Electronic Structure of trans‐[VIICl2(E(CH3)2CH2CH2E(CH3)2)2], E=N, P Article Swipe
Mehrafshan G. Jafari
,
Eva M. Zolnhofer
,
Dominik Fehn
,
Frank W. Heinemann
,
Adedamola A. Opalade
,
Patrick J. Carroll
,
Karsten Meyer
,
J. Krzystek
,
Andrew Ozarowski
,
Daniel J. Mindiola
,
Timothy A. Jackson
,
Joshua Telser
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/ejic.202400395
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/ejic.202400395
Coordination complexes of general formula trans ‐[MX 2 (R 2 ECH 2 CH 2 ER 2 ) 2 ] (M II =Ti, V, Cr, Mn; E=N or P; R=alkyl or aryl) are a cornerstone of coordination and organometallic chemistry. We investigate the electronic properties of two such complexes, trans ‐[VCl 2 (tmeda) 2 ] and trans ‐[VCl 2 (dmpe) 2 ], which thus represent trans ‐[MX 2 (R 2 ECH 2 CH 2 ER 2 ) 2 ] where M=V, X=Cl, R=Me and E=N (tmeda) and P (dmpe). These V II complexes have S =3/2 ground states, as expected for octahedral d 3 . Their tetragonal distortion leads to zero‐field splitting (zfs) that is modest in magnitude ( D ≈0.3 cm −1 ) relative to analogous S =1 Ti II and Cr II complexes. This parameter was determined from conventional EPR spectroscopy, but more effectively from high‐frequency and ‐field EPR (HFEPR) that determined the sign of D as negative for the diamine complex, but positive for the diphosphine, which information had not been known for any trans ‐[VX 2 (R 2 ECH 2 CH 2 ER 2 ) 2 ] systems. The ligand‐field parameters of trans ‐[VCl 2 (tmeda) 2 ] and trans ‐[VCl 2 (dmpe) 2 ] are obtained using both classical theory and ab initio quantum chemical theory. The results shed light not only on the electronic structure of V II in this environment, but also on differences between N and P donor ligands, a key comparison in coordination chemistry.
Related Topics
Concepts
Chemistry
Electron paramagnetic resonance
Ligand field theory
Octahedron
Crystallography
Electronic structure
Stereochemistry
Orthorhombic crystal system
Ligand (biochemistry)
Coordination complex
Ab initio
Crystal structure
Metal
Computational chemistry
Ion
Nuclear magnetic resonance
Physics
Biochemistry
Organic chemistry
Receptor
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/ejic.202400395
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395
- OA Status
- bronze
- References
- 54
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4401215403
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W4401215403Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/ejic.202400395Digital Object Identifier
- Title
-
Electronic Structure of trans‐[VIICl2(E(CH3)2CH2CH2E(CH3)2)2], E=N, PWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-08-01Full publication date if available
- Authors
-
Mehrafshan G. Jafari, Eva M. Zolnhofer, Dominik Fehn, Frank W. Heinemann, Adedamola A. Opalade, Patrick J. Carroll, Karsten Meyer, J. Krzystek, Andrew Ozarowski, Daniel J. Mindiola, Timothy A. Jackson, Joshua TelserList of authors in order
- Landing page
-
https://doi.org/10.1002/ejic.202400395Publisher landing page
- PDF URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
bronzeOpen access status per OpenAlex
- OA URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395Direct OA link when available
- Concepts
-
Chemistry, Electron paramagnetic resonance, Ligand field theory, Octahedron, Crystallography, Electronic structure, Stereochemistry, Orthorhombic crystal system, Ligand (biochemistry), Coordination complex, Ab initio, Crystal structure, Metal, Computational chemistry, Ion, Nuclear magnetic resonance, Physics, Biochemistry, Organic chemistry, ReceptorTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
0Total citation count in OpenAlex
- References (count)
-
54Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W4401215403 |
|---|---|
| doi | https://doi.org/10.1002/ejic.202400395 |
| ids.doi | https://doi.org/10.1002/ejic.202400395 |
| ids.openalex | https://openalex.org/W4401215403 |
| fwci | 0.0 |
| type | article |
| title | Electronic Structure of trans‐[VIICl2(E(CH3)2CH2CH2E(CH3)2)2], E=N, P |
| awards[0].id | https://openalex.org/G3539515544 |
| awards[0].funder_id | https://openalex.org/F4320306076 |
| awards[0].display_name | |
| awards[0].funder_award_id | CHE-1900384 |
| awards[0].funder_display_name | National Science Foundation |
| biblio.issue | 34 |
| biblio.volume | 27 |
| biblio.last_page | |
| biblio.first_page | |
| topics[0].id | https://openalex.org/T10092 |
| topics[0].field.id | https://openalex.org/fields/16 |
| topics[0].field.display_name | Chemistry |
| topics[0].score | 0.9998000264167786 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/1605 |
| topics[0].subfield.display_name | Organic Chemistry |
| topics[0].display_name | Organometallic Complex Synthesis and Catalysis |
| topics[1].id | https://openalex.org/T10163 |
| topics[1].field.id | https://openalex.org/fields/27 |
| topics[1].field.display_name | Medicine |
| topics[1].score | 0.9995999932289124 |
| topics[1].domain.id | https://openalex.org/domains/4 |
