].display_name	Crystallography
concepts[12].id	https://openalex.org/C179104552
concepts[12].level	1
concepts[12].score	0.3636976480484009
concepts[12].wikidata	https://www.wikidata.org/wiki/Q11165
concepts[12].display_name	Inorganic chemistry
concepts[13].id	https://openalex.org/C119824511
concepts[13].level	2
concepts[13].score	0.3112577795982361
concepts[13].wikidata	https://www.wikidata.org/wiki/Q13553575
concepts[13].display_name	Absorption spectroscopy
concepts[14].id	https://openalex.org/C185592680
concepts[14].level	0
concepts[14].score	0.27686119079589844
concepts[14].wikidata	https://www.wikidata.org/wiki/Q2329
concepts[14].display_name	Chemistry
concepts[15].id	https://openalex.org/C161790260
concepts[15].level	2
concepts[15].score	0.1609547734260559
concepts[15].wikidata	https://www.wikidata.org/wiki/Q82264
concepts[15].display_name	Catalysis
concepts[16].id	https://openalex.org/C191897082
concepts[16].level	1
concepts[16].score	0.1560748815536499
concepts[16].wikidata	https://www.wikidata.org/wiki/Q11467
concepts[16].display_name	Metallurgy
concepts[17].id	https://openalex.org/C71924100
concepts[17].level	0
concepts[17].score	0.0
concepts[17].wikidata	https://www.wikidata.org/wiki/Q11190
concepts[17].display_name	Medicine
concepts[18].id	https://openalex.org/C134018914
concepts[18].level	1
concepts[18].score	0.0
concepts[18].wikidata	https://www.wikidata.org/wiki/Q162606
concepts[18].display_name	Endocrinology
concepts[19].id	https://openalex.org/C55493867
concepts[19].level	1
concepts[19].score	0.0
concepts[19].wikidata	https://www.wikidata.org/wiki/Q7094
concepts[19].display_name	Biochemistry
concepts[20].id	https://openalex.org/C121332964
concepts[20].level	0
concepts[20].score	0.0
concepts[20].wikidata	https://www.wikidata.org/wiki/Q413
concepts[20].display_name	Physics
concepts[21].id	https://openalex.org/C62520636
concepts[21].level	1
concepts[21].score	0.0
concepts[21].wikidata	https://www.wikidata.org/wiki/Q944
concepts[21].display_name	Quantum mechanics
concepts[22].id	https://openalex.org/C178790620
concepts[22].level	1
concepts[22].score	0.0
concepts[22].wikidata	https://www.wikidata.org/wiki/Q11351
concepts[22].display_name	Organic chemistry
concepts[23].id	https://openalex.org/C120665830
concepts[23].level	1
concepts[23].score	0.0
concepts[23].wikidata	https://www.wikidata.org/wiki/Q14620
concepts[23].display_name	Optics
keywords[0].id	https://openalex.org/keywords/manganese
keywords[0].score	0.7428721189498901
keywords[0].display_name	Manganese
keywords[1].id	https://openalex.org/keywords/transition-metal
keywords[1].score	0.6970722675323486
keywords[1].display_name	Transition metal
keywords[2].id	https://openalex.org/keywords/materials-science
keywords[2].score	0.6334049105644226
keywords[2].display_name	Materials science
keywords[3].id	https://openalex.org/keywords/cobalt
keywords[3].score	0.6159858703613281
keywords[3].display_name	Cobalt
keywords[4].id	https://openalex.org/keywords/lithium
keywords[4].score	0.5880902409553528
keywords[4].display_name	Lithium (medication)
keywords[5].id	https://openalex.org/keywords/nickel
keywords[5].score	0.553741455078125
keywords[5].display_name	Nickel
keywords[6].id	https://openalex.org/keywords/x-ray-absorption-spectroscopy
keywords[6].score	0.5327131152153015
keywords[6].display_name	X-ray absorption spectroscopy
keywords[7].id	https://openalex.org/keywords/redox
keywords[7].score	0.4951845705509186
keywords[7].display_name	Redox
keywords[8].id	https://openalex.org/keywords/metal
keywords[8].score	0.4664565622806549
keywords[8].display_name	Metal
keywords[9].id	https://openalex.org/keywords/diffraction
keywords[9].score	0.4609108567237854
keywords[9].display_name	Diffraction
keywords[10].id	https://openalex.org/keywords/phase
keywords[10].score	0.4265303611755371
