Enantiopure Chiral Crystals: A Powerful Tool for Absolute Asymmetric Synthesis Article Swipe
Jiacheng Li
,
Valérie Alezra
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/ajoc.202500267
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/ajoc.202500267
This review explores the use of enantiopure chiral crystals as powerful tools for absolute asymmetric synthesis, a field focused on generating enantiomerically enriched products from achiral precursors without chiral reagents or catalysts. We discuss various strategies, including solid‐state reactions (solid‐gas, solid‐grinding, and photochemical reactions) and solution‐based approaches utilizing chiral crystals as reagents, catalysts, or products. Key examples include the use of chiral crystals in Strecker reactions, photocycloadditions, and asymmetric catalysis. The review also highlights recent advancements in leveraging chiral conglomerates for spontaneous resolution and enantioenrichment. These methods demonstrate the potential for achieving high enantiomeric excesses and provide insights into the origin of homochirality on Earth.
Related Topics
Concepts
Enantiopure drug
Chemistry
Absolute configuration
Enantioselective synthesis
Absolute (philosophy)
Chirality (physics)
Nanotechnology
Organic chemistry
Chiral symmetry
Catalysis
Particle physics
Physics
Materials science
Epistemology
Quark
Philosophy
Nambu–Jona-Lasinio model
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/ajoc.202500267
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ajoc.202500267
- OA Status
- hybrid
- References
- 77
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4410812259
All OpenAlex metadata
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https://doi.org/10.1002/ajoc.202500267Digital Object Identifier
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Enantiopure Chiral Crystals: A Powerful Tool for Absolute Asymmetric SynthesisWork title
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articleOpenAlex work type
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enPrimary language
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2025Year of publication
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2025-05-28Full publication date if available
- Authors
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Jiacheng Li, Valérie AlezraList of authors in order
- Landing page
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https://doi.org/10.1002/ajoc.202500267Publisher landing page
- PDF URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ajoc.202500267Direct link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ajoc.202500267Direct OA link when available
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Enantiopure drug, Chemistry, Absolute configuration, Enantioselective synthesis, Absolute (philosophy), Chirality (physics), Nanotechnology, Organic chemistry, Chiral symmetry, Catalysis, Particle physics, Physics, Materials science, Epistemology, Quark, Philosophy, Nambu–Jona-Lasinio modelTop concepts (fields/topics) attached by OpenAlex
- Cited by
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0Total citation count in OpenAlex
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