Highly Selective Capture of CO2 by Ether-Functionalized Pyridinium Ionic Liquids with Low Viscosity Article Swipe
YOU?
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· 2015
· Open Access
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· DOI: https://doi.org/10.1021/acs.energyfuels.5b01274
\n\tIn this work, three kinds of ether-functionalized pyridinium-based ILs [EnPy][NTf2] with low viscosity were designed and synthesized and used for highly selective separation of CO2 from CH4. It was found that the ether groups play an important role on physicochemical properties and CO2/CH4 selectivity in these three ILs. Compared with the nonfunctionalized analogues [CmPy][NTf2], the viscosities of [E(n)PA [NTf2] are lower and obviously decrease with the increasing number of ether oxygen atoms. The presence of ether groups on the cation has weak impacts on CO2 solubility of the ILs, but it contributes to a much lower CH4 solubility, which leads to the great increase of CO2/CH4 selectivity using [E(n)PA][NTf2]. Moreover, CO2/CH4 selectivity in all investigated ILs greatly decreases with the increasing temperature due to the weaker temperature dependence of CH4 solubility. In addition, the thermodynamic properties including the Gibbs free energy, enthalpy, and entropy of CO2 and CH4 in these ILs were also obtained, and the CO2 and CH4 dissolution mechanisms were further analyzed. The results demonstrated that the gas-IL interaction plays a dominate role in CH4 solubility in the investigated ILs, but CO2 dissolution in ILs is determined by both the IL-gas interaction and free volume of ILs. This work will offer new insights into designing more competitive ILs for selective separation of CO2 from CH4.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.energyfuels.5b01274
- OA Status
- green
- Cited By
- 94
- References
- 45
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2344080047
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2344080047Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1021/acs.energyfuels.5b01274Digital Object Identifier
- Title
-
Highly Selective Capture of CO2 by Ether-Functionalized Pyridinium Ionic Liquids with Low ViscosityWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2015Year of publication
- Publication date
-
2015-08-26Full publication date if available
- Authors
-
Shaojuan Zeng, Jian Wang, Lu Bai, Binqi Wang, Hongshuai Gao, Dawei Shang, Xiangping Zhang, Suojiang ZhangList of authors in order
- Landing page
-
https://doi.org/10.1021/acs.energyfuels.5b01274Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
-
greenOpen access status per OpenAlex
- OA URL
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https://ir.ipe.ac.cn/handle/122111/19750Direct OA link when available
- Concepts
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Solubility, Ionic liquid, Selectivity, Chemistry, Dissolution, Gibbs free energy, Ether, Pyridinium, Enthalpy, Viscosity, Organic chemistry, Chemical engineering, Thermodynamics, Catalysis, Engineering, PhysicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
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94Total citation count in OpenAlex
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2025: 6, 2024: 8, 2023: 13, 2022: 14, 2021: 9Per-year citation counts (last 5 years)
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45Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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