keywords[10].display_name	Phase (matter)
keywords[11].id	https://openalex.org/keywords/crystallography
keywords[11].score	0.41720911860466003
keywords[11].display_name	Crystallography
keywords[12].id	https://openalex.org/keywords/inorganic-chemistry
keywords[12].score	0.3636976480484009
keywords[12].display_name	Inorganic chemistry
keywords[13].id	https://openalex.org/keywords/absorption-spectroscopy
keywords[13].score	0.3112577795982361
keywords[13].display_name	Absorption spectroscopy
keywords[14].id	https://openalex.org/keywords/chemistry
keywords[14].score	0.27686119079589844
keywords[14].display_name	Chemistry
keywords[15].id	https://openalex.org/keywords/catalysis
keywords[15].score	0.1609547734260559
keywords[15].display_name	Catalysis
keywords[16].id	https://openalex.org/keywords/metallurgy
keywords[16].score	0.1560748815536499
keywords[16].display_name	Metallurgy
language	en
locations[0].id	doi:10.3390/molecules25030601
locations[0].is_oa	True
locations[0].source.id	https://openalex.org/S108911230
locations[0].source.issn	1420-3049, 1433-1373
locations[0].source.type	journal
locations[0].source.is_oa	True
locations[0].source.issn_l	1420-3049
locations[0].source.is_core	True
locations[0].source.is_in_doaj	True
locations[0].source.display_name	Molecules
locations[0].source.host_organization	https://openalex.org/P4310310987
locations[0].source.host_organization_name	Multidisciplinary Digital Publishing Institute
locations[0].source.host_organization_lineage	https://openalex.org/P4310310987
locations[0].source.host_organization_lineage_names	Multidisciplinary Digital Publishing Institute
locations[0].license	cc-by
locations[0].pdf_url	https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273
locations[0].version	publishedVersion
locations[0].raw_type	journal-article
locations[0].license_id	https://openalex.org/licenses/cc-by
locations[0].is_accepted	True
locations[0].is_published	True
locations[0].raw_source_name	Molecules
locations[0].landing_page_url	https://doi.org/10.3390/molecules25030601
locations[1].id	pmid:32019178
locations[1].is_oa	False
locations[1].source.id	https://openalex.org/S4306525036
locations[1].source.issn
locations[1].source.type	repository
locations[1].source.is_oa	False
locations[1].source.issn_l
locations[1].source.is_core	False
locations[1].source.is_in_doaj	False
locations[1].source.display_name	PubMed
locations[1].source.host_organization	https://openalex.org/I1299303238
locations[1].source.host_organization_name	National Institutes of Health
locations[1].source.host_organization_lineage	https://openalex.org/I1299303238
locations[1].license
locations[1].pdf_url
locations[1].version	publishedVersion
locations[1].raw_type
locations[1].license_id
locations[1].is_accepted	True
locations[1].is_published	True
locations[1].raw_source_name	Molecules (Basel, Switzerland)
locations[1].landing_page_url	https://pubmed.ncbi.nlm.nih.gov/32019178
locations[2].id	pmh:oai:iris.uniroma1.it:11573/1362277
locations[2].is_oa	True
locations[2].source.id	https://openalex.org/S4377196107
locations[2].source.issn
locations[2].source.type	repository
locations[2].source.is_oa	False
locations[2].source.issn_l
locations[2].source.is_core	False
locations[2].source.is_in_doaj	False
locations[2].source.display_name	IRIS Research product catalog (Sapienza University of Rome)
locations[2].source.host_organization
locations[2].source.host_organization_name
locations[2].license	other-oa
locations[2].pdf_url	http://hdl.handle.net/11573/1362277
locations[2].version	submittedVersion
locations[2].raw_type	info:eu-repo/semantics/article
locations[2].license_id	https://openalex.org/licenses/other-oa
locations[2].is_accepted	False
locations[2].is_published	False
locations[2].raw_source_name
locations[2].landing_page_url	http://hdl.handle.net/11573/1362277
