Highly Crystalline and Semiconducting Imine‐Based Two‐Dimensional Polymers Enabled by Interfacial Synthesis Article Swipe
YOU?
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· 2020
· Open Access
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· DOI: https://doi.org/10.1002/anie.201915217
Single‐layer and multi‐layer 2D polyimine films have been achieved through interfacial synthesis methods. However, it remains a great challenge to achieve the maximum degree of crystallinity in the 2D polyimines, which largely limits the long‐range transport properties. Here we employ a surfactant‐monolayer‐assisted interfacial synthesis (SMAIS) method for the successful preparation of porphyrin and triazine containing polyimine‐based 2D polymer (PI‐2DP) films with square and hexagonal lattices, respectively. The synthetic PI‐2DP films are featured with polycrystalline multilayers with tunable thickness from 6 to 200 nm and large crystalline domains (100–150 nm in size). Intrigued by high crystallinity and the presence of electroactive porphyrin moieties, the optoelectronic properties of PI‐2DP are investigated by time‐resolved terahertz spectroscopy. Typically, the porphyrin‐based PI‐2DP 1 film exhibits a p‐type semiconductor behavior with a band gap of 1.38 eV and hole mobility as high as 0.01 cm 2 V −1 s −1 , superior to the previously reported polyimine based materials.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/anie.201915217
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201915217
- OA Status
- hybrid
- Cited By
- 156
- References
- 50
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2999992026
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2999992026Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/anie.201915217Digital Object Identifier
- Title
-
Highly Crystalline and Semiconducting Imine‐Based Two‐Dimensional Polymers Enabled by Interfacial SynthesisWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2020Year of publication
- Publication date
-
2020-01-15Full publication date if available
- Authors
-
Hafeesudeen Sahabudeen, Haoyuan Qi, Marco Ballabio, Miroslav Položij, Selina Olthof, Rishi Shivhare, Yu Jing, Sang-Wook Park, Kejun Liu, Tao Zhang, Ji Ma, Bernd Rellinghaus, Stefan C. B. Mannsfeld, Thomas Heine, Mischa Bonn, Enrique Cánovas, Zhikun Zheng, Ute Kaiser, Renhao Dong⧫, Xinliang FengList of authors in order
- Landing page
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https://doi.org/10.1002/anie.201915217Publisher landing page
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201915217Direct link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
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hybridOpen access status per OpenAlex
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201915217Direct OA link when available
- Concepts
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Imine, Materials science, Polymer, Chemical engineering, Nanotechnology, Polymer science, Organic chemistry, Chemistry, Composite material, Engineering, CatalysisTop concepts (fields/topics) attached by OpenAlex
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156Total citation count in OpenAlex
- Citations by year (recent)
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2025: 22, 2024: 34, 2023: 21, 2022: 25, 2021: 34Per-year citation counts (last 5 years)
- References (count)
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50Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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| primary_location.raw_source_name | Angewandte Chemie International Edition |
| primary_location.landing_page_url | https://doi.org/10.1002/anie.201915217 |
| publication_date | 2020-01-15 |
| publication_year | 2020 |
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| corresponding_author_ids | https://openalex.org/A5067286202, https://openalex.org/A5017684207, https://openalex.org/A5056113736, https://openalex.org/A5100659481 |
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