Electronic Finetuning of a Bio‐inspired Iron(II) tetra‐NHC Complex by trans Axial Isocyanide Substitution Article Swipe
Jonas F. Schlagintweit
,
Carolin Hintermeier
,
Markus R. Anneser
,
Eva‐Maria H. J. Esslinger
,
Stefan Haslinger
,
Fritz E. Kühn
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1002/asia.202000214
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1002/asia.202000214
The synthesis of trans axially substituted mono‐ ( 1 a ) and bis( tert ‐butylisocyanide) ( 1 b ) derivatives of the highly active homogeneous bio‐inspired iron(II) olefin epoxidation (pre‐)catalyst 1 bearing an equatorial macrocyclic tetra N ‐heterocyclic carbene and two trans axial labile acetonitrile ligands is reported. NMR spectroscopy and SC‐XRD indicate a considerable π‐backdonation from the iron(II) centres to the isocyanide ligand(s). The impact of isocyanide substitution on the electronic features of the complexes is studied by cyclic voltammetry revealing a significant increase in half‐cell potential assignable to the reversible Fe(II)/Fe(III) redox couple with an increasing number of isocyanides as a result of their π‐accepting properties: E 1/2 =0.15 V ( 1 ), E 1/2 =0.35 V ( 1 a ), E 1/2 =0.44 V ( 1 b ).
Related Topics
Concepts
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/asia.202000214
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214
- OA Status
- hybrid
- Cited By
- 14
- References
- 44
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3012867199
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W3012867199Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/asia.202000214Digital Object Identifier
- Title
-
Electronic Finetuning of a Bio‐inspired Iron(II) tetra‐NHC Complex by trans Axial Isocyanide SubstitutionWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2020Year of publication
- Publication date
-
2020-03-23Full publication date if available
- Authors
-
Jonas F. Schlagintweit, Carolin Hintermeier, Markus R. Anneser, Eva‐Maria H. J. Esslinger, Stefan Haslinger, Fritz E. KühnList of authors in order
- Landing page
-
https://doi.org/10.1002/asia.202000214Publisher landing page
- PDF URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
hybridOpen access status per OpenAlex
- OA URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214Direct OA link when available
- Concepts
-
Isocyanide, Carbene, Cyclic voltammetry, Chemistry, Acetonitrile, Tetra, Ligand (biochemistry), Medicinal chemistry, Redox, Stereochemistry, Catalysis, Electrochemistry, Organic chemistry, Physical chemistry, Biochemistry, Electrode, ReceptorTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
14Total citation count in OpenAlex
- Citations by year (recent)
-
2024: 3, 2023: 4, 2022: 2, 2021: 2, 2020: 3Per-year citation counts (last 5 years)
- References (count)
-
44Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W3012867199 |
|---|---|
| doi | https://doi.org/10.1002/asia.202000214 |
| ids.doi | https://doi.org/10.1002/asia.202000214 |
| ids.mag | 3012867199 |
| ids.pmid | https://pubmed.ncbi.nlm.nih.gov/32202690 |
| ids.openalex | https://openalex.org/W3012867199 |
| fwci | 1.3972058 |
| type | article |
| title | Electronic Finetuning of a Bio‐inspired Iron(II) tetra‐NHC Complex by trans Axial Isocyanide Substitution |
| biblio.issue | 12 |
| biblio.volume | 15 |
| biblio.last_page | 1902 |
| biblio.first_page | 1896 |
| topics[0].id | https://openalex.org/T11790 |
| topics[0].field.id | https://openalex.org/fields/16 |
| topics[0].field.display_name | Chemistry |
| topics[0].score | 0.9998000264167786 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/1605 |
| topics[0].subfield.display_name | Organic Chemistry |
| topics[0].display_name | N-Heterocyclic Carbenes in Organic and Inorganic Chemistry |
| topics[1].id | https://openalex.org/T11549 |
| topics[1].field.id | https://openalex.org/fields/16 |
| topics[1].field.display_name | Chemistry |
| topics[1].score | 0.9994000196456909 |
| topics[1].domain.id | https://openalex.org/domains/3 |
| topics[1].domain.display_name | Physical Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/1605 |
| topics[1].subfield.display_name | Organic Chemistry |