locations[3].id	pmh:oai:doaj.org/article:c6c57fbd150448dd8a5c239b415ddb15
locations[3].is_oa	True
locations[3].source.id	https://openalex.org/S4306401280
locations[3].source.issn
locations[3].source.type	repository
locations[3].source.is_oa	False
locations[3].source.issn_l
locations[3].source.is_core	False
locations[3].source.is_in_doaj	False
locations[3].source.display_name	DOAJ (DOAJ: Directory of Open Access Journals)
locations[3].source.host_organization
locations[3].source.host_organization_name
locations[3].license	cc-by-sa
locations[3].pdf_url
locations[3].version	submittedVersion
locations[3].raw_type	article
locations[3].license_id	https://openalex.org/licenses/cc-by-sa
locations[3].is_accepted	False
locations[3].is_published	False
locations[3].raw_source_name	Molecules, Vol 25, Iss 3, p 601 (2020)
locations[3].landing_page_url	https://doaj.org/article/c6c57fbd150448dd8a5c239b415ddb15
locations[4].id	pmh:oai:iris.unibas.it:11563/145626
locations[4].is_oa	True
locations[4].source.id	https://openalex.org/S4377196360
locations[4].source.issn
locations[4].source.type	repository
locations[4].source.is_oa	False
locations[4].source.issn_l
locations[4].source.is_core	False
locations[4].source.is_in_doaj	False
locations[4].source.display_name	CINECA IRIS Institutional Research Information System (University of Basilicata)
locations[4].source.host_organization	https://openalex.org/I20272500
locations[4].source.host_organization_name	University of Basilicata
locations[4].source.host_organization_lineage	https://openalex.org/I20272500
locations[4].license	cc-by
locations[4].pdf_url
locations[4].version	submittedVersion
locations[4].raw_type	info:eu-repo/semantics/article
locations[4].license_id	https://openalex.org/licenses/cc-by
locations[4].is_accepted	False
locations[4].is_published	False
locations[4].raw_source_name
locations[4].landing_page_url	https://www.mdpi.com/1420-3049/25/3/601
locations[5].id	pmh:oai:mdpi.com:/1420-3049/25/3/601/
locations[5].is_oa	True
locations[5].source.id	https://openalex.org/S4306400947
locations[5].source.issn
locations[5].source.type	repository
locations[5].source.is_oa	True
locations[5].source.issn_l
locations[5].source.is_core	False
locations[5].source.is_in_doaj	False
locations[5].source.display_name	MDPI (MDPI AG)
locations[5].source.host_organization	https://openalex.org/I4210097602
locations[5].source.host_organization_name	Multidisciplinary Digital Publishing Institute (Switzerland)
locations[5].source.host_organization_lineage	https://openalex.org/I4210097602
locations[5].license	cc-by
locations[5].pdf_url
locations[5].version	submittedVersion
locations[5].raw_type	Text
locations[5].license_id	https://openalex.org/licenses/cc-by
locations[5].is_accepted	False
locations[5].is_published	False
locations[5].raw_source_name	Molecules
locations[5].landing_page_url	http://dx.doi.org/10.3390/molecules25030601
locations[6].id	pmh:oai:pubmedcentral.nih.gov:7037934
locations[6].is_oa	True
locations[6].source.id	https://openalex.org/S2764455111
locations[6].source.issn
locations[6].source.type	repository
locations[6].source.is_oa	False
locations[6].source.issn_l
locations[6].source.is_core	False
locations[6].source.is_in_doaj	False
locations[6].source.display_name	PubMed Central
locations[6].source.host_organization	https://openalex.org/I1299303238
locations[6].source.host_organization_name	National Institutes of Health
locations[6].source.host_organization_lineage	https://openalex.org/I1299303238
locations[6].license	other-oa
locations[6].pdf_url
locations[6].version	submittedVersion
locations[6].raw_type	Text
locations[6].license_id	https://openalex.org/licenses/other-oa
locations[6].is_accepted	False
locations[6].is_published	False
locations[6].raw_source_name	Molecules