| topics[1].domain.display_name | Health Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/2730 |
| topics[1].subfield.display_name | Oncology |
| topics[1].display_name | Metal complexes synthesis and properties |
| topics[2].id | https://openalex.org/T11784 |
| topics[2].field.id | https://openalex.org/fields/21 |
| topics[2].field.display_name | Energy |
| topics[2].score | 0.9994000196456909 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/2105 |
| topics[2].subfield.display_name | Renewable Energy, Sustainability and the Environment |
| topics[2].display_name | CO2 Reduction Techniques and Catalysts |
| funders[0].id | https://openalex.org/F4320306076 |
| funders[0].ror | https://ror.org/021nxhr62 |
| funders[0].display_name | National Science Foundation |
| is_xpac | False |
| apc_list.value | 3860 |
| apc_list.currency | USD |
| apc_list.value_usd | 3860 |
| apc_paid | |
| concepts[0].id | https://openalex.org/C185592680 |
| concepts[0].level | 0 |
| concepts[0].score | 0.8751856088638306 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[0].display_name | Chemistry |
| concepts[1].id | https://openalex.org/C187961010 |
| concepts[1].level | 2 |
| concepts[1].score | 0.6577836275100708 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q260463 |
| concepts[1].display_name | Electron paramagnetic resonance |
| concepts[2].id | https://openalex.org/C57805442 |
| concepts[2].level | 3 |
| concepts[2].score | 0.6353645324707031 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q898951 |
| concepts[2].display_name | Ligand field theory |
| concepts[3].id | https://openalex.org/C198819137 |
| concepts[3].level | 3 |
| concepts[3].score | 0.5854502320289612 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q188884 |
| concepts[3].display_name | Octahedron |
| concepts[4].id | https://openalex.org/C8010536 |
| concepts[4].level | 1 |
| concepts[4].score | 0.5767931938171387 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q160398 |
| concepts[4].display_name | Crystallography |
| concepts[5].id | https://openalex.org/C86025842 |
| concepts[5].level | 2 |
| concepts[5].score | 0.49814414978027344 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q5358432 |
| concepts[5].display_name | Electronic structure |
| concepts[6].id | https://openalex.org/C71240020 |
| concepts[6].level | 1 |
| concepts[6].score | 0.4601360857486725 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q186011 |
| concepts[6].display_name | Stereochemistry |
| concepts[7].id | https://openalex.org/C37243968 |
| concepts[7].level | 3 |
| concepts[7].score | 0.45999157428741455 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q648961 |
| concepts[7].display_name | Orthorhombic crystal system |
| concepts[8].id | https://openalex.org/C116569031 |
| concepts[8].level | 3 |
| concepts[8].score | 0.44410187005996704 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q899107 |
| concepts[8].display_name | Ligand (biochemistry) |
| concepts[9].id | https://openalex.org/C68913812 |
| concepts[9].level | 3 |
| concepts[9].score | 0.4268485903739929 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q238156 |
| concepts[9].display_name | Coordination complex |
| concepts[10].id | https://openalex.org/C2781442258 |
| concepts[10].level | 2 |
| concepts[10].score | 0.41078421473503113 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q46310 |
| concepts[10].display_name | Ab initio |
| concepts[11].id | https://openalex.org/C115624301 |
| concepts[11].level | 2 |
| concepts[11].score | 0.28579360246658325 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q895901 |
| concepts[11].display_name | Crystal structure |
| concepts[12].id | https://openalex.org/C544153396 |
| concepts[12].level | 2 |
| concepts[12].score | 0.2787272334098816 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q11426 |
| concepts[12].display_name | Metal |
| concepts[13].id | https://openalex.org/C147597530 |
| concepts[13].level | 1 |
| concepts[13].score | 0.23565146327018738 |
| concepts[13].wikidata | https://www.wikidata.org/wiki/Q369472 |
| concepts[13].display_name | Computational chemistry |
| concepts[14].id | https://openalex.org/C145148216 |
| concepts[14].level | 2 |
| concepts[14].score | 0.16642731428146362 |
| concepts[14].wikidata | https://www.wikidata.org/wiki/Q36496 |
| concepts[14].display_name | Ion |
| concepts[15].id | https://openalex.org/C46141821 |
| concepts[15].level | 1 |
| concepts[15].score | 0.15500935912132263 |
| concepts[15].wikidata | https://www.wikidata.org/wiki/Q209402 |
| concepts[15].display_name | Nuclear magnetic resonance |
| concepts[16].id | https://openalex.org/C121332964 |
| concepts[16].level | 0 |
| concepts[16].score | 0.10049563646316528 |
| concepts[16].wikidata | https://www.wikidata.org/wiki/Q413 |
| concepts[16].display_name | Physics |
| concepts[17].id | https://openalex.org/C55493867 |
| concepts[17].level | 1 |
| concepts[17].score | 0.0 |
| concepts[17].wikidata | https://www.wikidata.org/wiki/Q7094 |
| concepts[17].display_name | Biochemistry |
| concepts[18].id | https://openalex.org/C178790620 |