| topics[1].display_name | Synthetic Organic Chemistry Methods |
| topics[2].id | https://openalex.org/T11286 |
| topics[2].field.id | https://openalex.org/fields/25 |
| topics[2].field.display_name | Materials Science |
| topics[2].score | 0.9944000244140625 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/2505 |
| topics[2].subfield.display_name | Materials Chemistry |
| topics[2].display_name | Polyoxometalates: Synthesis and Applications |
| is_xpac | False |
| apc_list.value | 4220 |
| apc_list.currency | USD |
| apc_list.value_usd | 4220 |
| apc_paid.value | 4220 |
| apc_paid.currency | USD |
| apc_paid.value_usd | 4220 |
| concepts[0].id | https://openalex.org/C2777010268 |
| concepts[0].level | 2 |
| concepts[0].score | 0.8655996322631836 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q421897 |
| concepts[0].display_name | Isocyanide |
| concepts[1].id | https://openalex.org/C2777164566 |
| concepts[1].level | 3 |
| concepts[1].score | 0.7530479431152344 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q419257 |
| concepts[1].display_name | Carbene |
| concepts[2].id | https://openalex.org/C2777869211 |
| concepts[2].level | 4 |
| concepts[2].score | 0.7520278692245483 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q1147647 |
| concepts[2].display_name | Cyclic voltammetry |
| concepts[3].id | https://openalex.org/C185592680 |
| concepts[3].level | 0 |
| concepts[3].score | 0.7202029824256897 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[3].display_name | Chemistry |
| concepts[4].id | https://openalex.org/C2777463227 |
| concepts[4].level | 2 |
| concepts[4].score | 0.6687666177749634 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q408047 |
| concepts[4].display_name | Acetonitrile |
| concepts[5].id | https://openalex.org/C2777873363 |
| concepts[5].level | 2 |
| concepts[5].score | 0.6528310775756836 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q13533436 |
| concepts[5].display_name | Tetra |
| concepts[6].id | https://openalex.org/C116569031 |
| concepts[6].level | 3 |
| concepts[6].score | 0.6265122890472412 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q899107 |
| concepts[6].display_name | Ligand (biochemistry) |
| concepts[7].id | https://openalex.org/C155647269 |
| concepts[7].level | 1 |
| concepts[7].score | 0.4944143295288086 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q243455 |
| concepts[7].display_name | Medicinal chemistry |
| concepts[8].id | https://openalex.org/C55904794 |
| concepts[8].level | 2 |
| concepts[8].score | 0.41925686597824097 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q82682 |
| concepts[8].display_name | Redox |
| concepts[9].id | https://openalex.org/C71240020 |
| concepts[9].level | 1 |
| concepts[9].score | 0.41178545355796814 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q186011 |
| concepts[9].display_name | Stereochemistry |
| concepts[10].id | https://openalex.org/C161790260 |
| concepts[10].level | 2 |
| concepts[10].score | 0.3401062488555908 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q82264 |
| concepts[10].display_name | Catalysis |
| concepts[11].id | https://openalex.org/C52859227 |
| concepts[11].level | 3 |
| concepts[11].score | 0.30692172050476074 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q7877 |
| concepts[11].display_name | Electrochemistry |
| concepts[12].id | https://openalex.org/C178790620 |
| concepts[12].level | 1 |
| concepts[12].score | 0.17016136646270752 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[12].display_name | Organic chemistry |
| concepts[13].id | https://openalex.org/C147789679 |
| concepts[13].level | 1 |
| concepts[13].score | 0.09415072202682495 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q11372 |
| concepts[13].display_name | Physical chemistry |
| concepts[14].id | https://openalex.org/C55493867 |
| concepts[14].level | 1 |
| concepts[14].score | 0.0 |
| concepts[14].wikidata | https://www.wikidata.org/wiki/Q7094 |
| concepts[14].display_name | Biochemistry |
| concepts[15].id | https://openalex.org/C17525397 |
| concepts[15].level | 2 |
| concepts[15].score | 0.0 |
| concepts[15].wikidata | https://www.wikidata.org/wiki/Q176140 |
| concepts[15].display_name | Electrode |
