FePc Adsorption on the Moiré Superstructure of Graphene Intercalated with a Cobalt Layer Article Swipe
Giulia Avvisati
,
Simone Lisi
,
Pierluigi Gargiani
,
Ada Della Pia
,
Oreste De Luca
,
D. Pacilè
,
Cláudia Cardoso
,
Daniele Varsano
,
Deborah Prezzi
,
Andrea Ferretti
,
Maria Grazia Betti
·
YOU?
·
· 2016
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpcc.6b09875
YOU?
·
· 2016
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpcc.6b09875
The moire superstructure of graphene grown on metals can drive the assembly of molecular architectures, such as iron phthalocyanine (FePc) molecules, allowing for the production of artificial molecular configurations. A detailed analysis of the Gr/Co interaction upon intercalation (including a modeling of the resulting moire pattern) is performed here by density functional theory, which provides an accurate description of the template as a function of the corrugation parameters. The theoretical results are a preliminary step to describe the interaction process of the FePc molecules adsorption on the Gr/Co system. Core level photoemission and absorption spectroscopies have been employed to control the preferential adsorption regions of the FePc on the graphene moire superstructure and the interaction of the central Fe ion with the underlying Co. Our results show that, upon molecular adsorption, the distance of C atoms from the Co template mainly drives the strength of the molecules-substrate interaction, thereby allowing for locally different electronic properties within the corrugated interface.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.jpcc.6b09875
- OA Status
- green
- Cited By
- 26
- References
- 44
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2562240536
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2562240536Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.jpcc.6b09875Digital Object Identifier
- Title
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FePc Adsorption on the Moiré Superstructure of Graphene Intercalated with a Cobalt LayerWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2016Year of publication
- Publication date
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2016-12-20Full publication date if available
- Authors
-
Giulia Avvisati, Simone Lisi, Pierluigi Gargiani, Ada Della Pia, Oreste De Luca, D. Pacilè, Cláudia Cardoso, Daniele Varsano, Deborah Prezzi, Andrea Ferretti, Maria Grazia BettiList of authors in order
- Landing page
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https://doi.org/10.1021/acs.jpcc.6b09875Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
- OA URL
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https://arxiv.org/pdf/1805.11513Direct OA link when available
- Concepts
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Superstructure, Graphene, Cobalt, Materials science, Layer (electronics), Moiré pattern, Adsorption, Nanotechnology, Chemistry, Metallurgy, Structural engineering, Optics, Physics, Organic chemistry, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
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26Total citation count in OpenAlex
- Citations by year (recent)
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2023: 2, 2022: 1, 2021: 4, 2020: 4, 2019: 5Per-year citation counts (last 5 years)
- References (count)
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44Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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