| concepts[18].level | 1 |
| concepts[18].score | 0.0 |
| concepts[18].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[18].display_name | Organic chemistry |
| concepts[19].id | https://openalex.org/C170493617 |
| concepts[19].level | 2 |
| concepts[19].score | 0.0 |
| concepts[19].wikidata | https://www.wikidata.org/wiki/Q208467 |
| concepts[19].display_name | Receptor |
| keywords[0].id | https://openalex.org/keywords/chemistry |
| keywords[0].score | 0.8751856088638306 |
| keywords[0].display_name | Chemistry |
| keywords[1].id | https://openalex.org/keywords/electron-paramagnetic-resonance |
| keywords[1].score | 0.6577836275100708 |
| keywords[1].display_name | Electron paramagnetic resonance |
| keywords[2].id | https://openalex.org/keywords/ligand-field-theory |
| keywords[2].score | 0.6353645324707031 |
| keywords[2].display_name | Ligand field theory |
| keywords[3].id | https://openalex.org/keywords/octahedron |
| keywords[3].score | 0.5854502320289612 |
| keywords[3].display_name | Octahedron |
| keywords[4].id | https://openalex.org/keywords/crystallography |
| keywords[4].score | 0.5767931938171387 |
| keywords[4].display_name | Crystallography |
| keywords[5].id | https://openalex.org/keywords/electronic-structure |
| keywords[5].score | 0.49814414978027344 |
| keywords[5].display_name | Electronic structure |
| keywords[6].id | https://openalex.org/keywords/stereochemistry |
| keywords[6].score | 0.4601360857486725 |
| keywords[6].display_name | Stereochemistry |
| keywords[7].id | https://openalex.org/keywords/orthorhombic-crystal-system |
| keywords[7].score | 0.45999157428741455 |
| keywords[7].display_name | Orthorhombic crystal system |
| keywords[8].id | https://openalex.org/keywords/ligand |
| keywords[8].score | 0.44410187005996704 |
| keywords[8].display_name | Ligand (biochemistry) |
| keywords[9].id | https://openalex.org/keywords/coordination-complex |
| keywords[9].score | 0.4268485903739929 |
| keywords[9].display_name | Coordination complex |
| keywords[10].id | https://openalex.org/keywords/ab-initio |
| keywords[10].score | 0.41078421473503113 |
| keywords[10].display_name | Ab initio |
| keywords[11].id | https://openalex.org/keywords/crystal-structure |
| keywords[11].score | 0.28579360246658325 |
| keywords[11].display_name | Crystal structure |
| keywords[12].id | https://openalex.org/keywords/metal |
| keywords[12].score | 0.2787272334098816 |
| keywords[12].display_name | Metal |
| keywords[13].id | https://openalex.org/keywords/computational-chemistry |
| keywords[13].score | 0.23565146327018738 |
| keywords[13].display_name | Computational chemistry |
| keywords[14].id | https://openalex.org/keywords/ion |
| keywords[14].score | 0.16642731428146362 |
| keywords[14].display_name | Ion |
| keywords[15].id | https://openalex.org/keywords/nuclear-magnetic-resonance |
| keywords[15].score | 0.15500935912132263 |
| keywords[15].display_name | Nuclear magnetic resonance |
| keywords[16].id | https://openalex.org/keywords/physics |
| keywords[16].score | 0.10049563646316528 |
| keywords[16].display_name | Physics |
| language | en |
| locations[0].id | doi:10.1002/ejic.202400395 |
| locations[0].is_oa | True |
| locations[0].source.id | https://openalex.org/S16435181 |
| locations[0].source.issn | 1099-0682, 1434-1948 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | False |
| locations[0].source.issn_l | 1099-0682 |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | False |
| locations[0].source.display_name | European Journal of Inorganic Chemistry |
| locations[0].source.host_organization | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_name | Wiley |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_lineage_names | Wiley |
| locations[0].license | |
| locations[0].pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395 |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | European Journal of Inorganic Chemistry |
| locations[0].landing_page_url | https://doi.org/10.1002/ejic.202400395 |
| indexed_in | crossref |
| authorships[0].author.id | https://openalex.org/A5089534950 |
| authorships[0].author.orcid | https://orcid.org/0000-0001-6807-7520 |
| authorships[0].author.display_name | Mehrafshan G. Jafari |
| authorships[0].countries | US |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I79576946 |
| authorships[0].affiliations[0].raw_affiliation_string | Department of Chemistry University of Pennsylvania Philadelphia, Pennsylvania 19104 United States |
| authorships[0].institutions[0].id | https://openalex.org/I79576946 |
| authorships[0].institutions[0].ror | https://ror.org/00b30xv10 |
| authorships[0].institutions[0].type | education |
| authorships[0].institutions[0].lineage | https://openalex.org/I79576946 |
| authorships[0].institutions[0].country_code | US |
| authorships[0].institutions[0].display_name | University of Pennsylvania |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Mehrafshan G. Jafari |
| authorships[0].is_corresponding | False |