| concepts[16].id | https://openalex.org/C170493617 |
| concepts[16].level | 2 |
| concepts[16].score | 0.0 |
| concepts[16].wikidata | https://www.wikidata.org/wiki/Q208467 |
| concepts[16].display_name | Receptor |
| keywords[0].id | https://openalex.org/keywords/isocyanide |
| keywords[0].score | 0.8655996322631836 |
| keywords[0].display_name | Isocyanide |
| keywords[1].id | https://openalex.org/keywords/carbene |
| keywords[1].score | 0.7530479431152344 |
| keywords[1].display_name | Carbene |
| keywords[2].id | https://openalex.org/keywords/cyclic-voltammetry |
| keywords[2].score | 0.7520278692245483 |
| keywords[2].display_name | Cyclic voltammetry |
| keywords[3].id | https://openalex.org/keywords/chemistry |
| keywords[3].score | 0.7202029824256897 |
| keywords[3].display_name | Chemistry |
| keywords[4].id | https://openalex.org/keywords/acetonitrile |
| keywords[4].score | 0.6687666177749634 |
| keywords[4].display_name | Acetonitrile |
| keywords[5].id | https://openalex.org/keywords/tetra |
| keywords[5].score | 0.6528310775756836 |
| keywords[5].display_name | Tetra |
| keywords[6].id | https://openalex.org/keywords/ligand |
| keywords[6].score | 0.6265122890472412 |
| keywords[6].display_name | Ligand (biochemistry) |
| keywords[7].id | https://openalex.org/keywords/medicinal-chemistry |
| keywords[7].score | 0.4944143295288086 |
| keywords[7].display_name | Medicinal chemistry |
| keywords[8].id | https://openalex.org/keywords/redox |
| keywords[8].score | 0.41925686597824097 |
| keywords[8].display_name | Redox |
| keywords[9].id | https://openalex.org/keywords/stereochemistry |
| keywords[9].score | 0.41178545355796814 |
| keywords[9].display_name | Stereochemistry |
| keywords[10].id | https://openalex.org/keywords/catalysis |
| keywords[10].score | 0.3401062488555908 |
| keywords[10].display_name | Catalysis |
| keywords[11].id | https://openalex.org/keywords/electrochemistry |
| keywords[11].score | 0.30692172050476074 |
| keywords[11].display_name | Electrochemistry |
| keywords[12].id | https://openalex.org/keywords/organic-chemistry |
| keywords[12].score | 0.17016136646270752 |
| keywords[12].display_name | Organic chemistry |
| keywords[13].id | https://openalex.org/keywords/physical-chemistry |
| keywords[13].score | 0.09415072202682495 |
| keywords[13].display_name | Physical chemistry |
| language | en |
| locations[0].id | doi:10.1002/asia.202000214 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S188582317 |
| locations[0].source.issn | 1861-471X, 1861-4728 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | False |
| locations[0].source.issn_l | 1861-471X |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | False |
| locations[0].source.display_name | Chemistry - An Asian Journal |
| locations[0].source.host_organization | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_name | Wiley |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_lineage_names | Wiley |
| locations[0].license | cc-by-nc-nd |
| locations[0].pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214 |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | https://openalex.org/licenses/cc-by-nc-nd |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | Chemistry – An Asian Journal |
| locations[0].landing_page_url | https://doi.org/10.1002/asia.202000214 |
| locations[1].id | pmid:32202690 |
| locations[1].is_oa | False |
| locations[1].source.id | https://openalex.org/S4306525036 |
| locations[1].source.issn | |
| locations[1].source.type | repository |
| locations[1].source.is_oa | False |
| locations[1].source.issn_l | |
| locations[1].source.is_core | False |
| locations[1].source.is_in_doaj | False |
| locations[1].source.display_name | PubMed |
| locations[1].source.host_organization | https://openalex.org/I1299303238 |
| locations[1].source.host_organization_name | National Institutes of Health |
| locations[1].source.host_organization_lineage | https://openalex.org/I1299303238 |
| locations[1].license | |
| locations[1].pdf_url | |
| locations[1].version | publishedVersion |
| locations[1].raw_type | |
| locations[1].license_id | |
| locations[1].is_accepted | True |
| locations[1].is_published | True |
