Experimental investigation of trace element partitioning between amphibole and alkali basaltic melt: Toward a more general partitioning model with implications for amphibole fractionation at deep crustal levels Article Swipe
Barbara Bonechi
,
Alessandro Fabbrizio
,
Cristina Perinelli
,
Mario Gaeta
,
Maurizio Petrelli
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.2138/am-2022-8536
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.2138/am-2022-8536
Time-series experiments were carried out in a piston-cylinder apparatus at 0.8 GPa and 1030–1080 °C using a hydrous K-basalt melt as the starting material to determine the element partition coefficients between amphibole and silicate glass. Major, minor, and trace element compositions of amphibole and glass were determined with a combination of electron microprobe and laser ablation inductively coupled plasma mass spectrometry. Results show that the main mineral phase is calcic amphibole, and the coexisting glass compositions range from basaltic trachyandesite to andesite. We estimated the ideal radius, the maximum partition coefficient and the apparent Young’s modulus of the A, M1-M2-M3, and M4-M4′ sites of amphibole. The influence of melt and amphibole composition, temperature, and pressure on the partition coefficients between amphiboles and glasses has also been investigated by comparing our data with a literature data set spanning a wide range of pressures (0.6–2.5 GPa), temperatures (780–1100 °C), and compositions (from basanite to rhyolite). Finally, we modeled a deep fractional crystallization process using the amphibole-melt partition coefficients determined in this study, observing that significant amounts of amphibole crystallization (>30 wt%) well reproduce the composition of an andesitic melt similar to that of the calc-alkaline volcanic products found in Parete and Castelvolturno boreholes (NW of Campi Flegrei, Italy).
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.2138/am-2022-8536
- https://pubs.geoscienceworld.org/msa/ammin/article-pdf/108/9/1678/5943809/am-2022-8536.pdf
- OA Status
- bronze
- Cited By
- 4
- References
- 99
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4306897111
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- OpenAlex ID
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https://openalex.org/W4306897111Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.2138/am-2022-8536Digital Object Identifier
- Title
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Experimental investigation of trace element partitioning between amphibole and alkali basaltic melt: Toward a more general partitioning model with implications for amphibole fractionation at deep crustal levelsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2022Year of publication
- Publication date
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2022-10-20Full publication date if available
- Authors
-
Barbara Bonechi, Alessandro Fabbrizio, Cristina Perinelli, Mario Gaeta, Maurizio PetrelliList of authors in order
- Landing page
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https://doi.org/10.2138/am-2022-8536Publisher landing page
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https://pubs.geoscienceworld.org/msa/ammin/article-pdf/108/9/1678/5943809/am-2022-8536.pdfDirect link to full text PDF
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YesWhether a free full text is available
- OA status
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bronzeOpen access status per OpenAlex
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https://pubs.geoscienceworld.org/msa/ammin/article-pdf/108/9/1678/5943809/am-2022-8536.pdfDirect OA link when available
- Concepts
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Amphibole, Andesite, Geology, Partition coefficient, Electron microprobe, Trace element, Mineralogy, Analytical Chemistry (journal), Basalt, Geochemistry, Volcanic rock, Chemistry, Volcano, Quartz, Chromatography, PaleontologyTop concepts (fields/topics) attached by OpenAlex
- Cited by
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4Total citation count in OpenAlex
- Citations by year (recent)
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2025: 2, 2024: 2Per-year citation counts (last 5 years)
- References (count)
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99Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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