| authorships[0].raw_affiliation_strings | Department of Chemistry University of Pennsylvania Philadelphia, Pennsylvania 19104 United States |
| authorships[1].author.id | https://openalex.org/A5067727357 |
| authorships[1].author.orcid | https://orcid.org/0000-0001-8614-5064 |
| authorships[1].author.display_name | Eva M. Zolnhofer |
| authorships[1].countries | DE |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I181369854 |
| authorships[1].affiliations[0].raw_affiliation_string | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[1].institutions[0].id | https://openalex.org/I181369854 |
| authorships[1].institutions[0].ror | https://ror.org/00f7hpc57 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I181369854 |
| authorships[1].institutions[0].country_code | DE |
| authorships[1].institutions[0].display_name | Friedrich-Alexander-Universität Erlangen-Nürnberg |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Eva M. Zolnhofer |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[2].author.id | https://openalex.org/A5018127084 |
| authorships[2].author.orcid | https://orcid.org/0000-0003-1377-4905 |
| authorships[2].author.display_name | Dominik Fehn |
| authorships[2].countries | DE |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I181369854 |
| authorships[2].affiliations[0].raw_affiliation_string | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[2].institutions[0].id | https://openalex.org/I181369854 |
| authorships[2].institutions[0].ror | https://ror.org/00f7hpc57 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I181369854 |
| authorships[2].institutions[0].country_code | DE |
| authorships[2].institutions[0].display_name | Friedrich-Alexander-Universität Erlangen-Nürnberg |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Dominik Fehn |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[3].author.id | https://openalex.org/A5051317911 |
| authorships[3].author.orcid | https://orcid.org/0000-0002-9007-8404 |
| authorships[3].author.display_name | Frank W. Heinemann |
| authorships[3].countries | DE |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I181369854 |
| authorships[3].affiliations[0].raw_affiliation_string | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[3].institutions[0].id | https://openalex.org/I181369854 |
| authorships[3].institutions[0].ror | https://ror.org/00f7hpc57 |
| authorships[3].institutions[0].type | education |
| authorships[3].institutions[0].lineage | https://openalex.org/I181369854 |
| authorships[3].institutions[0].country_code | DE |
| authorships[3].institutions[0].display_name | Friedrich-Alexander-Universität Erlangen-Nürnberg |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Frank W. Heinemann |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[4].author.id | https://openalex.org/A5001225668 |
| authorships[4].author.orcid | https://orcid.org/0000-0001-8508-2807 |
| authorships[4].author.display_name | Adedamola A. Opalade |
| authorships[4].countries | US |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I146416000 |
| authorships[4].affiliations[0].raw_affiliation_string | Department of Chemistry University of Kansas 1567 Irving Hill Road Lawrence, Kansas 66045 United States |
| authorships[4].institutions[0].id | https://openalex.org/I146416000 |
| authorships[4].institutions[0].ror | https://ror.org/001tmjg57 |
| authorships[4].institutions[0].type | education |
| authorships[4].institutions[0].lineage | https://openalex.org/I146416000 |
| authorships[4].institutions[0].country_code | US |
| authorships[4].institutions[0].display_name | University of Kansas |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Adedamola A. Opalade |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | Department of Chemistry University of Kansas 1567 Irving Hill Road Lawrence, Kansas 66045 United States |
| authorships[5].author.id | https://openalex.org/A5056500036 |
| authorships[5].author.orcid | https://orcid.org/0000-0002-8142-7211 |
| authorships[5].author.display_name | Patrick J. Carroll |
| authorships[5].countries | US |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I79576946 |
| authorships[5].affiliations[0].raw_affiliation_string | Department of Chemistry University of Pennsylvania Philadelphia, Pennsylvania 19104 United States |
| authorships[5].institutions[0].id | https://openalex.org/I79576946 |
| authorships[5].institutions[0].ror | https://ror.org/00b30xv10 |
| authorships[5].institutions[0].type | education |
| authorships[5].institutions[0].lineage | https://openalex.org/I79576946 |
| authorships[5].institutions[0].country_code | US |
| authorships[5].institutions[0].display_name | University of Pennsylvania |
| authorships[5].author_position | middle |
| authorships[5].raw_author_name | Patrick J. Carroll |
| authorships[5].is_corresponding | False |
| authorships[5].raw_affiliation_strings | Department of Chemistry University of Pennsylvania Philadelphia, Pennsylvania 19104 United States |
| authorships[6].author.id | https://openalex.org/A5011918079 |
| authorships[6].author.orcid | https://orcid.org/0000-0002-7844-2998 |