locations[6].landing_page_url	https://www.ncbi.nlm.nih.gov/pmc/articles/7037934
indexed_in	crossref, doaj, pubmed
authorships[0].author.id	https://openalex.org/A5071904776
authorships[0].author.orcid	https://orcid.org/0000-0003-4968-1049
authorships[0].author.display_name	Oriele Palumbo
authorships[0].affiliations[0].raw_affiliation_string	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[0].author_position	first
authorships[0].raw_author_name	Oriele Palumbo
authorships[0].is_corresponding	False
authorships[0].raw_affiliation_strings	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[1].author.id	https://openalex.org/A5112304882
authorships[1].author.orcid
authorships[1].author.display_name	Jessica Manzi
authorships[1].affiliations[0].raw_affiliation_string	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[1].author_position	middle
authorships[1].raw_author_name	Jessica Manzi
authorships[1].is_corresponding	False
authorships[1].raw_affiliation_strings	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[2].author.id	https://openalex.org/A5004004400
authorships[2].author.orcid	https://orcid.org/0000-0001-9717-133X
authorships[2].author.display_name	Daniele Meggiolaro
authorships[2].affiliations[0].raw_affiliation_string	Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO) Istituto CNR di Scienze e Tecnologie Chimiche "Giulio Natta"(CNR-SCITEC), Via Elce di Sotto 8, 06123 Perugia, Italy
authorships[2].author_position	middle
authorships[2].raw_author_name	Daniele Meggiolaro
authorships[2].is_corresponding	False
authorships[2].raw_affiliation_strings	Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO) Istituto CNR di Scienze e Tecnologie Chimiche "Giulio Natta"(CNR-SCITEC), Via Elce di Sotto 8, 06123 Perugia, Italy
authorships[3].author.id	https://openalex.org/A5081426938
authorships[3].author.orcid
authorships[3].author.display_name	Francesco Vitucci
authorships[3].affiliations[0].raw_affiliation_string	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[3].author_position	middle
authorships[3].raw_author_name	Francesco M. Vitucci
authorships[3].is_corresponding	False
authorships[3].raw_affiliation_strings	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[4].author.id	https://openalex.org/A5041091343
authorships[4].author.orcid	https://orcid.org/0000-0002-6521-7441
authorships[4].author.display_name	F. Trequattrini
authorships[4].countries	IT
authorships[4].affiliations[0].institution_ids	https://openalex.org/I861853513
authorships[4].affiliations[0].raw_affiliation_string	Department of Physics, University of Rome ''La Sapienza'', Piazzale A. Moro 5, 00185 Rome, Italy
authorships[4].affiliations[1].raw_affiliation_string	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[4].institutions[0].id	https://openalex.org/I861853513
authorships[4].institutions[0].ror	https://ror.org/02be6w209
authorships[4].institutions[0].type	education
authorships[4].institutions[0].lineage	https://openalex.org/I861853513
authorships[4].institutions[0].country_code	IT
authorships[4].institutions[0].display_name	Sapienza University of Rome
authorships[4].author_position	middle
authorships[4].raw_author_name	Francesco Trequattrini
authorships[4].is_corresponding	False
authorships[4].raw_affiliation_strings	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy, Department of Physics, University of Rome ''La Sapienza'', Piazzale A. Moro 5, 00185 Rome, Italy
authorships[5].author.id	https://openalex.org/A5058485943
authorships[5].author.orcid	https://orcid.org/0000-0001-7580-5725
authorships[5].author.display_name	Mariangela Curcio
authorships[5].countries	IT
authorships[5].affiliations[0].institution_ids	https://openalex.org/I20272500
authorships[5].affiliations[0].raw_affiliation_string	Department of Sciences, University of Basilicata, V.le dell'Ateneo Lucano 10, 85100 Potenza, Italy
