Elucidating Polyphosphate Anion Binding to Lanthanide Complexes Using EXAFS and Pulsed EPR Spectroscopy Article Swipe
Hannah K. Pyle
,
Martyna Judd
,
Anthony Barancewicz
,
Alexander J. Mayer
,
Nicholas J. Cox
,
Simon A. Kondrat
,
Stephen J. Butler
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/acs.inorgchem.4c03399
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1021/acs.inorgchem.4c03399
Reversible anion binding to lanthanide complexes in aqueous solution has emerged as an effective method for anion sensing. Through careful design of the organic ligand, luminescent lanthanide complexes capable of binding biologically relevant anions in a bidentate or monodentate manner can be realized. While single-crystal X-ray diffraction analyses and NMR spectroscopy have revealed the structural geometry of several host-guest complexes, the challenge remains in designing preorganized lanthanide receptors with enhanced anion selectivity for broader applications in diagnostics and bioimaging. To address this challenge, innovative and complementary methods to investigate host-anion binding geometry are becoming increasingly important. Herein, we demonstrate the combined use of Eu L3-edge extended X-ray absorption fine structure (EXAFS) and electron paramagnetic resonance (EPR) spectroscopy to elucidate the binding of nucleoside phosphates (ATP, ADP, and AMP) to a cationic lanthanide complex. We establish that ATP unequivocally binds the lanthanide center in a bidentate manner in water, while ADP adopts both bidentate and monodentate modes, and AMP binds in a monodentate manner. This interdisciplinary approach provides deeper insight into lanthanide host-guest chemistry in solution, laying the groundwork for designing emissive probes that undergo specific anion-induced structural changes and elicit desired optical responses upon binding.
Related Topics
Concepts
Chemistry
Polyphosphate
Lanthanide
Electron paramagnetic resonance
Extended X-ray absorption fine structure
Ion
Spectroscopy
Electron paramagnetic resonance spectroscopy
Inorganic chemistry
Competitive binding
Nuclear magnetic resonance spectroscopy
Crystallography
Absorption spectroscopy
Nuclear magnetic resonance
Stereochemistry
Organic chemistry
Phosphate
Biochemistry
Receptor
Quantum mechanics
Physics
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.inorgchem.4c03399
- OA Status
- hybrid
- Cited By
- 3
- References
- 32
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4403451072
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4403451072Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.inorgchem.4c03399Digital Object Identifier
- Title
-
Elucidating Polyphosphate Anion Binding to Lanthanide Complexes Using EXAFS and Pulsed EPR SpectroscopyWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-10-16Full publication date if available
- Authors
-
Hannah K. Pyle, Martyna Judd, Anthony Barancewicz, Alexander J. Mayer, Nicholas J. Cox, Simon A. Kondrat, Stephen J. ButlerList of authors in order
- Landing page
-
https://doi.org/10.1021/acs.inorgchem.4c03399Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
-
hybridOpen access status per OpenAlex
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https://doi.org/10.1021/acs.inorgchem.4c03399Direct OA link when available
- Concepts
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Chemistry, Polyphosphate, Lanthanide, Electron paramagnetic resonance, Extended X-ray absorption fine structure, Ion, Spectroscopy, Electron paramagnetic resonance spectroscopy, Inorganic chemistry, Competitive binding, Nuclear magnetic resonance spectroscopy, Crystallography, Absorption spectroscopy, Nuclear magnetic resonance, Stereochemistry, Organic chemistry, Phosphate, Biochemistry, Receptor, Quantum mechanics, PhysicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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3Total citation count in OpenAlex
- Citations by year (recent)
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2025: 3Per-year citation counts (last 5 years)
- References (count)
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32Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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