| locations[1].raw_source_name | Chemistry, an Asian journal |
| locations[1].landing_page_url | https://pubmed.ncbi.nlm.nih.gov/32202690 |
| locations[2].id | pmh:oai:pubmedcentral.nih.gov:7687264 |
| locations[2].is_oa | True |
| locations[2].source.id | https://openalex.org/S2764455111 |
| locations[2].source.issn | |
| locations[2].source.type | repository |
| locations[2].source.is_oa | False |
| locations[2].source.issn_l | |
| locations[2].source.is_core | False |
| locations[2].source.is_in_doaj | False |
| locations[2].source.display_name | PubMed Central |
| locations[2].source.host_organization | https://openalex.org/I1299303238 |
| locations[2].source.host_organization_name | National Institutes of Health |
| locations[2].source.host_organization_lineage | https://openalex.org/I1299303238 |
| locations[2].license | other-oa |
| locations[2].pdf_url | |
| locations[2].version | submittedVersion |
| locations[2].raw_type | Text |
| locations[2].license_id | https://openalex.org/licenses/other-oa |
| locations[2].is_accepted | False |
| locations[2].is_published | False |
| locations[2].raw_source_name | Chem Asian J |
| locations[2].landing_page_url | https://www.ncbi.nlm.nih.gov/pmc/articles/7687264 |
| indexed_in | crossref, pubmed |
| authorships[0].author.id | https://openalex.org/A5042306696 |
| authorships[0].author.orcid | https://orcid.org/0000-0002-4038-4307 |
| authorships[0].author.display_name | Jonas F. Schlagintweit |
| authorships[0].countries | DE |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I62916508 |
| authorships[0].affiliations[0].raw_affiliation_string | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[0].affiliations[1].raw_affiliation_string | These authors contributed equally to this work. |
| authorships[0].institutions[0].id | https://openalex.org/I62916508 |
| authorships[0].institutions[0].ror | https://ror.org/02kkvpp62 |
| authorships[0].institutions[0].type | education |
| authorships[0].institutions[0].lineage | https://openalex.org/I62916508 |
| authorships[0].institutions[0].country_code | DE |
| authorships[0].institutions[0].display_name | Technical University of Munich |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Jonas F. Schlagintweit |
| authorships[0].is_corresponding | False |
| authorships[0].raw_affiliation_strings | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany, These authors contributed equally to this work. |
| authorships[1].author.id | https://openalex.org/A5071974778 |
| authorships[1].author.orcid | |
| authorships[1].author.display_name | Carolin Hintermeier |
| authorships[1].countries | DE |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I62916508 |
| authorships[1].affiliations[0].raw_affiliation_string | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[1].affiliations[1].raw_affiliation_string | These authors contributed equally to this work. |
| authorships[1].institutions[0].id | https://openalex.org/I62916508 |
| authorships[1].institutions[0].ror | https://ror.org/02kkvpp62 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I62916508 |
| authorships[1].institutions[0].country_code | DE |
| authorships[1].institutions[0].display_name | Technical University of Munich |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Carolin Hintermeier |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany, These authors contributed equally to this work. |
| authorships[2].author.id | https://openalex.org/A5070593505 |
| authorships[2].author.orcid | https://orcid.org/0000-0002-8876-4747 |
| authorships[2].author.display_name | Markus R. Anneser |
| authorships[2].countries | DE |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I62916508 |
| authorships[2].affiliations[0].raw_affiliation_string | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[2].institutions[0].id | https://openalex.org/I62916508 |
| authorships[2].institutions[0].ror | https://ror.org/02kkvpp62 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I62916508 |
| authorships[2].institutions[0].country_code | DE |
| authorships[2].institutions[0].display_name | Technical University of Munich |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Markus R. Anneser |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[3].author.id | https://openalex.org/A5113218415 |