| authorships[6].author.display_name | Karsten Meyer |
| authorships[6].countries | DE |
| authorships[6].affiliations[0].institution_ids | https://openalex.org/I181369854 |
| authorships[6].affiliations[0].raw_affiliation_string | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[6].institutions[0].id | https://openalex.org/I181369854 |
| authorships[6].institutions[0].ror | https://ror.org/00f7hpc57 |
| authorships[6].institutions[0].type | education |
| authorships[6].institutions[0].lineage | https://openalex.org/I181369854 |
| authorships[6].institutions[0].country_code | DE |
| authorships[6].institutions[0].display_name | Friedrich-Alexander-Universität Erlangen-Nürnberg |
| authorships[6].author_position | middle |
| authorships[6].raw_author_name | Karsten Meyer |
| authorships[6].is_corresponding | False |
| authorships[6].raw_affiliation_strings | Department of Chemistry and Pharmacy, Inorganic Chemistry Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) 91058 Erlangen Germany |
| authorships[7].author.id | https://openalex.org/A5076922382 |
| authorships[7].author.orcid | https://orcid.org/0000-0001-6088-1936 |
| authorships[7].author.display_name | J. Krzystek |
| authorships[7].countries | US |
| authorships[7].affiliations[0].institution_ids | https://openalex.org/I103163165, https://openalex.org/I4210132808 |
| authorships[7].affiliations[0].raw_affiliation_string | National High Magnetic Field Laboratory Florida State University Tallahassee, Florida 32310 United States |
| authorships[7].institutions[0].id | https://openalex.org/I103163165 |
| authorships[7].institutions[0].ror | https://ror.org/05g3dte14 |
| authorships[7].institutions[0].type | education |
| authorships[7].institutions[0].lineage | https://openalex.org/I103163165 |
| authorships[7].institutions[0].country_code | US |
| authorships[7].institutions[0].display_name | Florida State University |
| authorships[7].institutions[1].id | https://openalex.org/I4210132808 |
| authorships[7].institutions[1].ror | https://ror.org/03s53g630 |
| authorships[7].institutions[1].type | facility |
| authorships[7].institutions[1].lineage | https://openalex.org/I103163165, https://openalex.org/I1311060795, https://openalex.org/I1330989302, https://openalex.org/I1343871089, https://openalex.org/I198811213, https://openalex.org/I33213144, https://openalex.org/I4210120050, https://openalex.org/I4210132808 |
| authorships[7].institutions[1].country_code | US |
| authorships[7].institutions[1].display_name | National High Magnetic Field Laboratory |
| authorships[7].author_position | middle |
| authorships[7].raw_author_name | J. Krzystek |
| authorships[7].is_corresponding | False |
| authorships[7].raw_affiliation_strings | National High Magnetic Field Laboratory Florida State University Tallahassee, Florida 32310 United States |
| authorships[8].author.id | https://openalex.org/A5067242790 |
| authorships[8].author.orcid | https://orcid.org/0000-0001-6225-9796 |
| authorships[8].author.display_name | Andrew Ozarowski |
| authorships[8].countries | US |
| authorships[8].affiliations[0].institution_ids | https://openalex.org/I103163165, https://openalex.org/I4210132808 |
| authorships[8].affiliations[0].raw_affiliation_string | National High Magnetic Field Laboratory Florida State University Tallahassee, Florida 32310 United States |
| authorships[8].institutions[0].id | https://openalex.org/I103163165 |
| authorships[8].institutions[0].ror | https://ror.org/05g3dte14 |
| authorships[8].institutions[0].type | education |
| authorships[8].institutions[0].lineage | https://openalex.org/I103163165 |
| authorships[8].institutions[0].country_code | US |
| authorships[8].institutions[0].display_name | Florida State University |
| authorships[8].institutions[1].id | https://openalex.org/I4210132808 |
| authorships[8].institutions[1].ror | https://ror.org/03s53g630 |
| authorships[8].institutions[1].type | facility |
| authorships[8].institutions[1].lineage | https://openalex.org/I103163165, https://openalex.org/I1311060795, https://openalex.org/I1330989302, https://openalex.org/I1343871089, https://openalex.org/I198811213, https://openalex.org/I33213144, https://openalex.org/I4210120050, https://openalex.org/I4210132808 |
| authorships[8].institutions[1].country_code | US |
| authorships[8].institutions[1].display_name | National High Magnetic Field Laboratory |
| authorships[8].author_position | middle |
| authorships[8].raw_author_name | Andrew Ozarowski |
| authorships[8].is_corresponding | False |
| authorships[8].raw_affiliation_strings | National High Magnetic Field Laboratory Florida State University Tallahassee, Florida 32310 United States |
| authorships[9].author.id | https://openalex.org/A5080206718 |
| authorships[9].author.orcid | https://orcid.org/0000-0001-8205-7868 |
| authorships[9].author.display_name | Daniel J. Mindiola |
| authorships[9].countries | US |
| authorships[9].affiliations[0].institution_ids | https://openalex.org/I79576946 |
| authorships[9].affiliations[0].raw_affiliation_string | Department of Chemistry University of Pennsylvania Philadelphia, Pennsylvania 19104 United States |
