Formation and characterization of embedded Fe3Si binary structures in Si Article Swipe
Wickramaarachchige J. Lakshantha
,
Floyd D. McDaniel
,
Bibhudutta Rout
·
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.1063/1.5091541
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.1063/1.5091541
Chemical and electronic properties of ion beam synthesized Fe-Si binary structures are studied using X-ray photoelectron spectroscopy binding energy analysis. Ferromagnetic Fe-Si (Fe3Si) binary structure formation is enhanced in the ion-beam synthesis process by applying an in situ external magnetic field parallel to the Si substrate during the Fe implantation. Core-level analysis shows features corresponding to chemical environments of different Fe-Si phases. Fe 2p3/2 and Fe 3s peaks were analyzed, considering peak position, symmetry, and splitting. The ferromagnetic Fe3Si phase shows a highly asymmetric 2p3/2 peak at 706.6 eV and peak splitting in the 3s peak due to the exchange interaction with unfilled 3d electrons in the valance band. In contrast, the Si core-level did not show any significant features leading to the identification of Fe-Si binary compounds. The Si 2p peak showed a constant 0.2 eV peak shift toward the high-energy side compared to the elemental Si. Further valance band spectra reveal distinct features to help identify the Fe3Si phase. In general, core and valance band features of Fe-Si binary compounds provided definitive information about Fe3Si phase identification and its electronic structure with direct evidence of the exchange interaction, which occurs between core levels, valance band, and the unfilled 3d shell.
Related Topics
Concepts
X-ray photoelectron spectroscopy
Ferromagnetism
Electronic structure
Materials science
Binding energy
Band gap
Phase (matter)
Substrate (aquarium)
Exchange interaction
Electronic band structure
Atomic physics
Condensed matter physics
Chemistry
Computational chemistry
Nuclear magnetic resonance
Optoelectronics
Physics
Oceanography
Geology
Organic chemistry
Metadata
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- article
- Language
- en
- Landing Page
- https://doi.org/10.1063/1.5091541
- OA Status
- gold
- Cited By
- 5
- References
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- Related Works
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All OpenAlex metadata
Raw OpenAlex JSON
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https://doi.org/10.1063/1.5091541Digital Object Identifier
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Formation and characterization of embedded Fe3Si binary structures in SiWork title
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articleOpenAlex work type
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enPrimary language
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2019Year of publication
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2019-05-16Full publication date if available
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Wickramaarachchige J. Lakshantha, Floyd D. McDaniel, Bibhudutta RoutList of authors in order
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https://doi.org/10.1063/1.5091541Publisher landing page
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://digital.library.unt.edu/ark:/67531/metadc1944115/m2/1/high_res_d/1.5091541.pdfDirect OA link when available
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X-ray photoelectron spectroscopy, Ferromagnetism, Electronic structure, Materials science, Binding energy, Band gap, Phase (matter), Substrate (aquarium), Exchange interaction, Electronic band structure, Atomic physics, Condensed matter physics, Chemistry, Computational chemistry, Nuclear magnetic resonance, Optoelectronics, Physics, Oceanography, Geology, Organic chemistryTop concepts (fields/topics) attached by OpenAlex
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5Total citation count in OpenAlex
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2022: 1, 2021: 2, 2020: 1, 2019: 1Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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| referenced_works | https://openalex.org/W2067622988, https://openalex.org/W2017453082, https://openalex.org/W2891477920, https://openalex.org/W2766079728, https://openalex.org/W2069365890, https://openalex.org/W1624098932, https://openalex.org/W1968120472, https://openalex.org/W1967273204, https://openalex.org/W1973006222, https://openalex.org/W2028687073, https://openalex.org/W1983542408, https://openalex.org/W1508921712, https://openalex.org/W2094244728, https://openalex.org/W2009967805, https://openalex.org/W1991308161, https://openalex.org/W2252100697, https://openalex.org/W2054155631, https://openalex.org/W1997085100, https://openalex.org/W1986125650, https://openalex.org/W2084345439, https://openalex.org/W2022995399, https://openalex.org/W1989867944, https://openalex.org/W1996875323, https://openalex.org/W2077980148, https://openalex.org/W1993334165, https://openalex.org/W4250154895, https://openalex.org/W2023488790, https://openalex.org/W2053667303, https://openalex.org/W2047491557, https://openalex.org/W2017809842, https://openalex.org/W2024172140, https://openalex.org/W1053614910, https://openalex.org/W1998260542, https://openalex.org/W2085516809, https://openalex.org/W2016076883, https://openalex.org/W1971653886, https://openalex.org/W1649884554, https://openalex.org/W2041201148, https://openalex.org/W2070848917 |
| referenced_works_count | 39 |
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| abstract_inverted_index.3d | 103, 200 |
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| abstract_inverted_index.Si | 44, 112, 129 |
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| corresponding_author_ids | https://openalex.org/A5087626448 |
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| institutions_distinct_count | 3 |
| corresponding_institution_ids | https://openalex.org/I123534392 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/7 |
| sustainable_development_goals[0].score | 0.8799999952316284 |
| sustainable_development_goals[0].display_name | Affordable and clean energy |
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| citation_normalized_percentile.is_in_top_10_percent | False |