Impact of Chlorine on the Internal Transition Rates and Excited States of the Thermally Delayed Activated Fluorescence Molecule 3CzClIPN Article Swipe
Martin Streiter
,
Tillmann G. Fischer
,
Christian Wiebeler
,
Sebastian Reichert
,
Jörn Langenickel
,
Kirsten Zeitler
,
Carsten Deibel
·
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpcc.0c03341
YOU?
·
· 2020
· Open Access
·
· DOI: https://doi.org/10.1021/acs.jpcc.0c03341
We analyze internal transition rates and the singlet-triplet energy gap of the thermally activated delayed fluorescence (TADF) molecule 3CzClIPN, which recently was introduced as an efficient photocatalyst. Distribution and origin of the non-monoexponential decays, which are commonly observed in TADF films, are revealed by analysis of transient fluorescence with an inverse Laplace transform. A numerically robust global rate fit routine, which extracts all relevant TADF parameters by modeling the complete set of data, is introduced. To compare and verify the results, all methods are also applied to the well-known 4CzIPN. The influence of the molecular matrix is discussed by embedding low concentrations of TADF molecules in polystyrene films. Finally, quantum chemical calculations are compared to the experimental results to demonstrate that the chlorine atom increases the charge transfer character of the relevant states, resulting in a reduction of the singlet-triplet energy gap.
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.jpcc.0c03341
- OA Status
- green
- Cited By
- 9
- References
- 56
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3037740811
All OpenAlex metadata
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https://openalex.org/W3037740811Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.jpcc.0c03341Digital Object Identifier
- Title
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Impact of Chlorine on the Internal Transition Rates and Excited States of the Thermally Delayed Activated Fluorescence Molecule 3CzClIPNWork title
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articleOpenAlex work type
- Language
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enPrimary language
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2020Year of publication
- Publication date
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2020-06-23Full publication date if available
- Authors
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Martin Streiter, Tillmann G. Fischer, Christian Wiebeler, Sebastian Reichert, Jörn Langenickel, Kirsten Zeitler, Carsten DeibelList of authors in order
- Landing page
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https://doi.org/10.1021/acs.jpcc.0c03341Publisher landing page
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YesWhether a free full text is available
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greenOpen access status per OpenAlex
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https://arxiv.org/pdf/2001.11317Direct OA link when available
- Concepts
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Fluorescence, Excited state, Molecule, Singlet state, Photochemistry, Materials science, Chlorine atom, Atom (system on chip), Chlorine, Chemistry, Molecular physics, Atomic physics, Physics, Optics, Medicinal chemistry, Metallurgy, Embedded system, Computer science, Organic chemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
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9Total citation count in OpenAlex
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2025: 1, 2024: 2, 2023: 3, 2022: 2, 2021: 1Per-year citation counts (last 5 years)
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56Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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