Face-controlled chirality induction in octahedral thiacalixarene-based porous coordination cages Article Swipe

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Chirality (physics) Octahedron Supramolecular chemistry Crystallography Enantiomer Molecule Porosity Materials science Adsorption Chemistry Crystal structure Stereochemistry Organic chemistry Quark Quantum mechanics Chiral symmetry breaking Nambu–Jona-Lasinio model Physics Composite material

Ivan V. Khariushin , Alexander S. Ovsyannikov , Stéphane A. Baudron , Jas S. Ward , Anniina Kiesilä , Kari Rissanen , Elina Kalenius , Matthieu Chessé , Beata Nowicka , S. Е. Solovieva , И. С. Антипин , V. Bulach , Sylvie Ferlay ·

YOU? · · 2024 · Open Access · · DOI: https://doi.org/10.1039/d4nr03622k · OA: W4405190494

Two pairs of enantiomers were obtained via self-assembly of sulfonylcalix[4]arene tetranuclear M( ii ) clusters (M = Co or Ni) with enantiomerically enriched linkers based on tris(dipyrrinato)cobalt( iii ) complexes, leading to nanosized porous cages.