| authorships[3].author.orcid | |
| authorships[3].author.display_name | Eva‐Maria H. J. Esslinger |
| authorships[3].countries | DE |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I62916508 |
| authorships[3].affiliations[0].raw_affiliation_string | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[3].institutions[0].id | https://openalex.org/I62916508 |
| authorships[3].institutions[0].ror | https://ror.org/02kkvpp62 |
| authorships[3].institutions[0].type | education |
| authorships[3].institutions[0].lineage | https://openalex.org/I62916508 |
| authorships[3].institutions[0].country_code | DE |
| authorships[3].institutions[0].display_name | Technical University of Munich |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Eva‐Maria H. J. Esslinger |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[4].author.id | https://openalex.org/A5112308823 |
| authorships[4].author.orcid | |
| authorships[4].author.display_name | Stefan Haslinger |
| authorships[4].countries | DE |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I62916508 |
| authorships[4].affiliations[0].raw_affiliation_string | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[4].institutions[0].id | https://openalex.org/I62916508 |
| authorships[4].institutions[0].ror | https://ror.org/02kkvpp62 |
| authorships[4].institutions[0].type | education |
| authorships[4].institutions[0].lineage | https://openalex.org/I62916508 |
| authorships[4].institutions[0].country_code | DE |
| authorships[4].institutions[0].display_name | Technical University of Munich |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Stefan Haslinger |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[5].author.id | https://openalex.org/A5015811493 |
| authorships[5].author.orcid | https://orcid.org/0000-0002-4156-780X |
| authorships[5].author.display_name | Fritz E. Kühn |
| authorships[5].countries | DE |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I62916508 |
| authorships[5].affiliations[0].raw_affiliation_string | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| authorships[5].institutions[0].id | https://openalex.org/I62916508 |
| authorships[5].institutions[0].ror | https://ror.org/02kkvpp62 |
| authorships[5].institutions[0].type | education |
| authorships[5].institutions[0].lineage | https://openalex.org/I62916508 |
| authorships[5].institutions[0].country_code | DE |
| authorships[5].institutions[0].display_name | Technical University of Munich |
| authorships[5].author_position | last |
| authorships[5].raw_author_name | Fritz E. Kühn |
| authorships[5].is_corresponding | True |
| authorships[5].raw_affiliation_strings | Molecular Catalysis, Catalysis Research Center and Department of Chemistry Department Technische Universität München Lichtenbergstrasse 4 D-85748 Garching bei München Germany |
| has_content.pdf | True |
| has_content.grobid_xml | True |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214 |
| open_access.oa_status | hybrid |
| open_access.any_repository_has_fulltext | False |
| created_date | 2020-03-27T00:00:00 |
| display_name | Electronic Finetuning of a Bio‐inspired Iron(II) tetra‐NHC Complex by trans Axial Isocyanide Substitution |
| has_fulltext | True |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T11790 |
| primary_topic.field.id | https://openalex.org/fields/16 |
| primary_topic.field.display_name | Chemistry |
| primary_topic.score | 0.9998000264167786 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/1605 |
| primary_topic.subfield.display_name | Organic Chemistry |
| primary_topic.display_name | N-Heterocyclic Carbenes in Organic and Inorganic Chemistry |
| related_works | https://openalex.org/W1990749895, https://openalex.org/W4394921354, https://openalex.org/W3180379284, https://openalex.org/W1982356735, https://openalex.org/W2084339730, https://openalex.org/W2953123463, https://openalex.org/W2951000415, https://openalex.org/W1987134648, https://openalex.org/W2393950418, https://openalex.org/W4250115240 |
| cited_by_count | 14 |
| counts_by_year[0].year | 2024 |
| counts_by_year[0].cited_by_count | 3 |
