High‐Voltage Performance of Ni‐Rich NCA Cathodes: Linking Operating Voltage with Cathode Degradation Article Swipe
Lamuel David
,
Debasish Mohanty
,
Linxiao Geng
,
Rose E. Ruther
,
Athena S. Sefat
,
Ercan Cakmak
,
Gabriel M. Veith
,
Harry M. Meyer
,
Hsin Wang
,
David L. Wood
·
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.1002/celc.201901338
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.1002/celc.201901338
High‐voltage Ni‐rich cathodes have been studied as a possible way to achieve high energy density in Li‐ion batteries. However, capacity fade due to structural changes at high voltages has limited their applications. This study identifies 4.5 V (vs. graphite) as the optimum upper cutoff voltage (UCV) for a Ni‐rich NCA cathode [LiNi 0.8 Co 0.15 Al 0.05 O 2 ]. At this UCV, NCA delivers a 12 % increase in reversible capacity (when discharged to 2.5 V) and retains 92 % of its initial capacity after 100 cycles at 1C/‐1C cycling when compared to 4.2 V as UCV. By increasing UCV to 4.7 V, the discharge capacity can be raised to >200 mAh/g. However, the rate of capacity fade is greater when compared to 4.5 V as UCV. This increased rate of capacity fade, at higher UCV, is related to irreversible lattice contractions that leads to structural rearrangement at charged states during high‐voltage cycling. Our results show a change in transition metal oxidation states and an onset of structural ordering occurs when the UCV is 4.7 V.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/celc.201901338
- OA Status
- green
- Cited By
- 21
- References
- 35
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2968321571
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2968321571Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/celc.201901338Digital Object Identifier
- Title
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High‐Voltage Performance of Ni‐Rich NCA Cathodes: Linking Operating Voltage with Cathode DegradationWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2019Year of publication
- Publication date
-
2019-08-16Full publication date if available
- Authors
-
Lamuel David, Debasish Mohanty, Linxiao Geng, Rose E. Ruther, Athena S. Sefat, Ercan Cakmak, Gabriel M. Veith, Harry M. Meyer, Hsin Wang, David L. WoodList of authors in order
- Landing page
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https://doi.org/10.1002/celc.201901338Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
- OA URL
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https://www.osti.gov/biblio/1558680Direct OA link when available
- Concepts
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Cathode, Voltage, Fade, Degradation (telecommunications), Materials science, Chemistry, Electrical engineering, Physics, Engineering, AcousticsTop concepts (fields/topics) attached by OpenAlex
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21Total citation count in OpenAlex
- Citations by year (recent)
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2025: 4, 2024: 3, 2023: 1, 2022: 8, 2021: 1Per-year citation counts (last 5 years)
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35Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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