Host–Guest Encapsulation of RIBO with TSC4X: Synthesis, Characterization, and Its Application by Physicochemical and Computational Investigations Article Swipe
Biswajit Ghosh
,
Niloy Roy
,
Saikat Mandal
,
Salim Ali
,
Pranish Bomzan
,
Debadrita Roy
,
Md Salman Haydar
,
Vikas Kumar Dakua
,
Anupam Upadhyay
,
Debabrata Biswas
,
Kausik Kumar Paul
,
Mahendra Nath Roy
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1021/acsomega.2c07396
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1021/acsomega.2c07396
In our present work, we synthesized a new encapsulated complex denoted as RIBO-TSC4X, which was derived from an important vitamin riboflavin (RIBO) and p-sulfonatothiacalix[4]arene(TSC4X). The synthesized complex RIBO-TSC4X was then characterized by utilizing several spectroscopic techniques such as 1H-NMR, FT-IR, PXRD, SEM, and TGA. Job's plot has been employed to show the encapsulation of RIBO (guest) with TSC4X (host) having a 1:1 molar ratio. The molecular association constant of the complex entity (RIBO-TSC4X) was found to be 3116.29 ± 0.17 M-1, suggesting the formation of a stable complex. The augment in aqueous solubility of the RIBO-TSC4X complex compared to pure RIBO was investigated by UV-vis spectroscopy, and it was viewed that the newly synthesized complex has almost 30 times enhanced solubility over pure RIBO. The enhancement of thermal stability upto 440 °C for the RIBO-TSC4X complex was examined by TG analysis. This research also forecasts RIBO's release behavior in the presence of CT-DNA, and at the same time, BSA binding study was also carried out. The synthesized RIBO-TSC4X complex exhibited comparatively better free radical scavenging activity, thereby minimizing oxidative injury of the cell as evident from a series of antioxidant and anti-lipid peroxidation assay. Furthermore, the RIBO-TSC4X complex showed peroxidase-like biomimetic activity, which is very useful for several enzyme catalyst reactions.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsomega.2c07396
- OA Status
- gold
- Cited By
- 10
- References
- 66
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4319347993
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4319347993Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsomega.2c07396Digital Object Identifier
- Title
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Host–Guest Encapsulation of RIBO with TSC4X: Synthesis, Characterization, and Its Application by Physicochemical and Computational InvestigationsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-02-07Full publication date if available
- Authors
-
Biswajit Ghosh, Niloy Roy, Saikat Mandal, Salim Ali, Pranish Bomzan, Debadrita Roy, Md Salman Haydar, Vikas Kumar Dakua, Anupam Upadhyay, Debabrata Biswas, Kausik Kumar Paul, Mahendra Nath RoyList of authors in order
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https://doi.org/10.1021/acsomega.2c07396Publisher landing page
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
- OA URL
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https://doi.org/10.1021/acsomega.2c07396Direct OA link when available
- Concepts
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Chemistry, Solubility, Aqueous solution, Antioxidant, Complex formation, Lipid peroxidation, Organic chemistry, Inorganic chemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
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10Total citation count in OpenAlex
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2025: 3, 2024: 4, 2023: 3Per-year citation counts (last 5 years)
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66Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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