| counts_by_year[1].year | 2023 |
| counts_by_year[1].cited_by_count | 4 |
| counts_by_year[2].year | 2022 |
| counts_by_year[2].cited_by_count | 2 |
| counts_by_year[3].year | 2021 |
| counts_by_year[3].cited_by_count | 2 |
| counts_by_year[4].year | 2020 |
| counts_by_year[4].cited_by_count | 3 |
| locations_count | 3 |
| best_oa_location.id | doi:10.1002/asia.202000214 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S188582317 |
| best_oa_location.source.issn | 1861-471X, 1861-4728 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | False |
| best_oa_location.source.issn_l | 1861-471X |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | False |
| best_oa_location.source.display_name | Chemistry - An Asian Journal |
| best_oa_location.source.host_organization | https://openalex.org/P4310320595 |
| best_oa_location.source.host_organization_name | Wiley |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| best_oa_location.source.host_organization_lineage_names | Wiley |
| best_oa_location.license | cc-by-nc-nd |
| best_oa_location.pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214 |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | https://openalex.org/licenses/cc-by-nc-nd |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | Chemistry – An Asian Journal |
| best_oa_location.landing_page_url | https://doi.org/10.1002/asia.202000214 |
| primary_location.id | doi:10.1002/asia.202000214 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S188582317 |
| primary_location.source.issn | 1861-471X, 1861-4728 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | False |
| primary_location.source.issn_l | 1861-471X |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | False |
| primary_location.source.display_name | Chemistry - An Asian Journal |
| primary_location.source.host_organization | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_name | Wiley |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_lineage_names | Wiley |
| primary_location.license | cc-by-nc-nd |
| primary_location.pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/asia.202000214 |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | https://openalex.org/licenses/cc-by-nc-nd |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | Chemistry – An Asian Journal |
| primary_location.landing_page_url | https://doi.org/10.1002/asia.202000214 |
| publication_date | 2020-03-23 |
| publication_year | 2020 |
| referenced_works | https://openalex.org/W2178730319, https://openalex.org/W2060234909, https://openalex.org/W2034816859, https://openalex.org/W2125845584, https://openalex.org/W1964892471, https://openalex.org/W2080766536, https://openalex.org/W1989527051, https://openalex.org/W1967700647, https://openalex.org/W2763070859, https://openalex.org/W2056866121, https://openalex.org/W2109756675, https://openalex.org/W1981763423, https://openalex.org/W2079003866, https://openalex.org/W2003555872, https://openalex.org/W2138511707, https://openalex.org/W2122982305, https://openalex.org/W1991312972, https://openalex.org/W2315391999, https://openalex.org/W2335736263, https://openalex.org/W3003944012, https://openalex.org/W2054745973, https://openalex.org/W2606639737, https://openalex.org/W2166723686, https://openalex.org/W2487674689, https://openalex.org/W2033254662, https://openalex.org/W1973670792, https://openalex.org/W2914946363, https://openalex.org/W2023834187, https://openalex.org/W2101647682, https://openalex.org/W2060367335, https://openalex.org/W2116138670, https://openalex.org/W2314892269, https://openalex.org/W2021933689, https://openalex.org/W1979665527, https://openalex.org/W1984443047, https://openalex.org/W4377201228, https://openalex.org/W1996273492, https://openalex.org/W1969360633, https://openalex.org/W2146426024, https://openalex.org/W1979368277, https://openalex.org/W2132454074, https://openalex.org/W3012867199, https://openalex.org/W2969251433, https://openalex.org/W2949802072 |
| referenced_works_count | 44 |
| abstract_inverted_index.( | 8, 16, 113, 120, 128 |
| abstract_inverted_index.) | 11, 19 |
| abstract_inverted_index.1 | 9, 17, 31, 114, 121, 129 |
| abstract_inverted_index.E | 109, 116, 124 |
| abstract_inverted_index.N | 37 |