| authorships[9].institutions[0].id | https://openalex.org/I79576946 |
| authorships[9].institutions[0].ror | https://ror.org/00b30xv10 |
| authorships[9].institutions[0].type | education |
| authorships[9].institutions[0].lineage | https://openalex.org/I79576946 |
| authorships[9].institutions[0].country_code | US |
| authorships[9].institutions[0].display_name | University of Pennsylvania |
| authorships[9].author_position | middle |
| authorships[9].raw_author_name | Daniel J. Mindiola |
| authorships[9].is_corresponding | False |
| authorships[9].raw_affiliation_strings | Department of Chemistry University of Pennsylvania Philadelphia, Pennsylvania 19104 United States |
| authorships[10].author.id | https://openalex.org/A5068835223 |
| authorships[10].author.orcid | https://orcid.org/0000-0002-3529-2715 |
| authorships[10].author.display_name | Timothy A. Jackson |
| authorships[10].countries | US |
| authorships[10].affiliations[0].institution_ids | https://openalex.org/I146416000 |
| authorships[10].affiliations[0].raw_affiliation_string | Department of Chemistry University of Kansas 1567 Irving Hill Road Lawrence, Kansas 66045 United States |
| authorships[10].institutions[0].id | https://openalex.org/I146416000 |
| authorships[10].institutions[0].ror | https://ror.org/001tmjg57 |
| authorships[10].institutions[0].type | education |
| authorships[10].institutions[0].lineage | https://openalex.org/I146416000 |
| authorships[10].institutions[0].country_code | US |
| authorships[10].institutions[0].display_name | University of Kansas |
| authorships[10].author_position | middle |
| authorships[10].raw_author_name | Timothy A. Jackson |
| authorships[10].is_corresponding | False |
| authorships[10].raw_affiliation_strings | Department of Chemistry University of Kansas 1567 Irving Hill Road Lawrence, Kansas 66045 United States |
| authorships[11].author.id | https://openalex.org/A5000558729 |
| authorships[11].author.orcid | https://orcid.org/0000-0003-3307-2556 |
| authorships[11].author.display_name | Joshua Telser |
| authorships[11].countries | US |
| authorships[11].affiliations[0].institution_ids | https://openalex.org/I102101047 |
| authorships[11].affiliations[0].raw_affiliation_string | Roosevelt University, Department of Biology, Chemistry, and Physical Sciences, 430 S. Michigan Ave, 60605 Chicago, UNITED STATES OF AMERICA |
| authorships[11].institutions[0].id | https://openalex.org/I102101047 |
| authorships[11].institutions[0].ror | https://ror.org/020vmqv16 |
| authorships[11].institutions[0].type | education |
| authorships[11].institutions[0].lineage | https://openalex.org/I102101047 |
| authorships[11].institutions[0].country_code | US |
| authorships[11].institutions[0].display_name | Roosevelt University |
| authorships[11].author_position | last |
| authorships[11].raw_author_name | Joshua Telser |
| authorships[11].is_corresponding | True |
| authorships[11].raw_affiliation_strings | Roosevelt University, Department of Biology, Chemistry, and Physical Sciences, 430 S. Michigan Ave, 60605 Chicago, UNITED STATES OF AMERICA |
| has_content.pdf | True |
| has_content.grobid_xml | False |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395 |
| open_access.oa_status | bronze |
| open_access.any_repository_has_fulltext | False |
| created_date | 2025-10-10T00:00:00 |
| display_name | Electronic Structure of trans‐[VIICl2(E(CH3)2CH2CH2E(CH3)2)2], E=N, P |
| has_fulltext | False |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T10092 |
| primary_topic.field.id | https://openalex.org/fields/16 |
| primary_topic.field.display_name | Chemistry |
| primary_topic.score | 0.9998000264167786 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/1605 |
| primary_topic.subfield.display_name | Organic Chemistry |
| primary_topic.display_name | Organometallic Complex Synthesis and Catalysis |
| related_works | https://openalex.org/W1981011544, https://openalex.org/W2082337540, https://openalex.org/W2084916282, https://openalex.org/W1994875143, https://openalex.org/W4240477990, https://openalex.org/W2039342409, https://openalex.org/W2067835298, https://openalex.org/W217254777, https://openalex.org/W2021044989, https://openalex.org/W1516884963 |
| cited_by_count | 0 |
| locations_count | 1 |
| best_oa_location.id | doi:10.1002/ejic.202400395 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S16435181 |
| best_oa_location.source.issn | 1099-0682, 1434-1948 |
| best_oa_location.source.type | journal |
| best_oa_location.source.is_oa | False |
| best_oa_location.source.issn_l | 1099-0682 |
| best_oa_location.source.is_core | True |
| best_oa_location.source.is_in_doaj | False |
| best_oa_location.source.display_name | European Journal of Inorganic Chemistry |
| best_oa_location.source.host_organization | https://openalex.org/P4310320595 |
| best_oa_location.source.host_organization_name | Wiley |
| best_oa_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| best_oa_location.source.host_organization_lineage_names | Wiley |