authorships[5].institutions[0].id	https://openalex.org/I20272500
authorships[5].institutions[0].ror	https://ror.org/03tc05689
authorships[5].institutions[0].type	education
authorships[5].institutions[0].lineage	https://openalex.org/I20272500
authorships[5].institutions[0].country_code	IT
authorships[5].institutions[0].display_name	University of Basilicata
authorships[5].author_position	middle
authorships[5].raw_author_name	Mariangela Curcio
authorships[5].is_corresponding	False
authorships[5].raw_affiliation_strings	Department of Sciences, University of Basilicata, V.le dell'Ateneo Lucano 10, 85100 Potenza, Italy
authorships[6].author.id	https://openalex.org/A5082279775
authorships[6].author.orcid	https://orcid.org/0000-0002-4839-7815
authorships[6].author.display_name	A. Paolone
authorships[6].affiliations[0].raw_affiliation_string	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[6].author_position	middle
authorships[6].raw_author_name	Annalisa Paolone
authorships[6].is_corresponding	False
authorships[6].raw_affiliation_strings	CNR-ISC, U.O.S. La Sapienza, Piazzale A. Moro 5, 00185 Rome, Italy
authorships[7].author.id	https://openalex.org/A5076989459
authorships[7].author.orcid	https://orcid.org/0000-0001-8853-9710
authorships[7].author.display_name	Sergio Brutti
authorships[7].countries	IT
authorships[7].affiliations[0].institution_ids	https://openalex.org/I861853513
authorships[7].affiliations[0].raw_affiliation_string	Department of Chemistry, University of Rome ''La Sapienza'', Piazzale Aldo Moro 5, 00185 Rome, Italy
authorships[7].institutions[0].id	https://openalex.org/I861853513
authorships[7].institutions[0].ror	https://ror.org/02be6w209
authorships[7].institutions[0].type	education
authorships[7].institutions[0].lineage	https://openalex.org/I861853513
authorships[7].institutions[0].country_code	IT
authorships[7].institutions[0].display_name	Sapienza University of Rome
authorships[7].author_position	last
authorships[7].raw_author_name	Sergio Brutti
authorships[7].is_corresponding	True
authorships[7].raw_affiliation_strings	Department of Chemistry, University of Rome ''La Sapienza'', Piazzale Aldo Moro 5, 00185 Rome, Italy
has_content.pdf	True
has_content.grobid_xml	True
is_paratext	False
open_access.is_oa	True
open_access.oa_url	https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273
open_access.oa_status	gold
open_access.any_repository_has_fulltext	False
created_date	2025-10-10T00:00:00
display_name	Effect of Transitional Metals (Mn and Ni) Substitution in LiCoPO4 Olivines
has_fulltext	True
is_retracted	False
updated_date	2025-11-06T03:46:38.306776
primary_topic.id	https://openalex.org/T10018
primary_topic.field.id	https://openalex.org/fields/22
primary_topic.field.display_name	Engineering
primary_topic.score	1.0
primary_topic.domain.id	https://openalex.org/domains/3
primary_topic.domain.display_name	Physical Sciences
primary_topic.subfield.id	https://openalex.org/subfields/2208
primary_topic.subfield.display_name	Electrical and Electronic Engineering
primary_topic.display_name	Advancements in Battery Materials
related_works	https://openalex.org/W2000881355, https://openalex.org/W101026528, https://openalex.org/W1991968061, https://openalex.org/W4252174567, https://openalex.org/W4242038730, https://openalex.org/W2886469245, https://openalex.org/W2321859376, https://openalex.org/W3209946368, https://openalex.org/W2767454602, https://openalex.org/W2066339053
cited_by_count	1
counts_by_year[0].year	2023
counts_by_year[0].cited_by_count	1
locations_count	7
best_oa_location.id	doi:10.3390/molecules25030601
best_oa_location.is_oa	True
best_oa_location.source.id	https://openalex.org/S108911230
best_oa_location.source.issn	1420-3049, 1433-1373
best_oa_location.source.type	journal
