Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis Article Swipe

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Acylation Chemistry Stereocenter Intramolecular force Oxime Nickel Catalysis Hydrogen atom Migratory insertion Stereochemistry Medicinal chemistry Combinatorial chemistry Organic chemistry Enantioselective synthesis Alkyl

Rui Wang , Chuan Wang ·

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YOU? · · 2023 · Open Access · · DOI: https://doi.org/10.1039/d3sc01945d · OA: W4377239298

By merging nickel-mediated aza-Heck cyclization and HAT-photo-promoted acyl C–H activation, an unprecedented highly enantioselective imino-acylation of oxime ester-tethered alkenes with aldehydes as the acyl source has been developed.

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