| best_oa_location.license | |
| best_oa_location.pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395 |
| best_oa_location.version | publishedVersion |
| best_oa_location.raw_type | journal-article |
| best_oa_location.license_id | |
| best_oa_location.is_accepted | True |
| best_oa_location.is_published | True |
| best_oa_location.raw_source_name | European Journal of Inorganic Chemistry |
| best_oa_location.landing_page_url | https://doi.org/10.1002/ejic.202400395 |
| primary_location.id | doi:10.1002/ejic.202400395 |
| primary_location.is_oa | True |
| primary_location.source.id | https://openalex.org/S16435181 |
| primary_location.source.issn | 1099-0682, 1434-1948 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | False |
| primary_location.source.issn_l | 1099-0682 |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | False |
| primary_location.source.display_name | European Journal of Inorganic Chemistry |
| primary_location.source.host_organization | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_name | Wiley |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_lineage_names | Wiley |
| primary_location.license | |
| primary_location.pdf_url | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202400395 |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | European Journal of Inorganic Chemistry |
| primary_location.landing_page_url | https://doi.org/10.1002/ejic.202400395 |
| publication_date | 2024-08-01 |
| publication_year | 2024 |
| referenced_works | https://openalex.org/W1974370161, https://openalex.org/W2070982858, https://openalex.org/W2004395045, https://openalex.org/W1997550078, https://openalex.org/W2170793973, https://openalex.org/W2002848990, https://openalex.org/W2466064439, https://openalex.org/W3015351260, https://openalex.org/W3034422183, https://openalex.org/W1969957097, https://openalex.org/W2068660531, https://openalex.org/W2056851663, https://openalex.org/W2157734893, https://openalex.org/W1858887304, https://openalex.org/W2136270314, https://openalex.org/W1982182382, https://openalex.org/W2056254282, https://openalex.org/W2087943866, https://openalex.org/W4223907221, https://openalex.org/W3192136363, https://openalex.org/W1997343083, https://openalex.org/W1819858826, https://openalex.org/W2134163000, https://openalex.org/W2157488983, https://openalex.org/W2088440437, https://openalex.org/W2077325420, https://openalex.org/W1973642089, https://openalex.org/W2096623546, https://openalex.org/W2067718414, https://openalex.org/W3210663094, https://openalex.org/W2787133322, https://openalex.org/W1995554509, https://openalex.org/W1479896687, https://openalex.org/W2891094560, https://openalex.org/W3014928962, https://openalex.org/W2801763239, https://openalex.org/W2068937827, https://openalex.org/W2029120395, https://openalex.org/W2010872322, https://openalex.org/W2952915922, https://openalex.org/W2845490148, https://openalex.org/W2077215848, https://openalex.org/W2006962588, https://openalex.org/W2058596427, https://openalex.org/W2033924505, https://openalex.org/W936914979, https://openalex.org/W1965505987, https://openalex.org/W4250304056, https://openalex.org/W2088633247, https://openalex.org/W1489107012, https://openalex.org/W1598334653, https://openalex.org/W4235985965, https://openalex.org/W2150935491, https://openalex.org/W2003553733 |
| referenced_works_count | 54 |
| abstract_inverted_index.( | 118 |
| abstract_inverted_index.) | 17, 76, 123, 188 |
| abstract_inverted_index.. | 104 |
| abstract_inverted_index.2 | 8, 10, 12, 14, 16, 18, 51, 53, 58, 60, 67, 69, 71, 73, 75, 77, 179, 181, 183, 185, 187, 189, 198, 200, 205, 207 |
| abstract_inverted_index.3 | 103 |
| abstract_inverted_index.D | 119, 157 |
| abstract_inverted_index.N | 242 |
| abstract_inverted_index.P | 87, 244 |
| abstract_inverted_index.S | 94, 127 |
| abstract_inverted_index.V | 90, 232 |
| abstract_inverted_index.] | 19, 54, 78, 190, 201, 208 |
| abstract_inverted_index.a | 33, 247 |
| abstract_inverted_index.d | 102 |
| abstract_inverted_index.(M | 20 |
| abstract_inverted_index.(R | 9, 68, 180 |
| abstract_inverted_index.=1 | 128 |
| abstract_inverted_index.CH | 13, 72, 184 |
| abstract_inverted_index.Cr | 132 |
| abstract_inverted_index.ER | 15, 74, 186 |
| abstract_inverted_index.II | 21, 91, 130, 133, 233 |
| abstract_inverted_index.P; | 28 |
| abstract_inverted_index.Ti | 129 |
| abstract_inverted_index.V, | 23 |
| abstract_inverted_index.We | 40 |
| abstract_inverted_index.], | 61 |
| abstract_inverted_index.ab | 216 |
| abstract_inverted_index.as | 98, 158 |
| abstract_inverted_index.cm | 121 |
| abstract_inverted_index.in | 116, 234, 250 |
| abstract_inverted_index.is | 114 |
| abstract_inverted_index.of | 3, 35, 45, 156, 195, 231 |
| abstract_inverted_index.on | 227, 239 |
| abstract_inverted_index.or | 27, 30 |
| abstract_inverted_index.to | 109, 125 |
| abstract_inverted_index.Cr, | 24 |
| abstract_inverted_index.E=N | 26, 84 |
| abstract_inverted_index.ECH | 11, 70, 182 |
| abstract_inverted_index.EPR | 141, 150 |
| abstract_inverted_index.Mn; | 25 |