best_oa_location.source.is_oa	True
best_oa_location.source.issn_l	1420-3049
best_oa_location.source.is_core	True
best_oa_location.source.is_in_doaj	True
best_oa_location.source.display_name	Molecules
best_oa_location.source.host_organization	https://openalex.org/P4310310987
best_oa_location.source.host_organization_name	Multidisciplinary Digital Publishing Institute
best_oa_location.source.host_organization_lineage	https://openalex.org/P4310310987
best_oa_location.source.host_organization_lineage_names	Multidisciplinary Digital Publishing Institute
best_oa_location.license	cc-by
best_oa_location.pdf_url	https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273
best_oa_location.version	publishedVersion
best_oa_location.raw_type	journal-article
best_oa_location.license_id	https://openalex.org/licenses/cc-by
best_oa_location.is_accepted	True
best_oa_location.is_published	True
best_oa_location.raw_source_name	Molecules
best_oa_location.landing_page_url	https://doi.org/10.3390/molecules25030601
primary_location.id	doi:10.3390/molecules25030601
primary_location.is_oa	True
primary_location.source.id	https://openalex.org/S108911230
primary_location.source.issn	1420-3049, 1433-1373
primary_location.source.type	journal
primary_location.source.is_oa	True
primary_location.source.issn_l	1420-3049
primary_location.source.is_core	True
primary_location.source.is_in_doaj	True
primary_location.source.display_name	Molecules
primary_location.source.host_organization	https://openalex.org/P4310310987
primary_location.source.host_organization_name	Multidisciplinary Digital Publishing Institute
primary_location.source.host_organization_lineage	https://openalex.org/P4310310987
primary_location.source.host_organization_lineage_names	Multidisciplinary Digital Publishing Institute
primary_location.license	cc-by
primary_location.pdf_url	https://www.mdpi.com/1420-3049/25/3/601/pdf?version=1580719273
primary_location.version	publishedVersion
primary_location.raw_type	journal-article
primary_location.license_id	https://openalex.org/licenses/cc-by
primary_location.is_accepted	True
primary_location.is_published	True
primary_location.raw_source_name	Molecules
primary_location.landing_page_url	https://doi.org/10.3390/molecules25030601
publication_date	2020-01-30
publication_year	2020
referenced_works	https://openalex.org/W2476725121, https://openalex.org/W2092361285, https://openalex.org/W2210176796, https://openalex.org/W2325916941, https://openalex.org/W2093336984, https://openalex.org/W2078036943, https://openalex.org/W2003727516, https://openalex.org/W1976514859, https://openalex.org/W1971804673, https://openalex.org/W2277706203, https://openalex.org/W2053655800, https://openalex.org/W2087258955, https://openalex.org/W2116385447, https://openalex.org/W2619319443, https://openalex.org/W1970778865, https://openalex.org/W2197882449, https://openalex.org/W1835637410, https://openalex.org/W2002260387, https://openalex.org/W2071844654, https://openalex.org/W2018001805, https://openalex.org/W2013167533, https://openalex.org/W1988533325, https://openalex.org/W2052208476, https://openalex.org/W2292296062, https://openalex.org/W2190369457, https://openalex.org/W2331167943, https://openalex.org/W2012669505, https://openalex.org/W2070227796, https://openalex.org/W3106256585
referenced_works_count	29
abstract_inverted_index.a	4, 112
abstract_inverted_index.Mn	36
abstract_inverted_index.Ni	38
abstract_inverted_index.an	84, 90
abstract_inverted_index.as	17
abstract_inverted_index.by	69, 74
abstract_inverted_index.in	20, 31, 47, 61, 102, 115, 145, 147
abstract_inverted_index.is	3, 143
abstract_inverted_index.of	12, 35, 72, 86, 92, 130, 149
abstract_inverted_index.on	45
abstract_inverted_index.to	7, 63, 135
abstract_inverted_index.we	26
abstract_inverted_index.LCP	138
abstract_inverted_index.XAS	105
