High-Pressure Phase Transition in 3-D Printed Nanolamellar High-Entropy Alloy: Imaging and Simulation Insights Article Swipe
YOU?
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· 2024
· Open Access
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· DOI: https://doi.org/10.21203/rs.3.rs-4343886/v1
We report on the high-resolution imaging and molecular dynamics simulations of a 3D-printed eutectic high-entropy alloy (EHEA) Ni40Co20Fe10Cr10Al18W2 consisting of nanolamellar BCC and FCC phases. The direct lattice imaging of 3D-printed samples shows the Kurdjumov-Sachs (K-S) orientation relation {111} FCC parallel to {110} BCC planes in the dual-phase lamellae. Unlike traditional iron and steels, this alloy shows an irreversible BCC-to-FCC phase transformation under high pressures. The nanolamellar morphology is maintained after pressure cycling to 30 GPa, and nano-diffraction studies show both layers to be in the FCC phase. The chemical compositions of the dual-phase lamellae after pressure recovery remain unchanged, suggesting a diffusion-less BCC-FCC transformation in this EHEA. The lattice imaging of the pressure-recovered sample does not show any specific orientation relation between the two resulting FCC phases, indicating that many grain orientations are produced during the BCC-FCC phase transformation. Molecular dynamics simulations on phase transformation in a nanolamellar BCC/FCC in K-S orientation show that phase transformation from BCC to FCC is completed under high pressures, and the FCC phase is retained on decompression aided by the stable interfaces. Our work elucidates the irreversible phase transformation, providing an understanding of the orientation relationships in 3-D printed EHEA under high pressures.
Related Topics
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.21203/rs.3.rs-4343886/v1
- https://www.researchsquare.com/article/rs-4343886/latest.pdf
- OA Status
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- References
- 42
- Related Works
- 10
- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W4396855175Canonical identifier for this work in OpenAlex
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https://doi.org/10.21203/rs.3.rs-4343886/v1Digital Object Identifier
- Title
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High-Pressure Phase Transition in 3-D Printed Nanolamellar High-Entropy Alloy: Imaging and Simulation InsightsWork title
- Type
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preprintOpenAlex work type
- Language
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enPrimary language
- Publication year
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2024Year of publication
- Publication date
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2024-05-13Full publication date if available
- Authors
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Yogesh K. Vohra, Andrew D. Pope, Wen Chen, Hangman Chen, Penghui Cao, Khachatur V. Manukyan, Maksym Zhukovskyi, Armenuhi YeghishyanList of authors in order
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https://doi.org/10.21203/rs.3.rs-4343886/v1Publisher landing page
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https://www.researchsquare.com/article/rs-4343886/latest.pdfDirect link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://www.researchsquare.com/article/rs-4343886/latest.pdfDirect OA link when available
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Alloy, High pressure, Materials science, Phase transition, High entropy alloys, Entropy (arrow of time), Condensed matter physics, Statistical physics, Thermodynamics, Metallurgy, PhysicsTop concepts (fields/topics) attached by OpenAlex
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0Total citation count in OpenAlex
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42Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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