| abstract_inverted_index.V | 112, 119, 127 |
| abstract_inverted_index.a | 10, 54, 83, 103, 122 |
| abstract_inverted_index.b | 18, 130 |
| abstract_inverted_index.), | 115, 123 |
| abstract_inverted_index.). | 131 |
| abstract_inverted_index.an | 33, 97 |
| abstract_inverted_index.as | 102 |
| abstract_inverted_index.by | 79 |
| abstract_inverted_index.in | 86 |
| abstract_inverted_index.is | 47, 77 |
| abstract_inverted_index.of | 3, 21, 67, 74, 100, 105 |
| abstract_inverted_index.on | 70 |
| abstract_inverted_index.to | 61, 90 |
| abstract_inverted_index.1/2 | 110, 117, 125 |
| abstract_inverted_index.NMR | 49 |
| abstract_inverted_index.The | 1, 65 |
| abstract_inverted_index.and | 12, 40, 51 |
| abstract_inverted_index.the | 22, 58, 62, 71, 75, 91 |
| abstract_inverted_index.two | 41 |
| abstract_inverted_index.bis( | 13 |
| abstract_inverted_index.from | 57 |
| abstract_inverted_index.tert | 14 |
| abstract_inverted_index.with | 96 |
| abstract_inverted_index.=0.15 | 111 |
| abstract_inverted_index.=0.35 | 118 |
| abstract_inverted_index.=0.44 | 126 |
| abstract_inverted_index.axial | 43 |
| abstract_inverted_index.redox | 94 |
| abstract_inverted_index.tetra | 36 |
| abstract_inverted_index.their | 106 |
| abstract_inverted_index.trans | 4, 42 |
| abstract_inverted_index.active | 24 |
| abstract_inverted_index.couple | 95 |
| abstract_inverted_index.cyclic | 80 |
| abstract_inverted_index.highly | 23 |
| abstract_inverted_index.impact | 66 |
| abstract_inverted_index.labile | 44 |
| abstract_inverted_index.number | 99 |
| abstract_inverted_index.olefin | 28 |
| abstract_inverted_index.result | 104 |
| abstract_inverted_index.axially | 5 |
| abstract_inverted_index.bearing | 32 |
| abstract_inverted_index.carbene | 39 |
| abstract_inverted_index.centres | 60 |
| abstract_inverted_index.ligands | 46 |
| abstract_inverted_index.mono‐ | 7 |
| abstract_inverted_index.studied | 78 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.SC‐XRD | 52 |
| abstract_inverted_index.features | 73 |
| abstract_inverted_index.increase | 85 |
| abstract_inverted_index.indicate | 53 |
| abstract_inverted_index.iron(II) | 27, 59 |
| abstract_inverted_index.complexes | 76 |
| abstract_inverted_index.potential | 88 |
| abstract_inverted_index.reported. | 48 |
| abstract_inverted_index.revealing | 82 |
| abstract_inverted_index.synthesis | 2 |
| abstract_inverted_index.assignable | 89 |
| abstract_inverted_index.electronic | 72 |
| abstract_inverted_index.equatorial | 34 |
| abstract_inverted_index.increasing | 98 |
| abstract_inverted_index.isocyanide | 63, 68 |
| abstract_inverted_index.ligand(s). | 64 |
| abstract_inverted_index.reversible | 92 |
| abstract_inverted_index.derivatives | 20 |
| abstract_inverted_index.epoxidation | 29 |
| abstract_inverted_index.half‐cell | 87 |
| abstract_inverted_index.homogeneous | 25 |
| abstract_inverted_index.isocyanides | 101 |
| abstract_inverted_index.macrocyclic | 35 |
| abstract_inverted_index.properties: | 108 |
| abstract_inverted_index.significant | 84 |
| abstract_inverted_index.substituted | 6 |
| abstract_inverted_index.voltammetry | 81 |
| abstract_inverted_index.acetonitrile | 45 |
| abstract_inverted_index.considerable | 55 |
| abstract_inverted_index.spectroscopy | 50 |
| abstract_inverted_index.substitution | 69 |
| abstract_inverted_index.Fe(II)/Fe(III) | 93 |
| abstract_inverted_index.bio‐inspired | 26 |
| abstract_inverted_index.π‐accepting | 107 |
| abstract_inverted_index.‐heterocyclic | 38 |
| abstract_inverted_index.(pre‐)catalyst | 30 |
| abstract_inverted_index.π‐backdonation | 56 |
| abstract_inverted_index.‐butylisocyanide) | 15 |
| cited_by_percentile_year.max | 97 |
| cited_by_percentile_year.min | 93 |
| corresponding_author_ids | https://openalex.org/A5015811493 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 6 |
| corresponding_institution_ids | https://openalex.org/I62916508 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/6 |
| sustainable_development_goals[0].score | 0.6000000238418579 |
| sustainable_development_goals[0].display_name | Clean water and sanitation |
| citation_normalized_percentile.value | 0.75131943 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |