Heavy halogen impact on Raman water bands at high pressure: Implications for salinity estimations in fluid inclusions Article Swipe
Tobias Grützner
,
Hélène Bureau
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1016/j.chemgeo.2024.122065
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1016/j.chemgeo.2024.122065
We present a new experimental dataset on the impact of the heavy halogens chlorine, bromine and iodine on the Raman water bands concerning pressure and their concentration at room temperature. These experiments were conducted at ambient temperature, with variations in halogen concentration and pressure ranging from 0 to 1.4 GPa. The strength of the Raman water band shift change increases with the ionic size from chlorine, over bromine, to iodine. Our experiments further demonstrate that increased pressure diminishes the impact of the halogen shift change to a varying extent for each of the three halogens. This finding can have significant implications for the salinity calculation of fluid inclusions in minerals such as quartz or olivine. Particularly in the low salinity range, the concentration can be markedly underestimated if the pressure effect is neglected. For experiments in diamond anvil cells involving halogens dissolved in water, the change in Raman water band shifts can serve either as a new tool to monitor pressure, or to monitor the salinity.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.chemgeo.2024.122065
- OA Status
- hybrid
- Cited By
- 1
- References
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All OpenAlex metadata
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https://doi.org/10.1016/j.chemgeo.2024.122065Digital Object Identifier
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Heavy halogen impact on Raman water bands at high pressure: Implications for salinity estimations in fluid inclusionsWork title
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articleOpenAlex work type
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enPrimary language
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2024Year of publication
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2024-03-26Full publication date if available
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Tobias Grützner, Hélène BureauList of authors in order
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https://doi.org/10.1016/j.chemgeo.2024.122065Publisher landing page
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hybridOpen access status per OpenAlex
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https://doi.org/10.1016/j.chemgeo.2024.122065Direct OA link when available
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Halogen, Raman spectroscopy, Bromine, Salinity, Chlorine, Quartz, Geology, Iodine, Mineralogy, Analytical Chemistry (journal), Chemistry, Environmental chemistry, Oceanography, Optics, Physics, Organic chemistry, Alkyl, PaleontologyTop concepts (fields/topics) attached by OpenAlex
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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