abstract_inverted_index.XRD	78
abstract_inverted_index.and	37, 42, 52, 76, 89, 98, 140
abstract_inverted_index.but	111
abstract_inverted_index.key	5
abstract_inverted_index.out	60
abstract_inverted_index.the	9, 28, 32, 43, 65, 87, 93, 103, 116, 120, 131, 136, 150
abstract_inverted_index.Here	25
abstract_inverted_index.been	58
abstract_inverted_index.data	106
abstract_inverted_index.have	57
abstract_inverted_index.ions	101
abstract_inverted_index.poor	128
abstract_inverted_index.pure	137
abstract_inverted_index.that	81
abstract_inverted_index.this	141
abstract_inverted_index.used	16
abstract_inverted_index.view	148
abstract_inverted_index.(XRD)	51
abstract_inverted_index.LIBs.	48
abstract_inverted_index.X-ray	49, 54
abstract_inverted_index.ions.	123
abstract_inverted_index.local	117
abstract_inverted_index.metal	1, 100, 122
abstract_inverted_index.order	62
abstract_inverted_index.phase	41
abstract_inverted_index.redox	132
abstract_inverted_index.tests	126
abstract_inverted_index.around	119
abstract_inverted_index.cobalt	73
abstract_inverted_index.detail	146
abstract_inverted_index.impact	44
abstract_inverted_index.showed	127
abstract_inverted_index.(LIBs).	24
abstract_inverted_index.LiCoPO4	40
abstract_inverted_index.between	96
abstract_inverted_index.carried	59
abstract_inverted_index.failure	142
abstract_inverted_index.induced	68
abstract_inverted_index.induces	83
abstract_inverted_index.lattice	34
abstract_inverted_index.lithium	22, 97
abstract_inverted_index.nickel.	77
abstract_inverted_index.olivine	33
abstract_inverted_index.partial	70
abstract_inverted_index.sample,	139
abstract_inverted_index.advanced	13
abstract_inverted_index.analysis	79
abstract_inverted_index.antisite	94
abstract_inverted_index.changes.	154
abstract_inverted_index.compared	134
abstract_inverted_index.disorder	95, 110
abstract_inverted_index.extended	53
abstract_inverted_index.increase	91
abstract_inverted_index.lattices	88
abstract_inverted_index.observed	151
abstract_inverted_index.optimize	8
abstract_inverted_index.positive	18
abstract_inverted_index.reaction	133
abstract_inverted_index.relevant	113
abstract_inverted_index.strategy	6
abstract_inverted_index.suggests	80
abstract_inverted_index.Moreover,	124
abstract_inverted_index.batteries	23
abstract_inverted_index.different	121
abstract_inverted_index.discussed	144
abstract_inverted_index.expansion	85
abstract_inverted_index.highlight	64, 107
abstract_inverted_index.manganese	75
abstract_inverted_index.materials	15
abstract_inverted_index.secondary	21
abstract_inverted_index.Transition	0
abstract_inverted_index.absorption	55
abstract_inverted_index.electrodes	19
abstract_inverted_index.electronic	109
abstract_inverted_index.functional	10
abstract_inverted_index.modulation	114
abstract_inverted_index.negligible	108
abstract_inverted_index.properties	11
abstract_inverted_index.remarkable	152
abstract_inverted_index.structural	29, 66, 153
abstract_inverted_index.structure.	104
abstract_inverted_index.transition	99
abstract_inverted_index.alterations	30, 67
abstract_inverted_index.crystalline	14
abstract_inverted_index.diffraction	50
abstract_inverted_index.experiments	56
abstract_inverted_index.investigate	27
abstract_inverted_index.performance	46
abstract_inverted_index.substituted	39
abstract_inverted_index.coordination	118
abstract_inverted_index.substitution	2, 71, 82
abstract_inverted_index.galvanostatic	125
abstract_inverted_index.reversibility	129
cited_by_percentile_year.max	94
cited_by_percentile_year.min	89
corresponding_author_ids	https://openalex.org/A5076989459
countries_distinct_count	1
institutions_distinct_count	8
corresponding_institution_ids	https://openalex.org/I861853513
citation_normalized_percentile.value	0.40249737
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False