Electrochemical Determination of Triclosan Using ZIF-11/Activated Carbon Derived from the Rice Husk Modified Electrode Article Swipe

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Nguyen Dinh Luyen , Trần Thanh Tâm Toàn , Hà Thùy Trang , Vo Thang Nguyen , Le Van Thanh Sơn , Tran Si Thanh , Nguyen Mau Thanh , Phan Tứ Quý , Đinh Quang Khiếu ·

YOU? · · 2021 · Open Access · · DOI: https://doi.org/10.1155/2021/8486962

In the present paper, the composite of zeolite imidazolate framework-11 (ZIF-11) and activated carbon derived from rice husks (RHAC) was synthesized. The obtained materials were characterized by XRD, SEM, EDX-mapping, and nitrogen adsorption/desorption isotherms. The final composite ZIF-11/RHAC exhibits an even dispersion of ZIF-11 particles on activated carbon matrix. Herein, an electrochemical sensor based on a ZIF-11/RHAC was developed for a rapid determination of triclosan (TCS). It was found that the oxidation of TCS is irreversible and involves the transfer of one electron. The linear range for TCS detection in the optimized experimental conditions was found to be 0.1-8 μM with the limit of detection of 0.076 μM. Finally, the proposed method was successfully employed to detect TCS in different personal care product samples with high accuracy, which was confirmed by a good agreement between these results and those obtained using high-performance liquid chromatography (HPLC).

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Husk Activated carbon Detection limit Triclosan Materials science Adsorption Imidazolate Electrochemistry Composite number Dispersion (optics) Microcrystalline Linear range Carbon fibers Desorption Cyclic voltammetry Electrode Electrochemical gas sensor Chemical engineering Chromatography Chemistry Inorganic chemistry Composite material Organic chemistry Optics Physical chemistry Botany Crystallography Physics Engineering Medicine Biology Pathology

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Type: article
Language: en
Landing Page: https://doi.org/10.1155/2021/8486962
PDF: https://downloads.hindawi.com/journals/jnm/2021/8486962.pdf
OA Status: hybrid
Cited By: 20
References: 35
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Title: Electrochemical Determination of Triclosan Using ZIF-11/Activated Carbon Derived from the Rice Husk Modified Electrode

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Language: en

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Publication year: 2021

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Publication date: 2021-10-01

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Authors: Nguyen Dinh Luyen, Trần Thanh Tâm Toàn, Hà Thùy Trang, Vo Thang Nguyen, Le Van Thanh Sơn, Tran Si Thanh, Nguyen Mau Thanh, Phan Tứ Quý, Đinh Quang Khiếu

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Landing page: https://doi.org/10.1155/2021/8486962

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Concepts: Husk, Activated carbon, Detection limit, Triclosan, Materials science, Adsorption, Imidazolate, Electrochemistry, Composite number, Dispersion (optics), Microcrystalline, Linear range, Carbon fibers, Desorption, Cyclic voltammetry, Electrode, Electrochemical gas sensor, Chemical engineering, Chromatography, Chemistry, Inorganic chemistry, Composite material, Organic chemistry, Optics, Physical chemistry, Botany, Crystallography, Physics, Engineering, Medicine, Biology, Pathology

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