Electronic Structure of Sr3Fe2−xCoxO7−δ Studied by Photoemission and X-ray Absorption Spectroscopy Article Swipe
Rie Naito
,
Yuta Nakano
,
Mario Okawa
,
Hiroki Wadati
,
Ryouta Nakamura
,
J Tozawa
,
Mitsuru Akaki
,
H. Kuwahara
,
Takeharu Sugiyama
,
Eiji Ikenaga
,
Hiroshi Kumigashira
,
Enju Sakai
,
T. Saitoh
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.7566/jpscp.30.011073
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.7566/jpscp.30.011073
We have investigated the electronic structure of Sr 3 Fe 2-x Co x O 7-δ using photoemission and soft xray absorption spectroscopy (XAS).From the analysis on the O 1s, Fe 2p, and Co 2p core level photoemission spectra and the line-shape analysis on the Fe and Co L 2,3 edge XAS spectra, we concluded that the valence of Fe and Co are both ∼3.85+, the expected value.From the analysis of 2p-3d resonant photoemission spectra, we found that the electron density of states near the Fermi level has a dominant Fe 3d character and the Co 3d states are located below the Fe 3d states by ∼1 eV, in agreement with the smaller charge-transfer energy of Co 4+ than that of Fe 4+ .
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- article
- Language
- en
- Landing Page
- https://doi.org/10.7566/jpscp.30.011073
- https://journals.jps.jp/doi/pdf/10.7566/JPSCP.30.011073
- OA Status
- hybrid
- References
- 17
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3012288810
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https://openalex.org/W3012288810Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.7566/jpscp.30.011073Digital Object Identifier
- Title
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Electronic Structure of Sr3Fe2−xCoxO7−δ Studied by Photoemission and X-ray Absorption SpectroscopyWork title
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2020Year of publication
- Publication date
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2020-03-18Full publication date if available
- Authors
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Rie Naito, Yuta Nakano, Mario Okawa, Hiroki Wadati, Ryouta Nakamura, J Tozawa, Mitsuru Akaki, H. Kuwahara, Takeharu Sugiyama, Eiji Ikenaga, Hiroshi Kumigashira, Enju Sakai, T. SaitohList of authors in order
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https://doi.org/10.7566/jpscp.30.011073Publisher landing page
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https://journals.jps.jp/doi/pdf/10.7566/JPSCP.30.011073Direct link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://journals.jps.jp/doi/pdf/10.7566/JPSCP.30.011073Direct OA link when available
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X-ray crystallography, Materials science, Crystallography, Physics, Chemistry, Diffraction, OpticsTop concepts (fields/topics) attached by OpenAlex
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0Total citation count in OpenAlex
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