| abstract_inverted_index.The | 192, 221 |
| abstract_inverted_index.and | 37, 55, 83, 86, 131, 148, 202, 215, 243 |
| abstract_inverted_index.any | 176 |
| abstract_inverted_index.are | 32, 209 |
| abstract_inverted_index.but | 143, 164, 237 |
| abstract_inverted_index.for | 100, 160, 166, 175 |
| abstract_inverted_index.had | 171 |
| abstract_inverted_index.key | 248 |
| abstract_inverted_index.not | 172, 225 |
| abstract_inverted_index.the | 42, 154, 161, 167, 228 |
| abstract_inverted_index.two | 46 |
| abstract_inverted_index.was | 137 |
| abstract_inverted_index.=3/2 | 95 |
| abstract_inverted_index.=Ti, | 22 |
| abstract_inverted_index.M=V, | 80 |
| abstract_inverted_index.R=Me | 82 |
| abstract_inverted_index.This | 135 |
| abstract_inverted_index.also | 238 |
| abstract_inverted_index.been | 173 |
| abstract_inverted_index.both | 212 |
| abstract_inverted_index.from | 139, 146 |
| abstract_inverted_index.have | 93 |
| abstract_inverted_index.more | 144 |
| abstract_inverted_index.only | 226 |
| abstract_inverted_index.shed | 223 |
| abstract_inverted_index.sign | 155 |
| abstract_inverted_index.such | 47 |
| abstract_inverted_index.that | 113, 152 |
| abstract_inverted_index.this | 235 |
| abstract_inverted_index.thus | 63 |
| abstract_inverted_index.−1 | 122 |
| abstract_inverted_index.(zfs) | 112 |
| abstract_inverted_index.Their | 105 |
| abstract_inverted_index.These | 89 |
| abstract_inverted_index.X=Cl, | 81 |
| abstract_inverted_index.aryl) | 31 |
| abstract_inverted_index.donor | 245 |
| abstract_inverted_index.known | 174 |
| abstract_inverted_index.leads | 108 |
| abstract_inverted_index.light | 224 |
| abstract_inverted_index.trans | 6, 49, 56, 65, 177, 196, 203 |
| abstract_inverted_index.using | 211 |
| abstract_inverted_index.where | 79 |
| abstract_inverted_index.which | 62, 169 |
| abstract_inverted_index.(dmpe) | 59, 206 |
| abstract_inverted_index.ground | 96 |
| abstract_inverted_index.initio | 217 |
| abstract_inverted_index.modest | 115 |
| abstract_inverted_index.theory | 214 |
| abstract_inverted_index.‐[MX | 7, 66 |
| abstract_inverted_index.‐[VX | 178 |
| abstract_inverted_index.≈0.3 | 120 |
| abstract_inverted_index.(HFEPR) | 151 |
| abstract_inverted_index.(dmpe). | 88 |
| abstract_inverted_index.(tmeda) | 52, 85, 199 |
| abstract_inverted_index.R=alkyl | 29 |
| abstract_inverted_index.between | 241 |
| abstract_inverted_index.diamine | 162 |
| abstract_inverted_index.formula | 5 |
| abstract_inverted_index.general | 4 |
| abstract_inverted_index.quantum | 218 |
| abstract_inverted_index.results | 222 |
| abstract_inverted_index.states, | 97 |
| abstract_inverted_index.theory. | 220 |
| abstract_inverted_index.‐[VCl | 50, 57, 197, 204 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.chemical | 219 |
| abstract_inverted_index.complex, | 163 |
| abstract_inverted_index.expected | 99 |
| abstract_inverted_index.ligands, | 246 |
| abstract_inverted_index.negative | 159 |
| abstract_inverted_index.obtained | 210 |
| abstract_inverted_index.positive | 165 |
| abstract_inverted_index.relative | 124 |
| abstract_inverted_index.systems. | 191 |
| abstract_inverted_index.‐field | 149 |
| abstract_inverted_index.analogous | 126 |
| abstract_inverted_index.classical | 213 |
| abstract_inverted_index.complexes | 2, 92 |
| abstract_inverted_index.magnitude | 117 |
| abstract_inverted_index.parameter | 136 |
| abstract_inverted_index.represent | 64 |
| abstract_inverted_index.splitting | 111 |
| abstract_inverted_index.structure | 230 |
| abstract_inverted_index.chemistry. | 39, 252 |
| abstract_inverted_index.comparison | 249 |
| abstract_inverted_index.complexes, | 48 |
| abstract_inverted_index.complexes. | 134 |
| abstract_inverted_index.determined | 138, 153 |
| abstract_inverted_index.distortion | 107 |
| abstract_inverted_index.electronic | 43, 229 |
| abstract_inverted_index.octahedral | 101 |
| abstract_inverted_index.parameters | 194 |
| abstract_inverted_index.properties | 44 |
| abstract_inverted_index.tetragonal | 106 |
| abstract_inverted_index.cornerstone | 34 |
| abstract_inverted_index.differences | 240 |
| abstract_inverted_index.effectively | 145 |
| abstract_inverted_index.information | 170 |
| abstract_inverted_index.investigate | 41 |
| abstract_inverted_index.Coordination | 1 |
| abstract_inverted_index.conventional | 140 |
| abstract_inverted_index.coordination | 36, 251 |
| abstract_inverted_index.diphosphine, | 168 |
| abstract_inverted_index.environment, | 236 |
| abstract_inverted_index.zero‐field | 110 |
| abstract_inverted_index.spectroscopy, | 142 |
| abstract_inverted_index.ligand‐field | 193 |
| abstract_inverted_index.organometallic | 38 |
| abstract_inverted_index.high‐frequency | 147 |
| cited_by_percentile_year | |
| corresponding_author_ids | https://openalex.org/A5000558729 |
| countries_distinct_count | 2 |
| institutions_distinct_count | 12 |
| corresponding_institution_ids | https://openalex.org/I102101047 |
| citation_normalized_percentile.value | 0.11038754 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |