Homologous Ladder Cyclohexasilanes Article Swipe

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Rebekka S. Klausen , Fan Fang , Andrew Molino , Kelsie E. Wentz , Carlton P. Folster , Jessica Williams , Maxime A. Siegler ·

YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.1002/anie.202506054

We report the synthesis of five new examples of ladder cyclohexasilanes, possessing up to three consecutive fused rings and differing in relative ring fusion configuration and side chain structure. By coupling a 1,4‐dipotassiooligosilyl dianion to a cyclohexasilane, we obtained bi‐ and tricyclic ladder cyclohexasilanes. Combined experimental and theoretical studies suggested that annulation could favor the cis configuration under kinetic control, while the trans configuration predominates under thermodynamic control. Computational studies show that with each additional ring in the trans ‐diastereomeric series, the predicted onset of light absorption shifts to longer wavelengths.

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Chemistry

Crystallography

Organic Chemistry

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Diastereomer Ring (chemistry) Chemistry Stereochemistry Selectivity Crystallography Organic chemistry Catalysis

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Type: article
Language: en
Landing Page: https://doi.org/10.1002/anie.202506054
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DOI: https://doi.org/10.1002/anie.202506054

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Title: Homologous Ladder Cyclohexasilanes

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Publication year: 2025

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Publication date: 2025-06-28

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Authors: Rebekka S. Klausen, Fan Fang, Andrew Molino, Kelsie E. Wentz, Carlton P. Folster, Jessica Williams, Maxime A. Siegler

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Landing page: https://doi.org/10.1002/anie.202506054

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Concepts: Diastereomer, Ring (chemistry), Chemistry, Stereochemistry, Selectivity, Crystallography, Organic chemistry, Catalysis

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Cited by: 2

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abstract_inverted_index.we	38
abstract_inverted_index.and	19, 26, 41, 47
abstract_inverted_index.cis	56
abstract_inverted_index.new	7
abstract_inverted_index.the	3, 55, 62, 78, 82
abstract_inverted_index.each	74
abstract_inverted_index.five	6
abstract_inverted_index.ring	23, 76
abstract_inverted_index.show	71
abstract_inverted_index.side	27
abstract_inverted_index.that	51, 72
abstract_inverted_index.with	73
abstract_inverted_index.bi‐	40
abstract_inverted_index.chain	28
abstract_inverted_index.could	53
abstract_inverted_index.favor	54
abstract_inverted_index.fused	17
abstract_inverted_index.light	86
abstract_inverted_index.onset	84
abstract_inverted_index.rings	18
abstract_inverted_index.three	15
abstract_inverted_index.trans	63, 79
abstract_inverted_index.under	58, 66
abstract_inverted_index.while	61
abstract_inverted_index.fusion	24
abstract_inverted_index.ladder	10, 43
abstract_inverted_index.longer	90
abstract_inverted_index.report	2
abstract_inverted_index.shifts	88
abstract_inverted_index.dianion	34
abstract_inverted_index.kinetic	59
abstract_inverted_index.series,	81
abstract_inverted_index.studies	49, 70
abstract_inverted_index.Abstract	0
abstract_inverted_index.Combined	45
abstract_inverted_index.control,	60
abstract_inverted_index.control.	68
abstract_inverted_index.coupling	31
abstract_inverted_index.examples	8
abstract_inverted_index.obtained	39
abstract_inverted_index.relative	22
abstract_inverted_index.differing	20
abstract_inverted_index.predicted	83
abstract_inverted_index.suggested	50
abstract_inverted_index.synthesis	4
abstract_inverted_index.tricyclic	42
abstract_inverted_index.absorption	87
abstract_inverted_index.additional	75
abstract_inverted_index.annulation	52
abstract_inverted_index.possessing	12
abstract_inverted_index.structure.	29
abstract_inverted_index.consecutive	16
abstract_inverted_index.theoretical	48
abstract_inverted_index.experimental	46
abstract_inverted_index.predominates	65
abstract_inverted_index.wavelengths.	91
abstract_inverted_index.Computational	69
abstract_inverted_index.configuration	25, 57, 64
abstract_inverted_index.thermodynamic	67
abstract_inverted_index.cyclohexasilane,	37
abstract_inverted_index.cyclohexasilanes,	11
abstract_inverted_index.cyclohexasilanes.	44
abstract_inverted_index.‐diastereomeric	80
abstract_inverted_index.1,4‐dipotassiooligosilyl	33
cited_by_percentile_year.max	97
cited_by_percentile_year.min	95
countries_distinct_count	1
institutions_distinct_count	7
citation_normalized_percentile.value	0.91053556
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	True